activities report activities report 2014
Transcription
activities report activities report 2014
ENVIRONMENT AND MATERIALS RESEARCH ASSOCIATION ACTIVITIES REPORT ACTIVITIES REPORT 2014 Activities Report EMRA - 2014 Sommaire Editorial ...................................................... p. 1 Activities .................................................... p. 2 Research & Development ...................... p. 3 Services to companies ............................ p. 16 Studies & tests ........................................... p. 21 Participations ............................................ p. 25 Key figures ................................................. p. 28 Meetings and councils............................ p. 29 Publications & conferences ................... p. 35 Activities Report EMRA - 2014 Editorial 2014 was a year of change in the EMRA landscape. The main changes included the new European Regional Development Fund (ERDF) programming period, the new European framework, the election of a new European Parliament, the double amendment of the decree on support for research, development and innovation in Wallonia, amendments to the General Block Exemption Regulation and the new Community Framework for State Aid for Research and Development and Innovation. Change means adaptation and therefore challenges, some of which were already met in 2014 through effective coordination of action within EMRA. Preparation for the new ERDF programming period, which started within EMRