Voltage Waveform Tailoring in a RF-CCP reactor: Exploration
Transcription
Voltage Waveform Tailoring in a RF-CCP reactor: Exploration
Voltage Waveform Tailoring in a RF-CCP reactor: Exploration of self-bias, electron density and current waveform Pierre-Alexandre Delattre1,2, S. Pouliquen1, E.V. Johnson2, J.P. Booth1 1 Laboratory of Plasma Physics, Palaiseau, France 2 Laboratory of Physics of Interfaces and Thin Films, Palaiseau, France Introduction Electron density We have implemented Voltage Waveform Tailoring to excite capacitive plasmas with arbitrary voltage waveforms. In particular we have investigated peak and valley waveforms (see figure 1). These lead to electrical asymmetry [1], causing self-bias, even for a geometrically symmetrical reactor. These waveforms differ from standard sine waveforms by their fast voltage rise-time (efficient for electron heating) and their skewed duty cycle, which allows the average sheath potential drop, and therefore the ion energy hitting electrodes to be controlled. The electron density in H2 plasma, determined by hairpin quarter-wave microwave resonator [3] C V plasma substrate electron density (cm-3) ground Figure 1 : The RF-CCP reactor used. Philix is geometrically asymmetric (grounded / powered area ratio≈ 2). The substrate is on grounded electrode for PECVD. [1] Donko Z et al. J. Phys. D: Appl. Phys., 42(02):5205, 2009. Electron density Peaks > Valleys > Sine Peaks 1E10 Valleys 1E9 Sine 100 mTorr 1E8 0 100 200 300 400 500 600 700 a) Vpp (V) Voltage Waveform Tailoring electron density (cm-3) Peaks We create the desired voltage waveforms by superposing 4 harmonics (fundamental at 15 MHz) and correcting for distortion in fourier space [2](Fig 3). The voltage is measured at the RF feedthrough. 0 -5 -100 -10 -200 Voltage (V) 0 -20 40 60 80 100 Time (ns) Frequency Response 20 15 100 5 0 0 -5 -100 -10 Sine Slopes are different 1E9 250 mTorr 1E8 100 200 300 400 500 600 700 b) Vpp (V) -15 -300 120 Valleys 0 10 -200 -15 -300 a) 200 10 5 20 V selfbias I Current (A) Voltage (V) 15 100 0 valleys 300 20 -20 0 20 b) Capacitively Coupled Plasma no impedance matching 40 60 80 100 120 Time (ns) Figure 3 : Correction loop. VTW optimise d waveforms FG : function generator RF : RF amplifier C : decoupling capacitor HV : high voltage probe Derivative : Vigilant-VI derivative probe (www.solayl.com) probe Note the absence of impedance matching. • Why do the complementary waveforms (peaks and valley) give different electron density ? The reactor is asymmetric. Geometrical asymmetry and electrical asymmetry interact each other. • How do you measure Vpp ? Peak to peak voltage is measured at RF feedthrough and not exactly at electrode. Therefore, there exists some uncertainty on Vpp. 900 mTorr 1E10 Peaks Valleys 1E9 Sine Difference is smaller at higher pressure 1E8 0 100 200 300 400 500 600 700 c) Vpp (V) Figure 4 : Vpp is peak to peak voltage. [3] Piejak R.B. J. Appl. Phys., 95(7):3785, 2004. [2] Patterson et al. 2007 Plasma Sources Sci. Technol. 16 257 Discussion electron density (cm-3) V selfbias I 200 Correction (in fourier space) signal power numerical peaks 300 Current (A) Figure 2 : Tailored voltage waveform & current waveforms. The self-bias is a combination of geometrical and electrical asymmetry (a : Vpp = -80 - 100 = -180 V, b : Vpp = -80 + 100 = +20 V). Duty cycle are a) 35 % and b) 65 %. 1E10 Conclusion Perspective • The peaks and valleys waveforms lead to significantly higher electron density than sine due to faster slew rate for the same Vpp. • The electrical asymmetry effect is sensitive to geometrical asymmetry of the reactor • Use a more symmetric reactor • Measure voltage directly at the electrode • Investigate uniformity in a larger reactor • Measure ion energy distribution function Thanks : JPB, EVJ, SP & S. Dine Fundings : CNRS-PIE STEP-UP, ANR-CANASTA, Ecole Polytechnique Bourse de Thèse [email protected] +331 6933 5871 http://www.lpp.fr/?Pierre-Alexandre-Delattre
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