Propane
Transcription
Propane
Propane customer safety information book BP is interested in enhancing propane customers and their end consumers knowledge associated with the use of propane, educating them in the safe handling of the product. The voluntary guidelines as recommended in this CD / document were developed by independent propane industry consultants. BP does not independently test or verify the accuracy of the information or methods used to collect the data that supports the conclusions or recommendations reflected in this document. BP disclaims any liability for any personal injury, property damage, business losses or other damages of any nature whatsoever, whether special, indirect, consequential or compensatory, directly or indirectly resulting from the publication, use, or reliance on this document, or any information, apparatus, method, process or similar item disclosed in this document. This disclaimer of liability shall apply even if such loss or damage results, in whole or in part, from any acts or omissions of or by any negligence on the part of BP or any persons who contributed to the development of the information contained in this document. BP makes no warranty or guaranty as to the accuracy or completeness of any information published in this document. Users of this CD / document should consult the law of their individual jurisdictions for codes, standards and legal requirements applicable to them. This document is not intended nor should it be construed to (1) set forth policies or procedures which are the general custom or practice in the propane industry; (2) to establish the legal standards of care owed by propane distributors to their customers; or (3) to prevent the user from using different methods to implement applicable codes, standards or legal requirements. By disseminating or publishing this CD / document, BP is not undertaking to render any professional or other service to or on behalf of any person or entity. Anyone reading or using this document should rely on his or her own judgment or, as appropriate, should seek the advice of a competent professional in determining the exercise of reasonable care in any and all circumstances. 2 Welcome to our Propane Customers When used properly propane is a safe, economical, clean burning and environmentally friendly fuel with many different uses such as: • Home heating, cooking, water heating, fireplaces • Lawn maintenance – mowing, trimming • Power generation – portable generators • Forklift operation • Barbeque grills, smokers, fish fryers • Temporary construction heating • Vehicle fuel • Commercial heating • Industrial / process heating • Agricultural uses – crop drying, irrigation, etc. • RV heating, cooking, water heating As with any energy product (gasoline, natural gas, electricity, fuel oil, wood, etc.), it is important to respect, understand and know how to safely use propane, your propane system and appliances. This CD provides information regarding: “what propane is”, leak detection and emergency procedures to follow if you suspect a leak, propane odorization and odor fade, a technical information bulletin, Material Safety Data Sheets (MSDS), and much more. The health and safety of propane workers, consumers and the general public remain of paramount concern and a core value of the propane industry. Propane wholesale and retail companies along with regulators, and other industry members and support groups are committed to and guided by a vision of safe storage, transporting and usage of propane. BP, as a supplier of propane to wholesalers and retailers, shares this safety vision. To that end, a well informed propane workforce is essential to maintaining the health and well being of propane customers, consumers and the general public. BP is committed to enhancing our customers’ knowledge of propane and it’s properties, educating them on the safe handling of the product. It is our hope that in this CD you will find the safety information useful. Please feel free to print the materials in this CD and review it with your employees. Equally important, please share all safety information with your end users to keep them informed and safe. For more propane safety and educational information as well as training materials and course offerings around the safe handling and usage of propane, please visit the PERC Safety & Training web site www.propanesafety.com. Thank you for your diligence in this important area. Some of the information in this CD was provided with permission from the Propane Education and Research Council (PERC), extracted from information and training materials found on the PERC website www.propanesafety.com . Besides generally promoting propane industry safety throughout the CD, BP also supports the fine work of PERC in building awareness for propane safety and providing training and education venues for propane retailers and suppliers. 3 A Legal Duty to Inform Customers In most states the law requires every person or company in the chain of distribution, to provide the end propane consumer instruction on how to use it properly, the inherent dangers associated with propane use and the proper means to avoid those dangers. Propane retailers must provide full and adequate warning to its direct customer. Adequate information would include a description and sources where the proper warnings may be obtained. Retailers should annually review and take stock of their propane safety programs. Each company needs to tailor its safety program to its specific circumstances. Good propane safety programs typically focus on three basic areas: warnings and safety information for their customers, employee training, and policies and procedures implementing practices taught in training. Consumer Education Every retailer should have a warning program in place with two primary goals: (1) getting warning and safety information to customers and (2) documenting that warning and safety information was provided to customers (e.g. customer receipts or utilization of mailing services). Warning and safety material can take a variety of forms – warning labels/decals available from local Propane Marketers, State Propane Gas Associations, and PERC, posters, brochures (e.g. ‘Scratch and Sniff’ for odor detection), printed information that can be included on invoices and other customer mailings – some of which can be found within this Safety CD. Other sources of safety information material are the State Propane Gas Associations, PERC, NFPA 58 and more. Safety Training It is vitally important that all employees handling propane are adequately trained. This includes everyone from people that fill barbecue cylinders for walk-in customers, to bulk delivery drivers filling tanks at consumer’s homes, and to customer service representatives. Training is not just common sense, it is required. NFPA 58 provides, “In the interest of safety, all persons employed in the handling of LP gases shall be trained in proper handling and operating procedures, which the employee shall document. 4 Contents I. PROPANE INFORMATION …………………………………………………………………… 7 • What is Propane? • Properties and Characteristics • Personal Protective Equipment II. ODORANTS …………………………………………………………………………………….11 • Purpose of Propane Odorants • Odorant Characteristics • Adding Odorants • Verifying Propane Odorization • Odor Fade • Preserving Odorants III. HANDLING AND DISPENSING PROPANE SAFELY……………………………………..14 • Receiving Propane Safely . . . . . . . - Tank Types / Specifics – features, capacity, mode of transport, etc. • Dispensing Propane Overview - Dispensing Stations - Dispenser Operators - Dispenser Training Requirements - Operating Safely and Consumer Responsibilities • Dispensing Equipment - Typical Equipment - Preparing the Dispenser - Dispenser Shutdown • Inspecting, Filling and Labeling Small Cylinders - Visual Inspections - Re-qualification - Purging - Filling and Labeling Cylinders - Cylinder Loading and Transporting • Additional Handling Safety Measures • Basic Fire Prevention Information - Fire Response Information - Fire Extinguisher Usage - Leaks and Fires • Delivering Propane Safely To End User Customers via: - Bobtail - Cargo Tank Motor Vehicle • Unloading a Cargo Tank Motor Vehicle 5 IV. GAS LEAK DETECTION – CONSUMER GAS COMPLAINTS, GAS LEAKS AND SERVICE INTERRUPTIONS ………………………………………………………….34 • Leak Detection • End Customer Response • Taking Safety Precautions • Investigating and Identifying Gas Leaks • Gas Service Interruptions • System and Surrounding Inspections V. EXHIBITS – INFORMATIONAL MATERIAL TO BE USED TO PROMOTE WORK AND HOME PROPANE SAFE USAGE ……………………………………………37 • Emergency Procedure for a Propane Leak • Steps to Take in the Event of an Accident Involving Propane • How to Control LP-Gas Leaks and Fires • NFPA 704 Hazardous Material Identification System • Technical Information Bulletin 34.19-2 VI. MATERIAL SAFETY DATA SHEETS (MSDS) …………………………………………….56 6 I. PROPANE INFORMATION What is Propane? Propane is a hydrocarbon (C3H8) and is sometimes referred to as liquefied petroleum gas, LPgas or LPG. Propane is produced from both natural gas processing and crude oil refining. Most propane used in the United States is produced domestically with some imported from Canada and from overseas. It is nontoxic, colorless and virtually odorless. As with natural gas, an identifying odor is added so the gas can be readily detected. In its natural state, propane is a liquid stored under pressure in tanks and cylinders. In most systems, propane is vaporized to a gas before it leaves the tank or cylinder and is then dispensed through a pressure regulator to an appliance, vehicle or piece of equipment. Millions of Americans use propane each day. Propane is used in and around homes for furnaces, water heaters, air conditioners, outdoor grills, fireplaces, and appliances; on farms for uses such as pest control, crop drying and irrigation pumps; for industrial uses such as forklifts and fleet vehicles and in millions of commercial establishments, including restaurants and hotels that depend on propane for heating, cooking, and other uses. In the United States there are approximately 70,000 miles of interstate pipelines and more than 25,000 retail dealers making propane readily available for most homeowners and convenient to use. Because propane is stored in portable tanks, it can be used in areas beyond gas mains. To fuel homes, large tanks can be buried underground because it is a nontoxic, non-poisonous fuel that doesn’t contaminate aquifers or soil. Refueling a propane vehicle takes about the same amount of time as refueling a gasoline vehicle. Nationwide, propane refueling infrastructure consists of more than 10,000 public and private sites. Propane is one of the cleanest burning of all fossil fuels. Propane is an approved clean fuel listed in the 1990 Clean Air Act and the Energy Policy Act of 1992. Tests conducted by the U.S. Environmental Protection Agency show that propane-fueled vehicles produce 30 to 90 percent less carbon monoxide and about 50 percent fewer toxins and other smog-producing emissions than gasoline engines. Propane also is non-toxic, so it’s not harmful to soil or water. PROPANE PROPERTIES AND CHARACTERISTI CS Safe handling and dispensing of propane involves knowing its properties and characteristics, plus being aware of safe handling procedures, wearing the proper protective equipment and taking safe measures to reduce the chance of injury occurring on the job. More on this later in the CD. CHARACTERISTICS Safe dispensing of propane involves knowing its properties and characteristics, plus being aware of safety procedures. A Material Safety Data Sheet (MSDS) is available from propane suppliers and distributors, and by law must be available and accessible to all employees at the workplace. Within this CD is information from the MSDS that relates to the job of safely dispensing propane. There are propane MSDS at the end of the CD. More detailed information on dispensing propane can be found in later sections of the CD. 7 Propane can be either a liquid or a gas depending on the amount of pressure in which it is stored. To store propane as a liquid above its normal boiling point (-44 ºF), it must be stored and transported in pressure-tight containers. Propane liquid stored in containers at ambient temperatures will begin to boil off and pressurize the vapor space of the container. This vapor is what is used in customer propane appliances and equipment. In its natural state, propane is colorless and odorless. To increase the likelihood that a propane leak will be detected, an odorant (usually sulfur-based) is added to the gas at the time of production or shipping. Learn to recognize the odor of propane and always be sensitive to the slightest smell of gas. Under certain conditions, the chemical odorant can fade or diminish in intensity. Some persons may have difficulty detecting this odorant. Colds, allergies, sinus congestion, cooking odors, certain medications, age, prolonged exposure to the odor of propane, damp or musty smells and the use of tobacco, alcohol or drugs may diminish the dispenser’s or end users’ ability to detect the odorant. More detailed information on odorization and odor fade can be found in the next section as this is a critically important safety area. If for any reason a dispenser or end use customer cannot smell odorized propane, they are to notify a supervisor or their propane supplier immediately. Both the dispenser or the end user’s safety may depend on their ability to smell propane in the event of a leak. Liquid propane, like water, will expand when heat is added to it. Propane liquid, however will increase in volume nearly 17 times greater than water over the same temperature increase. To allow for this expansion, propane containers are typically filled to only 80% of their capacity. If propane liquid is released into the air, the lack of pressure quickly vaporizes it, expanding it to 270 times its original volume. Therefore, liquid propane leaks can be more hazardous than vapor leaks. Propane is non-toxic, but if released in a confined space, will displace air. Therefore, avoid inhaling propane. Propane vapor is 1-1/2 times heavier than air. If released into still air, it may initially settle in low lying areas. However, if there is sufficient air movement, especially outside, the vapor will quickly dissipate in the air. Propane also causes a refrigerating effect that makes everything it touches extremely cold. This means if it comes in contact with skin, it can cause third degree or deep freeze burns. The following section talks about Personal Protective Equipment that should be worn when handling or dispensing propane. 8 Personal Protective Equipment (PPE) Because of propane’s refrigerating effect and other characteristics, gloves or other personal protective equipment resistant to propane should be worn when filling containers. Employers may require other personal protective equipment e.g. goggles, respirators, boots, etc. depending on the responsibilities of the employee. When necessary, always wear personal protective equipment such as gloves, safety shoes, safety glasses and hard hats to eliminate on-the-job accidents. Using personal protective equipment requires hazard awareness and knowledge of the equipment’s purpose, limitations, proper fit and maintenance. Personal Protective Equipment: OSHA Requirements Under OSHA regulations employers are responsible for: • Determining the use and selection of personal protective equipment. • Training all employees to properly use and care for personal protective equipment. • Documenting employee training and use of personal protective equipment. OSHA requires the use of personal protective equipment during operations that present the risk of injury to employees that cannot be eliminated by engineering or process procedures. Head and Face Protection Face and eye protection is absolutely necessary when chipping, grinding, drilling, sledging, or using air-powered tools for breaking pavement. In these situations, protect your eyes and face by wearing a face shield or protective goggles. Head protection means wearing a hard hat on construction sites where it is possible to be hit on the head by falling or swinging objects, or when required. Bump hats may be worn when working in crawl spaces or other areas where piping and irregular structures may cause head cuts or bruises. Hearing protection includes ear plugs or acoustical ear muffs. Wear hearing protection when noise makes it difficult to communicate verbally with other workers. Depending on the work area or job function, employers may determine that hearing protection is necessary. When steady or impulse noise levels are at or above 85 decibels, hearing protection is required. Hands, Arms and Feet Protection Suitable work gloves should be worn to protect hands when doing jobs such as: • Handling pipes or planks • Using heavy tools • Moving tanks or cylinders • Cutting with torches or welding • Transferring liquid propane 9 Gloves should never be worn around moving machinery where there is a possibility of hands or gloves getting caught and pulled into moving parts. Encourage employees to wear long sleeve shirts with the sleeves rolled down to protect their arms, and to wear safety shoes to protect their feet, particularly if they are a cylinder delivery technician. Much of that work involves handling heavy tools, equipment, and installation materials. First aid treatment should be given if minor cuts, scratches, or bruises occur. Respirators Respirators are an important piece of equipment to help employees breathe when the oxygen level is low or if the air is contaminated with toxic substances such as carbon monoxide. There are two basic types of respirators: • Air Purifying Respirators use filters that remove harmful substances from the air. They range from simple disposable masks to complex powered air purifying respirators. But air purifying respirators don’t supply oxygen and should not be used in oxygendeficient air or in air that is immediately dangerous to life or health. • Air Supplying Respirators provide breathable air from a clean air source when the surrounding air is contaminated. They range from supplied air respirators, called SARs, and self contained breathing apparatuses called SCBAs, to complete air supplied suits. Be sure to consult Material Safety Data Sheets to determine which respirator to select and the requirements associated with its use. Under the Dispensing Propane section in the CD, we will provide more suggested safety measures to help prevent bodily injury when handling propane or propane cylinders. 10 II. ODORANTS Odorants This section is critically important to everyone’s safety in handling propane. Please pay particular attention to it and be sure to share it with employees. Purpose of odorants Because propane is naturally odorless and colorless, a commercial odorant is added so propane can be detected if it leaks into the environment. Although other odorants may be used, the one most commonly used is ethyl mercaptan, which is added at the rate of at least one pound per 10,000 gallons of propane. Effective odorization enables the detection of leaks before gas concentration in the air reaches a flammable level. It also reduces gas loss through early detection and repair of leaking pipes, fittings and storage container fixtures Odorant Characteristics Odorants have the following characteristics: • An odorous and unpleasant smell; distinctive and readily identifiable as a gas additive and unlike other odors • Mix well with liquid propane at the same or nearly the same rate - volatile • Stable, inert or chemically inactive enough not to bond with, decompose or react with other parts of the gas or with materials in the distribution system or appliance - inert • Non-corrosive under conditions found in gas transmission, distribution and utilization. • Burns completely in the gas flame to form products that are not corrosive, irritating or toxic - combustible Adding Odorant - Requirements Propane is odorized at a refinery, processing plant or pipeline terminal before it is shipped to the bulk plant. Both NFPA 58 and the Department of Transportation (DOT) set safety standards regulating the addition of odorants. Both NFPA 58 and DOT require that propane be odorized before transporting it to a bulk plant. The only exception is when the propane will be used in a manufacturing process that requires the use of “unstenched” LP-gas. According to NFPA 58, a sniff test must be performed and documented whenever a tank car or transport delivers propane to the bulk plant. Propane dispensers may also perform sniff tests when filling cargo tanks and customers’ containers. NOTE: Know company policy and standard operating procedures for documenting the presence of propane odorant and responding, if there is a suspicion that propane is not properly odorized. For safety reasons, a person should be able to smell the odorant when the concentration of propane is below the Lower Flammability Limit or LFL. When there is a slight smell of propane odorant, proper actions must be taken to determine the source. 11 HANDLING UNODORIZED PROPANE If propane appears to be unodorized: • Do not load the cargo tank or cylinder. • Disconnect the transfer hoses and secure them in their storage racks. • Contact a supervisor immediately. • Alert others in the area not to load until approved by the facility manager or supervisor. The company may also require closing and tagging the withdrawal valves on the storage container so it is not distributed to consumers. VERIFYING PROPANE ODORIZATION Simply smelling the propane is one method of verifying that odorant has been added to propane. This is called a sniff test. THE SNIFF TEST The sniff test is the most widely used method to check for propane odorant and is considered by the industry as standard procedure. Being heavier than air, leaking propane will initially sink and collect near the floor. To check whether there is a leak using the sniff test, get down on your hands and knees and sniff close to the floor to smell for propane. Always take the following precautions when performing the sniff test: • Wearing appropriate protective gear • Only vent a small amount of liquid propane • Sniff only after the vent is closed and the liquid propane has vaporized • Become familiar with company policies and standard operating procedures, including how to document the presence of propane odorant and procedures to follow upon encountering potentially under odorized propane. There are other, less commonly used tests for verifying propane odorant, such as using stain tubes or odorometers. THE SNIFF TEST DURING BOBTAIL LOADING Follow these steps to perform the sniff test when loading a bobtail: 1. After securing the plant liquid transfer hose to the cargo tank connection and before filling the cargo tank, briefly open and close the transfer hose end valve. 2. Vent a small amount of liquid propane through a #54 vent and then close it. 3. Sniff the area immediately after the liquid vaporizes. 4. Verify that the propane is odorized. 5. Record the sniff test results on the loading ticket, daily routing report or other company form and proceed with the loading operation. There is more bobtail loading information in a later section of the CD. 12 PRESERVING ODORANTS / CAUSES OF ODOR FADE Odor fade can occur when there is an underground propane leak. The movement of gas through the soil can filter out the odorant. Oxidation (a chemical reaction involving internal rust in the tank or cylinder) also causes odor fade. New and reconditioned tanks and cylinders that sit too long before being filled are prone to internal rust when moisture and air get inside. Absorption is another cause of odor fade. The odorant in leaking gas can absorb (stick) on new or old building materials such as unpainted or untreated masonry, rough wall surfaces, on the inside of gas piping and on furniture fabrics and drapes thus reducing the intensity of the odor. Note: • Under some conditions, the chemical odorant (usually ethyl mercaptan) that gives propane its distinctive smell can fade or diminish in intensity. • On rare occasions, a leak can exist and the gas may not have an odor. Generally odor fade doesn’t occur in containers that have been in continuous use. However, with new containers, or ones that have been left open to the atmosphere, you must take precautions to maintain odorant integrity. Follow these practices to keep odorants from oxidizing and fading: • Purge air and moisture from the propane container. • Keep propane containers pressurized when shipping and until installation at customer locations. • Keep valves closed on containers in storage to prevent moisture in the air from entering the container. This keeps water and rust from building up inside the container. Know company procedures regarding container purging and storage practices. Some containers are now being shipped with a vacuum in them. In other words, manufacturers suck the air and moisture out of the containers right after they’re manufactured. This is an attempt to prevent the inside walls from forming the ferrous oxides (rust) that do the most damage to odorants. On these containers, make sure that the vacuum seal is not broken until the container is filled with propane. Loss of sense of smell In addition to odor fade, physical conditions may prevent smelling a propane leak. Some physical causes are: • Colds, allergies, sinus congestion • Use of tobacco, alcohol or drugs • Cooking odors and certain foods eaten • Certain medications • Decline in ability to smell, especially for older people • Prolong exposure to the odor of propane • Musty or damp smells such as in a basement Contact a doctor when concerned about the ability to smell propane. 13 III. HANDLING AND DISPENSING PROPANE SAFELY Receiving Propane at a Bulk Plant Cargo, Railroad and Intermodal Portable Tanks Large shipments of propane are transported to bulk plants in three different types of tanks: cargo tanks, railroad tank cars and intermodal (IM) portable tanks. All of these tanks are designed according to DOT specifications. Cargo Tanks • Features: Cargo tanks are the most common tank used to transport propane to a bulk plant. They’re installed on both bobtails and transport trucks. • Water capacity (transport cargo tanks): Approximately 9,000-11,600 gallons (some exceed 14,000 gallons). • Water capacity (bobtail cargo tanks): Approximately 1,800-5,000 gallons (some as small as 350 gallons). • Mode of transport: Bobtail or transport truck Railroad Tank Cars • Features: Railroad tank cars are the largest DOT tanks that transport propane. They have fittings and valves enclosed in a dome and are painted off-white to indicate thermal insulation or black to indicate a jacketed tank car. • Water capacity: 4,000-45,000 gallons. • Mode of transport: Railroad Intermodal (IM) Portable Tanks • Features: IM portable tanks are used to deliver propane to locations requiring multiple modes of transportation. They are also used for temporary or emergency service at customer sites or bulk plants. • Water capacity: 4,500-6,500 gallons. • Mode of transport: Boat, truck, or railroad Cargo Tanks – Overall Structure Cargo tanks are built according to DOT design code MC330 or MC331, as well as ASME codes. They are constructed of steel and are equipped with openings and baffles. • Tank steel — Every cargo tank is built from a certain type of steel. Some cargo tanks use heat-treated steel that has been through a heat-treating process called quenching and tempering (QT). These tanks are somewhat lighter than tanks made from nonquenched and tempered (NQT) steel. • Tank openings — Cargo tank openings are either threaded or flanged. An inspection manway is usually located in the upper section of the rear head. Since 1994, manways have been required in cargo in cargo tanks. Openings for transferring propane liquid and vapor are usually located on the bottom of the tank. Openings for the relief valves are located on the top of the tank. 14 • Tank baffles — Tank baffles are circular, rectangular or cross-shaped steel plates mounted inside the cargo tank. They limit the movement of liquid when the vehicle is in motion. While they effectively decrease the sloshing of liquid in forward and backward motion, baffles are not effective in limiting side-to-side motion or preventing vehicle rollover. Baffles cannot be inspected from outside the cargo tank. If a baffle breaks, however, it may make a clanging noise when the vehicle moves or is loaded or unloaded. Railroad Tank Car Overall structure • Railroad tank cars are built according to DOT design specifications 105, 112 and 114. They are equipped with tank openings, tank protection and tank insulation. • Tank openings—All valve openings in railroad tank cars are located on the top of the tank and protected by the dome. The dome encloses a large opening on the top of the tank and connects to a welded fitting at least 14" to 18" in diameter. As a safety precaution, always inspect the dome area and the valves for leakage or damage. Contact your supervisor and follow company policy if you identify any unsafe conditions. • Tank Protection—Rail car tanks are protected by thick steel at each end to prevent a coupler or any other object from puncturing the lower half of the tank head. Check the head of the car for damage and report any unsafe conditions. • Tank insulation—All railroad tank cars used for propane transportation have special thermal protection in the event of exposure to fire. DISPENSING PROPANE SAFELY Overview Propane Dispensing Stations Dispensing stations can be found on bulk plant cylinder docks, industrial locations, hardware stores, campgrounds, rental equipment companies or gasoline stations. They offer a convenient fueling source for residential, recreational and business users of propane. Propane dispenser operators play a critical role in safely and efficiently providing propane to the end users. Propane Dispenser Operators Propane dispenser operators’ responsibilities include: • Understanding the operation of the dispensing equipment, the regulations pertaining to it, and the routine inspections which should be performed before each use. • Inspecting end use customer containers to ensure that they are safe for filling. • Filling containers to their proper levels and ensuring that containers are not overfilled; • Communicating to end users product safety information and warnings such as the proper securing of containers when transporting them; • Maintaining the security of the propane dispenser and transfer area to control ignition sources and to prevent tampering or release of propane; • Knowing how to shut down and secure the dispenser in the event of an emergency. 15 Dispenser Training Requirements There are specific training and inspection requirements published in national codes (such as NFPA58, the LP Gas Code) and by government agencies such as the United States Department of Transportation (DOT), the Department of Labor (DOL) and the Occupational Safety & Health Administration (OSHA). NFPA 58, the LP-Gas Code, is a national standard that addresses: • Dispensing station equipment requirements • Cylinder storage and refueling • Cylinder appurtenances (such as overfilling protection devices) • Dispenser operator training States and jurisdictions have differing policies relative to the adoption of various editions of NFPA 58; some may add or delete provisions to the code. Check with a supervisor to determine which edition of NFPA 58 applies locally and whether any provisions have been modified. Some of the DOT requirements cover: • Visual inspection prior to filling cylinders • Pressure relief device leak checking and replacement • Periodic cylinder requalification • Cylinder markings and labeling • Cylinder weight verification • Filling methods used (weight or volume) • Hazardous material training and documentation OSHA rules include: • The use of and training in personal protective equipment (PPE) • Written Hazard Communication Plans and Material Safety Data Sheets (MSDS) • Emergency Action Plans Propane dispensers must know their responsibilities, be properly trained to follow proper handling procedures and understand the applicable regulations and local laws in order to provide end users and the general public a safe, efficient energy source. Safe Propane Dispensing Every release or leak creates the potential for a hazardous situation. Keep in mind that the proper mixture of propane vapor, air and a source of ignition causes propane to burn. To minimize the likelihood of sources of ignition or propane release, customers should be restricted from the immediate area around the liquid propane transfer operation. To safely dispense propane, it is important to know the following: • The location of and how to operate emergency shutdown and pump controls • The location and condition of the fire extinguisher • Plant fire prevention and emergency evacuation plans • That ignition sources are not permitted within 25 feet of the point of transfer and combustible materials within 10 feet 16 • • Valve protection is required, except for the time that cylinders are on the scales and being filled Proper cylinder handling techniques Upon dispensing propane to a consumer (filling a cylinder), please remind them of the following regarding: • Transportation and Storage of Cylinders - Always transport cylinders in a secure and upright position so they will not fall or roll - Never transport in the passenger compartment of any vehicle - Never transport without closing and sealing the valve • Heat Never keep a filled cylinder inside a hot vehicle or inside the closed trunk of a car. Heat may cause the pressure relief valve to release propane. Note: Flash fires and explosions can result from exposing cylinders to heat • Disposing of Small Propane Cylinders Never burn or crush empty containers. Many ordinary household products use unodorized propane as the propellant. Although they may seem empty, the containers may have propane vapors left in them. Propane can be released when exposed to heat or pressure, enabling flash fires or explosions to occur. Dispensing Equipment In order to safely dispense propane, propane dispensing employees must know the equipment they are working with and how to use it. There are two main types of packaged propane dispenser installations: vertical tank dispensers and horizontal tank dispensers. Dispensing equipment may vary with the location. Systems may or may not have the following components: • An ASME storage tank that supplies propane to the dispensing equipment • Valves to control the flow of propane through the piping system • Extra heavy piping and forged steel pipe fittings • A propane pump, driven by an explosion-proof electric motor • A platform scale for weighing cylinders during and after filling • Automatic pump by-pass valve(s), to protect the pump, piping and hoses against excessively high pressures when the hose end valves are closed and the pump is running • Electrical wiring, fixtures and switches to control the propane pump motor and provide for emergency shutdown. • A metering system for measuring liquid propane transferred into appropriate containers. • Propane transfer hose assemblies for cylinder filling and ASME tank filling. • Hose end adapters to accommodate the different valves used on DOT cylinders and ASME tanks. • An emergency break-away device for vehicle-mounted containers designed to provide protection in case of a pull-away. These are usually on the ASME tank transfer hose assembly to stop the flow of gas, if the customer drives away with the hose attached. • A fenced enclosure or lockable cabinet to secure the dispenser when not in use. Depending on the site and enclosure, traffic barricades may also be required. 17 Manual shutdown dispensers rely on the operator to determine when the maximum permitted filling limit for a cylinder is reached, and to stop the flow of liquid into cylinders by manually closing one or more valves. Automatic shutdown systems are used primarily where several cylinders are being filled simultaneously, such as the cylinder dock at a propane plant. They reduce the possibility of overfilling cylinders and normally consist of a sensor or trip lever mounted on the balance beam of the scale and a master control valve that restricts the flow of liquid propane to the dispensing hose. The dispenser tank may be equipped with either an internal excess flow valve in combination with a positive shutoff valve or an internal valve which incorporates excess flow protection and may include thermal and remote shutoff capability. Remote shutdown stations may also be located away from the pump and transfer location providing a greater level of emergency shutdown capability. Ball valves control the flow of propane from the supply tank through the piping and may be used as a hose end valve. A ball valve is open when the valve handle is pointed in the same direction as the piping (illustrated); in the closed position, the handle is across the piping. Globe valves are similar to a water faucet and are operated by turning the hand-wheel counter-clockwise to open and clockwise to close. They must be either fully open or fully closed. Hose end valves stop the flow of propane as part of the container filling operation. As another safeguard against overfilling containers hose end valves must be quick closing or snap acting types. Many designs also incorporate a safety latch to prevent accidental opening when the valve is not connected for filling. Platform balance beam scales determine when the proper filling weight for cylinders is reached and when to stop the flow of liquid propane into the cylinder. In many states and jurisdictions, scales must bear certification decals from weights and measures officials, and be periodically inspected and calibrated for accuracy. Platform scales can be either single beam or double beam. Both require periodic maintenance and should be checked daily for proper registration at zero and with a known weight. They must also be leveled and protected from weather, especially accumulation of water, debris, snow or ice. Preparing the Dispenser The first step in preparing the dispenser for operation is to unlock and open any or all entry gate or gates. If the dispenser is equipped with a cabinet, unlock the cabinet and verify that the hose end valves are closed. With the exception of the hose end valves, slowly open the liquid outlet valve and the first downstream manual valve. 18 • • • If valves are opened too quickly, the excess flow valve may close and you’ll hear a snapping noise. Shut off the manual valve and the internal valve. When the pressure equalizes, slowly open the operating valves including the vapor valve connected to the vapor return line from the meter. Inspect all valves, piping, transfer hose and fittings for proper operation as well as the threads of all connection adapters, especially brass for excess wear and to assure that the gaskets are in place and in suitable working condition. Verify there are no propane leaks. Dispenser Shutdown When the dispenser is not in use, or at any time that a qualified dispenser operator is not in attendance, the dispenser should be shut down and secured. The shut down procedure is basically the reverse of preparing the dispenser for operation. • Close all valves at the storage tank. • Place a dust cap or plug in the hose end valve or Filling adapter • Store the filler hose in the proper location • Close and lock the cabinet and/or fence gates Becoming familiar with the dispensing equipment and how it works will enable dispenser / operators to safely fill cylinders and protect end users, the workplace and the employee. INSPECTING, FILLING AND LABELING SMALL CYLINDERS Pre-fill Visual Check Safely inspecting and filling small portable cylinders is an important job that requires following specific procedures. End users are often not aware of cylinder inspection, requalification, purging and filling requirements. Consequently certain cylinders may be compromised and should not be filled with propane. There are unknowns as to conditions of the container prior to its arrival for refilling, or after the container leaves the filling station. Reasonable care must be exercised in handling the cylinder while it is at the filling location. Before a small cylinder can be filled or refilled DOT regulations require a visual check to verify that it is fit for continued service. If any of the following conditions are found, the cylinder must not be refilled. • Leaks • Cracks • Bulging • Serious denting or gouging • Defective valves • Defective or leaking pressure relief device • Evidence of physical abuse, fire or heat damage, or excessive rusting or corrosion • Damage to the cylinder valve, valve protection and cylinder foot rings • Out-of-date requalification 19 If any of these conditions are found, identify the cylinder and set it aside in a designated safe area. Steel cylinders subjected to fire must be requalified, reconditioned or repaired prior to being put back into service. Aluminum cylinders subjected to fire must be permanently removed from service. Cylinders with a series of XXXs over the DOT specification number and marked service pressure or stamped with “CONDEMNED” on the shoulder, head, or collar are condemned cylinders and must not be refilled or continued in service. Valves and accessories should be inspected prior to filling. Many cylinder valves are made with non-metallic or soft parts such as Nylon, rubber or Teflon®. When these materials wear out or are damaged, propane liquid or vapor can leak out of the valve and create a potentially hazardous situation. They should be checked regularly for signs of aging and wear. Valve accessories may become broken or even lost, allowing dirt or moisture to enter. Inspect and replace faulty or missing dust caps. Many states and jurisdictions require that cylinders be equipped with an OPD, an overfilling prevention device. Check your company’s policies for refilling and handling cylinders that do not have an OPD. Valves may also be damaged through improper cylinder maintenance. For example service personnel may fail to use proper brushes or applicators around cylinder openings when painting them. As a result, gauge faces, "weep" holes in filler valves, and discharge openings of relief valves may be covered with paint. A blue-green stain on the brass portion of the cylinder valve is evidence that it has been in contact with anhydrous ammonia, which is often used to manufacture illegal drugs. If a cylinder is found in this condition, isolate it by placing it in an area where hazards from ejection of the valve and product loss would be minimized then and notify a supervisor. Requalification All refillable cylinders must be requalified at regular intervals. Requalification is performed only by qualified individuals whose facility is registered with the DOT, not at dispenser locations. The most recent requalification date is stamped on the cylinder. • A date without a letter indicates the next requalification must be within 12 years. • The letter “S” following the date indicates the cylinder must be requalified within seven years of the marked date. • The letter “E” following the date indicates that requalification is required again within five years of the marked date. Cylinders that are out of qualification must NOT be refilled. 20 Purging In order for equipment to operate safely, both new cylinders that have not been vacuum purged by the manufacturer and those that have been opened to the atmosphere must be purged of air or moisture before they are filled. If air or moisture enter a propane cylinder, they can slow down the filling operation, create unusually high service pressures, may cause regulator freeze-up and may cause fading of the odorant in the cylinder. More details on odor fade later in the CD. Purging should be done in an approved area as outlined in NFPA 58, usually at a propane plant, and never done with propane liquid. Cylinder filling stations — Many bulk plants have a separate cylinder filling station or dock for loading, unloading and filling cylinders. Most plants use a separate pump with a very low pumping capacity for filling cylinders. These pumps transfer only 10-15 gallons of propane per minute. Filling Cylinders by Weight Cylinders less than 200 pounds water capacity and subject to DOT jurisdiction must be filled by weight. Please check for any exceptions. During the filling procedure, the operator must be in attendance the entire time. To fill a cylinder by weight: • Set the scale to the proper total weight of the filled cylinder: tare weight plus 42% of water capacity plus the weight of the hose and nozzle. • Filling charts with common cylinder capacities are also available • Open the liquid outlet valve on the storage / supply tank and any valves in the by-pass return line, if this has not already been done. • Connect the dispensing hose to the service valve • Open the service valve on the cylinder • Start the pump and slowly open the hose end valve • Close the hose end valve as soon as the scale beam or indicator tips • Close the cylinder valve • Shut off the pump • Disconnect the dispensing hose. Check the weight of the filled cylinder • If it has been overfilled, contact a supervisor. DO NOT GIVE THE END USER AN OVERFILLED CYLINDER, since the relief valve may release propane and create a flammable mixture. • Close the liquid outlet valve on the storage tank • Check the cylinder valves, especially the relief valve, for leaks Service valve outlets on cylinders of 45 lbs. propane capacity or less must be either plugged or equipped with a quick closing or quick connect coupling. No plug is required for OPD service valves; however, a protective cap or cover may be installed to keep out dust and debris. After the cylinder filling operation is completed, or at any time the dispensing station is unattended, shut off the pump, close valves at the storage tank and disconnect and store the hose. At locations that are not weather protected, install a dust cap or plug in hose filling adapter. Secure the installation against tampering. Cylinder Labeling NFPA 58, DOT and OSHA require specific labeling for all cylinders. DOT cylinders used to transport propane must be clearly and durably marked with the proper shipping name and hazard class. 21 In addition, a consumer information / warning label must be on all portable refillable cylinders of 100 lb. propane capacity or less not filled on site. The label must include information on the potential hazards of propane. Cylinders used in industrial applications must have additional warning information. Apply a new warning label if the original manufacturer’s label is not present or legible. If you have any question regarding the legibility or completeness of the warning label that is on the cylinder, place a new warning label on the cylinder. Cylinder Loading and Transporting Prior to releasing the cylinder to the end user, be sure it is protected against damage to the cylinder valves and fittings while being transported. Cylinders of 2-1/2 pound water capacity (1 pound propane capacity) or more must be positioned so that each cylinder's pressure relief valve is in direct communication with the vapor space at all times. Cylinders must also be fastened securely in a position to minimize the possibility of movement, tipping or physical damage related to each other or to the supporting structure, while in transit. It is important to recognize the difference between horizontal and vertical cylinders. They are typically marked to indicate in which position they are to be used. Failure to properly position cylinders during transportation may result in a very serious situation should the relief valve need to vent while having liquid in the valve. NFPA58 limits closed bodied vehicles such as passenger cars and vans to a maximum of 90# LP-Gas capacity with no single container having a capacity of more that 45#. Verify state and local codes, as they may be different. Many propane retailers distribute safety information literature to their end users when cylinders are filled. Sharing safety information is a good business practice anytime, or when a new end user purchases a cylinder or on an annual basis with a billing statement. Properly inspecting, filling and marking cylinders enables The propane industry to safely serve and protect both the end users and the propane retailer. At the same time, customers are provided with a safe source of fuel for their cylinder needs. Additional Safe Handling Measures When handling and dispensing propane, please take the following additional safety measures and precautions, and always wear personal protective gear. Lifting Materials Correctly Injuries resulting from lifting heavy materials can be prevented. 22 Follow the steps below for proper lifting: 1. Set feet solidly on the floor about 12" apart, with one foot slightly ahead of the other. 2. Crouch in front of the object with knees bent to a 90° angle. Do not squat. 3. Keep the back straight and firmly grasp the object. Make a preliminary lift to determine if the load is too heavy to lift alone. If yes, get help. 4. To lift the object, straighten legs and at the same time bring the back to a vertical or upright position. 5. Lift with a smooth, even movement. Avoid a jerking motion. If a change in direction is necessary, do not twist the body. Instead, turn the whole body. NOTE: Remember, improper lifting of light objects is much more likely to cause a back injury than properly lifting heavy objects. Loading and Securing Materials There are many precautions you should take when loading and securing materials. Some of these are: • When loading materials of different sizes and weights, place the heaviest objects on the truck bed and distribute the weight evenly on all wheels. • Place a flag or light on any materials hanging over the edge of the truck bed. • Properly secure pipe loads to the truck bed. • Be certain to secure any material that can shift on the truck. • A sudden shifting of weight can cause loss of control of the vehicle and damage the load. Use chains, straps or cables to secure loads properly. Because of the varying sizes, shapes, and weights of loads, it is difficult to list all of the precautions that should be followed for securing them. DOT and OSHA regulations require that securing devices be inspected prior to each use. Damaged securing devices should be repaired or replaced. Always follow company procedures whenever tying down a load on a truck or trailer. Storing Materials and Cylinders When storing materials at the propane plant, be sure to use: • Bins and racks • Appropriate supports • Signage showing safe floor loads and maximum heights to which materials may be stacked When storing cylinders, always be sure to: • • • • • Keep ignitable material at least 10 feet from cylinders Prohibit smoking or open flames Label all cylinders properly Monitor cylinders for leakage Understand all OSHA and NFPA 58 requirements Moving Cylinders with Hand Trucks Use hand trucks to move large or heavy cylinders, appliances, or drums. Hand trucks come in many designs and with varying wheel sizes depending on their capacity. Some are constructed with rails or treads to allow you to move on stairways. Don’t use a platform hand truck to move cylinders or drums. Instead, use a hand truck specifically designed for these. It may have a holding strap that can be tightened around the cylinder. 23 Loading Cylinders with Lift Gates Truck-mounted lift gates reduce labor when moving cylinders. When using lift gates, always be sure to: • Clear the are a of objects or people that could be hit by the lift • Properly balance the cylinder on the lift before operating • Lock the lift gate in the “travel” position before moving the vehicle Using Ladders and Platforms Falling incidents account for nearly 20% of disabling accidents each year. Most falls happen when ladders or platforms aren’t used properly. Ladders may be used for painting tanks and maintaining company buildings. Platforms are time savers when used properly and safely. They are commonly used for tank maintenance or railcar unloading. Basic Fire Prevention Information Fire has the potential to destroy property and take human lives. Therefore, it is critical to understand the following fire prevention rules when working with propane: • Observe any fire prevention signs posted at the plant and any warnings marked on containers with flammable material. • Note the location of emergency shutdown controls and fire extinguishers at the plant and on the truck. • Never block access to the fire control equipment including fire alarms, fire extinguishers, sliding fire doors, fire escapes, and sprinklers. • Know how to use the fire extinguishers and inspect them frequently to verify they are fully charged. • Keep all ignition sources, including cigarettes and open flames, away from propane transfer areas. Never turn on or off any electrical switch in the area of a propane discharge. If power must be turned off to avoid a fire, try turning it off from the circuit breaker in another location not affected by the discharge. • Know the telephone number of the local fire department. • Report any leak or potential fire hazards to your supervisor. Fire Response Information It is important to train your employees what to do if they encounter an uncontrolled Leak or fire. They should remain calm and, if it’s safe, do the following: • If there is an emergency shutdown device, activate it • Immediately eliminate the sources of ignition • Evacuate the immediate area; contact the fire department and do not re-enter until it has been determined safe. Move and stay upwind of a propane leak, fire or vapor cloud. • Shut off the electrical power at the main power source • If the fire involves a propane delivery vehicle on a highway, block off the roadway at least 2,500 feet in both directions from the accident. • Contact their supervisor from a safe location. If they are unsure about what to do in the event of a fire, or if there is any danger of personal injury, do not approach the fire. Evacuate the area and wait for fire fighting personnel to arrive. 24 Fire Extinguishers NFPA 58, the National Liquefied Petroleum Gas Code, requires at least one fire extinguisher easily available at the filling site. It should be at least an 18 lb. dry chemical extinguisher with a B:C rating, and each employee must be trained in the proper use and operation of it. OSHA requires employees to be trained on fire extinguisher use upon initial hiring as well as annually. Fire extinguishers are not intended to put out propane fires and have a limited application area. They are only effective for small fires, such as those involving combustible materials. They are also valuable in providing an escape route for personnel. NFPA 10 requires a monthly visual inspection of all fire extinguishers. This includes checking the extinguisher to be sure it is fully charged and has a tag showing the last annual inspection. If the extinguisher is due for inspection, low on charge, damaged, or even missing an inspection tag, filling operations should be stopped. Notify your supervisor immediately. Leaks and Fires In the event of an uncontrolled leak or fire, if it is safe to do so, remain calm and do the following: • If there is an emergency shutdown device, activate it • Immediately eliminate sources of ignition • Evacuate the immediate area • Contact the fire department and do not re-enter the area until it has been determined to be safe • Move and stay upwind of a propane leak, fire or vapor cloud • Shut off the electrical power at the main power supply • Contact your propane supplier from a safe location It is important to remember that in any propane emergency where there is fire, flames should not be extinguished unless by doing so the fuel supply can be turned off. An explosion hazard is much greater than what the fire hazard could produce. After a fire, do not operate a dispenser that has been exposed to fire until it has been thoroughly inspected and repaired by a qualified technician approved by a propane supplier. Companies may have specific instructions to be followed in both routine and emergency situations. Consult a supervisor for more information. Delivering Propane Safely to End Users This section covers the loading and delivering of propane to end users. The Bobtail Bobtails are basically bulk plants on wheels. They are containers that are filled on site. Bobtail equipment— The bobtail has a DOT cargo tank mounted directly on the chassis behind the cab. The typical bobtail cargo tank has a water capacity of 1,800 to 5,000 gallons. To deliver propane, bobtails are equipped with a pump, a liquid meter that measures the gallons of propane delivered, and special delivery hoses. 25 Filling the bobtail— To fill the bobtail cargo tank, propane is first withdrawn from the bulk storage tanks and then pumped through bulkhead hoses into the bobtail cargo tank. Most propane distribution plants have bobtail filling stations that are separate from transport unloading bulkheads. This ensures that the bobtails are filled quickly and easily. A stationary bulk plant pump is used to fill bobtails in most plants. These pumps have a high flow capacity and can transfer as much as 300 gallons of propane liquid per minute. Some bulk plants also use a liquid meter to keep track of how much propane is loaded each day for bobtail deliveries. Cylinder Delivery Vehicles Cylinder delivery vehicles are specialized straight trucks used for safely transporting cylinders to and from customer installations or retail stores, home improvement centers and convenience stores. Typically, cylinders are received, inspected, filled and prepared for delivery at a cylinder dock at the bulk plant. Cylinder delivery vehicles are usually equipped with cylinder handling dollies and lifting equipment to facilitate safe cylinder handling. Loading a Cargo Tank Motor Vehicle (CTMV) Using a Plant Pump (Detailed) Before the filling operation, the person loading the CTMV (bobtail or transport) should be familiar with the bulk plant layout and operating procedures. These procedures are designed to be as universal as possible, and are to be used as a guide only. They do not replace company policies or federal, state and local codes. Be sure to check company policy and state and local codes before beginning the unloading operation. 1. 2. 3. 4. 5. 6. 7. Prepare for the loading operation Check the liquid level gauges Check to see valves are closed and check hoses Connect the transfer hoses Perform the sniff test Fill the cargo tank Disconnect hoses and prepare the bobtail for travel Step 1: Prepare for the Loading Operation Upon arrival at the bulk plant to load a bobtail: • Check for obstacles that might create an unsafe filling condition. • Check to see that the liquid fill connection on the cargo tank is at least 10ft from the nearest bulk storage container. Always contact a supervisor to determine how to position the bobtail at the bulkhead in a way that maximizes the shearing effect of the hoses and piping in the event of a pull-away. • Set the parking brake and turn off the engine. • Place chock blocks in front of and behind a rear wheel to prevent the vehicle from rolling forward or backward. • Remove any ignition sources within 25ft of the transfer point. Shut down any internal combustion engines within 15ft of the transfer. Cease metal working operations (grinding, welding, brazing, etc.) within 35ft of the point of transfer. Smoking, open flame, portable electrical tools, and extension lights capable of igniting LP-gas shall not be permitted within 25ft of a point of transfer while filling operations are in progress. In addition, metal cutting, grinding, brazing, soldering or welding shall not be permitted within 35ft. of a point of transfer while filling operations are in progress. Step 2: Check the Liquid Level Gauges • Check the liquid level gauges on the bulk plant storage tank to make sure that it has enough liquid propane to fill the cargo tank. If it does not, contact a supervisor or plant manager so they can set up delivery. • Check the liquid level gauges on the cargo tank and record how much propane is in the tank before beginning the load operation. 26 Step 3: Make sure Valves are Closed and Check Hoses Before connecting the hoses to begin loading operations, make certain all appropriate valves are closed and hoses are in good working condition. • Make sure the liquid fill and vapor equalizing valves on the cargo tank are closed. • Remove the dust caps from the valves, inspect them for damage and wear, and if necessary, replace defective gaskets. • Make sure the bulk plant liquid and vapor hose-end valves are closed. • Inspect the transfer hoses, couplings, valves, and connectors, including ACME threads, to make sure they are free of defects or damage. Step 4: Connect the Transfer Hoses To properly connect the liquid transfer and vapor equalizing hoses: • Connect the plant liquid hose to the liquid fill valve on the bobtail cargo tank. Whenever handling the hose, be sure to point the end of the hose away from your body. • Tighten the plant liquid hose into the filler valve of the cargo tank by moving the hose assembly up and down while turning the ACME connector. Once the connection is hand tight, give it an additional quarter turn using a spanner wrench. • Connect the vapor equalizing hose between the storage container and the cargo tank and hand tighten so it doesn’t leak. NOTE: In accordance with company policy, operate the ESVs at the loading bulkhead to be sure they are functioning properly. If they are not operating properly, do not connect the transfer hoses between the storage container and the cargo tank on the bulk delivery vehicle. Step 5: Perform the Sniff Test (Verifying odorization described in Section III) Before filling the cargo tank, your company may require you to perform a sniff test and verify product odorization. To do this: • Vent a small quantity of propane through the vent valve located on the plant liquid hose. • Sniff the area immediately after the liquid vaporizes. • If there is a propane odorant smell, the propane dispenser may proceed with the loading operation. • If there is no propane odorant smell or any unusual smell, the dispenser should not load the cargo tank and should contact a supervisor imm ediately, telling others in the area not to load until approved by the facility manager or supervisor. Step 6: Fill the Cargo Tank During the transfer operation, a qualified person must be in attendance at all times. This means that the propane dispenser must be within 25ft of the cargo tank and have an unobstructed view of it in order to monitor the condition of the transfer operation, and handle any emergencies. To fill the cargo tank: • Insert a ticket in the plant meter and reset the register to zero if applicable. • Check to see that all liquid and vapor equalizing valves are fully open in the transfer piping between the plant storage tanks and the bulkhead. • Open the manual vapor equalizing valve and the manual filling valve on the cargo tank. If a leak is noticed, close all valves, stop the process, and repair any leaks before proceeding. • Start the pump and monitor the liquid level gauges. When the maximum permitted filling level is reached, immediately turn off the plant pump. • Close the plant liquid hose valve and all valves on the cargo tank. Be alert for signs of erratic pump operation during the transfer. If a leak or fire develops during the transfer, close all ESVs immediately and stop the pump, if they can be done safely. Move upwind and away from any uncontrolled release of propane. 27 Step 7: Disconnect Hoses and Prepare Bobtail for Travel When the loading operation is complete, do the following to prepare the bobtail for travel: • Bleed down and disconnect the plant liquid hose from the bobtail liquid fill connection. • Bleed down and disconnect the vapor equalizing hose from the vapor equalizing the connection on the bobtail. • Replace the dust caps on the bobtail liquid fill and vapor equalizing connections. • Replace the dust caps on the plant liquid and vapor hoses and store them as required. • Walk around the bobtail and check for any obstacles that may be in its path. • Remove the chock blocks and stow them in their travel compartment or holders. • Move the vehicle, but only after it has been determined the path is clear and the discharge of propane has dissipated. Loading a Cargo Tank Motor Vehicle (CTMV) Using a Plant Compressor Procedures for filling bobtails are based on practices commonly used in the propane industry, manufacturers’ instructions, and provisions in NFPANFPA 58. Propane dispensers should be familiar with plant layout, including bulk plant equipment, piping functions, and company operating procedures before attempting the filling operation. These procedures are designed to be as universal as possible, and are to be used as a guide only. They do not replace company policies or federal, state and local codes. Be sure to check company policy and state and local codes before beginning the unloading operation. Step 1: • Position the bobtail at the loading bulkhead, with the fill connection on the cargo tank at least 10 feet from the nearest bulk storage container. • Set the vehicle parking brake. • Shut down the engine. • Place chock blocks in front and behind a rear wheel to prevent movement of the vehicle. Step 2: Examine the plant piping and flow control valves. Determine how vapor will move from the bulk storage tank(s) to the suction side of the compressor and on to the cargo tank. Step 3: Set the liquid level gauges on the bobtail. • Before connecting the hoses from the bulk propane storage tank to the bobtail, determine the maximum permitted filling level. This is determined by obtaining the specific gravity of the propane from shipping papers and observing the liquid propane temperature on the thermometer located either in the cargo tank or in the storage container at the plant. • When a storage container is filled by volume, the filling stops when the volume of the liquid maximum permitted volume is indicated by a fixed maximum liquid level gauge. The gauge extends inside the container and measures the level of the liquid. The gauges most often used on bobtails are the fixed maximum liquid level gauge and the variable liquid level gauge. If either the temperature or the specific gravity is not known, the float gauge cannot be used to determine the correct set point and therefore, the maximum permitted filling level of the cargo tank cannot be determined. In that case, the fixed maximum liquid level gauge must be used to determine the maximum filling level. 28 Step 4: Inspect the compressor and check the crankcase oil level in the sight glass, or by using the dipstick Step 5: Connect the liquid fill and compressor vapor hoses to fill the cargo tank. Before connecting the transfer hoses, make sure all sources of ignition within 25 ft of the transfer point are removed. Internal combustion engines within 15 ft of the point of transfer must be shut down while transfer operations are in progress, with exceptions as listed in NFPA 58. Cease metal working operations (grinding, welding, brazing, etc.) within 35 ft of the point of transfer. • Carefully inspect the liquid and vapor transfer hose assemblies. If any defect is found, discontinue the operation, notify a supervisor and do not resume loading until the hose defect has been eliminated. If another loading bulkhead is available, move to it after notifying a supervisor and ensuring that a warning notice is placed on the defective hose. • Check to see that the fill and vapor equalizing valves on the bobtail are closed. Remove the dust covers from the valve connectors. Inspect the valve connectors for damage and wear and if necessary, replace any defective O-ring or flat gasket. • Check to see that the liquid and vapor hose-end valves are closed. In accordance with company policy, operate the emergency shut-down valves (ESVs) at the loading bulkhead to be sure they are functioning properly. CAUTION: If the ESV’s do not operate properly, do not connect the transfer hoses. • Connect the liquid plant hose-end valve to the fill valve on the bobtail. Carry it in the palm of the hand pointed away from the body. Tighten the plant hose-end valve into the filler valve of the bobtail by gently moving the hose-end valve up and down while turning the ACME connector. Once the connector is hand-tight, turn the connector an additional 1/8 to 1/4 turn using a spanner wrench, tapping the handle of the spanner wrench with the palm of a glovedhand. • Slightly open the liquid hose-end valve and check for leakage. If leakage exists, close the hose-end valve and disconnect the ACME adapter after the connection has bled down and is de-pressurized. Examine the condition of the O-ring or flat gasket in the cargo tank filler adapter and replace as needed. • Examine the ACME threads on the hose-end adapter and the bobtail filler connection. If either is excessively worn so the connection leaks with a new O-ring or gasket, replace the worn fitting or adapter before proceeding with the loading operation. • Connect the vapor equalizing hose between the storage container and the bobtail. • Follow the procedures used when connecting the plant liquid transfer hose with the exception of the use of the spanner wrench. Step 6: Sniff test to verify propane odorization . Step 7: Open the vent on the compressor’s liquid trap to verify that liquid is not present in the vapor hose and suction line; it may severely damage the compressor and ultimately produce leaks at the head gasket or oil sump. Step 8: Verify the 4-way valve is in the proper position for loading the bobtail and check all in-line valves and bulk tank valves for their proper open or closed position . Step 9: Check to see that that all shutoff valves are open in the liquid transfer, vapor suction and vapor discharge hoses. 29 Step 10: Start the compressor in accordance with manufacturer’s instructions. • Vapor compressors remove vapor from the receiving tank, compress the vapor to a higher pressure, and move it through piping into the supply tank. The higher pressure vapor in the supply tank forces liquid to move to the receiving tank where the pressure has been reduced by the action of the vapor compressor. Step 11: Verify the proper filling set for the cargo tank, using the thermometer reading and the liquid level gauge index. Step 12: Monitor the cargo tank filling and stop the compressor when the proper liquid level is reached, or if any abnormal operating condition is noticed. Step 13: Close all valves in the transfer hoses. Step 14: Close all valves in both the suction and discharge vapor piping circuits. Close the ESV(s) at the transfer bulkhead and the appropriate liquid and vapor valves in the bulk storage tank(s), if applicable. Step 15: Disconnect the transfer hoses and prepare the bobtail for travel. • Bleed down the gas trapped between the cargo tank filler valve and the transfer hose end valve and disconnect the liquid hose from the Bobtail fill valve. • Bleed down the gas trapped between the vapor return valve and the vapor equaling hose-end valve and disconnect the vapor hose from the vapor equalizing valve on the bobtail. • Replace the dust caps on the fill and vapor equalizing valves. • Replace the dust caps on the liquid and vapor hose-end valves. Store the hoses as required. • If applicable, operate the reset lever on the plant meter so that it stamps the loading ticket. • Fill out any company inventory forms and process them as required. • Before removing the chock blocks, walk around the Bobtail and check for any obstacles that may be in its path. • Move the truck only after it has been determined the path is clear and any discharge of propane has dissipated. • If for any reason the transfer operation is interrupted, or the attendant must leave the area, the compressor must be shutdown and transfer hoses disconnected as outlined in steps (12)-(14). DO NOT leave transfer hoses connected to a Bobtail while unattended by a qualified person. Unloading a Cargo Tank Motor Vehicle Procedures for liquid transfer operations at LP-Gas bulk storage tanks from transports are based on common industry practices, manufacturer’s instructions, and provisions listed in NFPA 582008 and U. S. Department of Transportation (DOT) cargo tank unloading regulations. Furthermore, the major steps in the unloading procedures will vary according to the emergency discharge system used on the CTMV. These procedures are designed to be as universal as possible, and are to be used as a guide only. They do not replace company policies or federal, state and local codes. Be sure to check company policy and state and local codes before beginning the unloading operation. Before performing the unloading operation, you should review bulk plant layout and operating procedures. Make sure you are familiar with the bulk plant equipment, piping functions, and company operating procedures. 30 US Department of Transportation Requirements U.S. DOT requirements for drivers and operators unloading cargo tank motor vehicles (CTMV) are set out in several sections of the Code of Federal Regulations. The principal requirements can be found in the following references: • Unloading Attendance Requirements – 49 CFR 177.834 • CTMV Safety Check – 49 CFR 177.840(m) • Unloading Procedures* – 49 CFR 177.840 (q) • Emergency Discharge Control – 49 CFR 178.337-11, 173.315(n) * for cargo tanks with capacities larger than 3500 water gallons, and cargo tanks in other than metered delivery service US DOT unloading rules include: 1. A qualified person must be in attendance at all times during unloading. 2. A person is ”qualified'' if he or she has been made aware of the nature of the hazardous material which is to be loaded or unloaded, has been instructed on the procedures to be followed in emergencies, is authorized to move the cargo tank, and has the means to do so. 3. The qualified person attending the unloading operation must be alert and remain within 25 feet of the cargo tank when the CTMV internal self closing stop valve is open. 4. The qualified person attending the unloading operation must have an unobstructed view of the cargo tank and delivery hose to the maximum extent practicable, except during short periods when it is necessary to activate controls or monitor the receiving container. New transport cargo tanks placed into service after July 1, 2001, must be equipped with either a passive emergency shutdown system or, if the transport is used in metered delivery service, a remote (radio frequency) shutdown system with a query feature for unloading operations lasting more than 5 minutes. Cargo tanks that are used in both metered and non-metered service must have both types of emergency shutdown systems. Startup 1. Inspect the transfer area, before giving the driver the signal to enter the plant area. 2. Spot the CTMV (most commonly, a “transport”) and guide it into position at the unloading bulkhead. To prevent unnecessary wear on the PTO (power take-off) drive shaft and the pump during unloading, the centerlines of the tractor and trailer should coincide. 3. Set the brakes and turn off all electrical devices. 4. Set the chock blocks at the front and back of one of the tractor drive wheels. 5. If applicable, check with company policy for procedures to follow if a water or ammonia test is required. Operation 1. Determine the maximum amount of LP-Gas to be transferred to the plant storage tanks. In most cases, a transport will arrive only when there is enough room in the plant storage tank(s) for the entire load of LP-Gas. To avoid accidentally overfilling the storage tank(s), calculate the maximum amount of LP-Gas that can be added safely. 2. Review and follow company procedures for checking the operation of the ESVs and pull-a-way protection installed in the plant. If the ESVs will not operate properly, do not continue the transfer operation. Notify the bulk plant’s manager or supervisor. 3. Check the manual shutoff valves on the transport liquid and vapor connections to be sure they are fully closed. Slowly remove the dust caps. 31 4. Remove the dust caps from the connectors on the transfer hoses. Check the connectors to be sure they are clean. Check the O-rings on the valve connectors to be sure they are in good condition. If necessary, clean the connectors with a rag and replace worn, flattened, or damaged O-rings before making connections to be transport. 5. Conduct a visual inspection of delivery hose deployed during each unloading operation. Rejection criteria include exposed reinforcement, permanently deformed wire braid reinforcement, soft spots, bulging, loose outer covering, damaged couplings, and loose/missing/corroded bolts. 6. Connect hoses between the transport and the bulkhead. When using ACME connectors, spin on the connectors until they are hand-tight. While tightening the connectors, move the hose or hose end valve up and down slightly to prevent the threads from seizing. When each connection is hand-tight, tighten it to “wrench tight” with a spanner wrench. Never bang on the connector with the dust cap, a hammer, or other device. 7. Check each connection for leaks by isolating it from the system and charging it with LP- Gas. If any connection leaks, close all valves and retighten the connection. If the leak persists, examine the condition of connection o-rings or gaskets, and replace them if they are defective. Do not transfer liquid if leaking LP-Gas is present. 8. Verify that the LP-Gas being delivered to the bulk plant is odorized by conducting a sniff test or other means, and document the results. 9. When all valves are fully open, start the pump by engaging the PTO. Listen carefully for sounds of erratic pump behavior and check the sight gauge or flow indicator to be sure liquid is flowing through the system. [Note: If an excess-flow valve slugs shut, stop the pump; then, reopen the excess-flow valve by equalizing pressure across the valve before continuing.] 10. Unload the transport tank. Remember that a qualified person must be present during the entire transfer operation to handle emergencies and monitor the condition of the transfer system. Monitor the liquid level gauges in the plant storage tanks carefully during the operation. If possible, equalize pressure between the transport and the plant storage tank. 11. When a tank reaches its maximum permitted filling level, stop the pump and adjust the valves in the plant piping to route the remainder of the load to another tank. Shutdown 1. When the plant storage tank reaches its maximum permitted filling level or the transport tank is empty, stop the pump and immediately close all liquid and vapor lines involved in the transfer operation. 2. Bleed down and disconnect the hoses. Store them away as necessary. Caution: Never disconnect any hose until the LP-Gas trapped in the connection has been safely bled off. This should be done through either the bleeder valve on the hose-end valve or a pipe-away adaptor in the transport or bulkhead connections. 3. Replace all caps on hose-end valves and on transport and plant liquid and vapor connections. 4. Complete the plant unloading form, any necessary accounting forms, and the return bill of lading. 32 5. Check to be sure that all bulkhead or transport hoses have been disconnected and securely stored and that all valves are tightly closed and capped. 6. Before removing the chock blocks, walk around the CTMV and check for any obstacles that may be in its path. When determined to be clear, remove the chock blocks and store them on the vehicle. 7. Move the truck only after it has been determined the path is clear and an discharge of LP-Gas has dissipated. 33 IV. GAS LEAK DETECTION – CONSUMER GAS COMPLAINTS, GAS LEAKS AND SERVICE INTERRUPTIONS This section deals with gas leak detection and handling the consumer service call. Leak and the Smell of Gas Always be sensitive to the slightest gas smell. Learn to recognize the odor of propane gas. It’s a distinctive and unpleasant garbage, sewage or a dead animal smell. Scratch and sniff brochures are available from the NPGA. Warning Signs Below are some warning signs of a gas leak. Always treat the smell of propane, no matter how strong or weak the smell, treat it as a serious gas leak. Note: if there is a gas leak, follow the emergency procedure in this CD / booklet. Examples of warning signs which may indicate a gas leak has occurred are: • When the presence of a foul odor persists • When something smells like garbage, sewage or a dead animal it may be a serious gas leak • A hissing sound near a gas appliance, piping or storage tanks and cylinders Gas Leak and Odor Complaint Reports Adding and properly preserving odorants is very important, because it helps ensure the safe use of propane. Always treat customer odor complaints and gas leak reports as priority service calls and take the necessary steps to fully investigate them because: • A customer complaint about a gas odor may indicate a leak. • A prompt response to a gas leak or odor call can protect both personnel and the public from the hazards caused by escaping gas. Office personnel, delivery personnel, and gas service technicians can effectively and safely respond to gas leak and odor complaint reports by properly applying company policies and procedure. Fielding Gas Leak Calls Most gas leaks are reported by telephone, sometimes making it difficult to determine the amount and concentration of the possible gas leak. Leak Report Forms/Guidelines Leak report forms and guidelines are designed to help propane employees collect and document details from the caller to determine: • The seriousness of the leak. • The source and location of the leak. • Whether to dispatch a service technician. • Appropriate instructions to give the customer. 34 Factors Related to Gas Leaks When a gas leak occurs in a home, the gas is mixed with air infiltrating inside the home through cracks, windows, and doors. Then this mixture is constantly diluted with fresh air. Therefore, small leaks (such as a pilot being out) can exist for a long time without detection. A gas leak may become more serious when there is an insufficient amount of air for dilution or where the leak allows so much gas to escape that the mixture becomes combustible. Responding to the Customer If there is a possible gas leak, instruct the customer to: 1. Evacuate the structure and keep a safe distance from the building. 2. Eliminate all sources of ignition. 3. Conduct further communication with the propane representative from a telephone outside the structure. 4. Once outside the structure and if the service valve for the propane supply can be approached safely, turn off the propane supply. Dispatch a service technician immediately to the scene. NOTE: Remember to apply company policies and procedures when receiving, responding to and documenting a gas odor or leak report. Taking Safety Precautions Since you have no way of knowing the nature of the leak, or how much gas has escaped, you must always use the following basic precautions and rules: • Treat all leak reports as propane gas until proven otherwise. • Assume a detected odor of gas is a combustible mixture and treat it accordingly • Take these precautions to prevent the ignition of the mixture: keep open flames and electric sparks clear of the area; do not turn electrical switches on or off; and do not turn on flashlights before entering an area where a gaseous mixture may exist. Although some flashlights have been specially manufactured to not pose an ignition threat, most flashlights should not be used any time while investigating a potential leak. • Keep everyone, except gas service technicians and emergency responder personnel, clear of the area. Despite safety precautions and training, some individuals choose not to heed warnings and therefore, accidents occur. Investigating Gas Odors The presence of propane in buildings is usually detected first by its odor. This suggests the presence of gas, but does not signify its concentration in air. When conducting a leak and odor investigation, an initial test should be done with a suitable leak detection method. NFPA 54 describes a three-minute leak test using a manometer or equivalent pressure gauge as an example of a suitable leak detection method. Some companies also use electronic sniffers when investigating gas odors. There are various ways to investigate gas odors. Always apply your company’s policies and procedures when selecting a suitable leak detection method. 35 Identifying Leak Sources Exposed Piping After determining the general area of the gas leak, apply a leak solution or use a gas-sensing device at the specific location where a leak is suspected. Buried Piping Sometimes propane will leak from buried piping and enter a customer’s basement or crawl space. Gas can enter into buildings with no propane service and create a hazardous situation. Many factors affect the spread pattern of gas escaping into the soil. To avoid the potential for further entry into buildings, a propane leak detection survey is suggested. Always apply your company’s policies and procedures when identifying leak sources. Gas Service Interruptions and Related Factors Understanding the various reasons for gas service interruptions gas situation. Routine gas service interruptions may occur when: • Cylinders or containers undergo normal maintenance or when they are exchanged or repaired. • Any changes are made to the gas distribution lines. Out-of-gas service interruptions may be caused by: • A gas leak • Increased gas consumption • Incorrect delivery frequency • A will-call account’s failure to schedule a delivery or pay the bill • Customer equipment failure Out-of-gas service interruptions must be considered • Appliances may not have 100% safety shutoff controls • A leak may have developed without the customer’s or gas supplier’s knowledge • Defective appliances may be present or appliances may have been removed without properly capping service lines. • Appliance pilot lights may not be lit. Service interruptions can be more than an inconvenience—they can lead to unsafe conditions if not handled properly. For gas out deliveries, schedule the deliveries for a time when you or another responsible person can be there. The delivery person must be able to get to the appliances to test them and the gas system. The service person is the one who should relight all appliance pilots The delivery person should leave a no one at home notice tag on the tank or door if the consumer is not at home and they are out of gas. The tag tells the consumer to call the propane dealer to arrange for a time for a service person to return and relight the pilots on the appliances. Ventilation Because of the threat of carbon monoxide build up due to an improperly vented appliance, you should inspect customers’ venting systems on a periodic basis. An annual inspection is recommended in the late summer or early fall before the cold days of the high season begin 36 V. EXHIBITS The following exhibits and informational material may be used to promote and better inform propane safe usage at work and home. Also, the National or State Propane Gas Association and the Propane Education and Research Council are excellent sources of safety information and material to support the propane retailer’s consumer customer safety education initiatives. Recommended brochures for consumer handout can be found and purchased on the PERC site http://www.propanecouncil.org/ in their Propane Marketing and Research Catalogue (MaRC). Look under Safety and Training. Log-in is required. For consideration the following consumer safety brochures are available through MaRC: Important Propane Safety Information for You and Your Family Brochure This brochure features important information including steps to take if you smell gas, odor fade, propane gas detectors, carbon monoxide safety, lighting of pilot lights and general appliance maintenance and safety tips. A scratch-and-sniff test is also included. The eight-panel, 3 ¾ x 9 brochure fits in a standard business size envelope and can be used as a self-mailer. It is designed to assist marketers with duty-to-warn compliance. It is also available in Spanish. (125/pack) This brochure contains detailed information on important small cylinder safety issues. Sections include steps to take if you smell gas, transportation and storage of cylinders, tampering with cylinders or outdoor appliances, testing for leaks, odor fade, refilling of cylinders, and disposal of old or damaged cylinders. A scratch-and-sniff test is also included. The eightpanel, 3 ¾ x 9 brochure fits in a standard business size envelope and can be used as a self-mailer. It is designed to assist marketers with duty-to-warn compliance. (125/pack) The PERC Web Site has a number of excellent employee safety tools and training programs available. 37 Below depicts a warning poster or label: 38 Below is a template for a safety information sheet dealing with typical after accident procedures: 34 39 35 40 36 41 Below is a template for an information sheet explaining how to control LP – Gas Leaks and Fires: How To Control LP-Gas Leaks and Fires 37 42 38 43 44 39 Leakage With Fire cont. 40 45 Below is a re-print of the NFPA 704 Hazardous Material Identification System for employee information and training purposes: Prepared by BP 28100 Torch Parkway Warrenville, Il. 60555 WWW.NGL.COM Printed in U.S.A. 24 46 PROPANE Red Blue 1 4 25 47 Yellow 0 Below is a re-print of a technical information bulletin # 34.19-2 dealing with LP Gas Odorant properties for employee information and training purposes: 26 48 27 49 28 50 29 51 30 52 31 53 32 54 55 33 Below are reprints of Odorized Propane and Propane without Odorant (English and Canadian) Material Safety Data Sheets for employee information and training purposes and to make available as needed to customers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d5'\8'40>%6 <1'1% <#9#"9'66F =6$%K$54+(1L$%L&$M OCNY=V0Z =]LV=J=^_0W^CJJC;^=0YCEF JC_0<CSE=0W^CEM0W3V=F CL0`=V_0M3YM0<HN<=NLVCL3HNE/0<CN0O3E!^C<=0LM=0NHVJC^0C3V0CNO0<CSE= ESWWH<CL3HN0WVHJ0^C<a0HW0H]_Y=NF 3NMC^CL3HN0<CSE=E0M=COC<M=E/0O3bb3N=EE/0OVHGE3N=EE0CNO0NCSE=C0CNO0JC_ ^=CO0LH0SN<HNE<3HSEN=EEF <#&7%:70[87R0"%$849?0'I$%&48&>0>%60@%?0:%56'0K5"&60#"0\"#67K87'F =98@8&%7'0%9908>&878#&06#5":'6F00<#&7%8&60>%605&4'"0$"'665"'F00=I7"'@'9?0\9%@@%K9'0>%6F03&0%0\8"'0#" 8\0R'%7'4/0%0$"'665"'08&:"'%6'0[8990#::5"0%&407R'0:#&7%8&'"0@%?0K5"670#"0'I$9#4'F0E8@$9' %6$R?I8%&70C70D'"?0R8>R0:#&:'&7"%78#&6/0:%&0486$9%:'07R'0&#"@%90%8"0%&40:%56'065\\#:%78#&0\"#@ 9%:c0#\0#I?>'&F00a''$0%[%?0\"#@0R'%7/06$%"c60%&40\9%@'F00O#0F$5&:75"'0#"08&:8&'"%7'0:#&7%8&'"F O#0F'&7'"067#"%>'0%"'%60%&40:#&\8&'406$%:'605&9'660%4'd5%7'9?0D'&789%7'4F00O#0FK"'%7R' >%6F00CD#840:#&7%:70[87R06c8&0%&40:9#7R8&>F00S6'0#&9?0[87R0%4'd5%7'0D'&789%78#&F00a''$0:#&7%8&'" 78>R79?0:9#6'40%&406'%9'405&7890"'%4?0\#"056'F >13#$:(1*($5#%+ O'"@%90:#&7%:7F0=?'0:#&7%:7F03&R%9%78#&F 01#$5#&"'(-$"'#-($**$4#: =+$: <#&7%:70[87R0"%$849?0'I$%&48&>0>%60@%?0:%56'0K5"&60#"0\"#67K87'F0G8990:%56'06'"8#5604%@%>'07#07R' '?'6F 0%1234#(5"6$ !"#$%&' R$%:&15 + ,"#$(1*(&::3$ (*e12e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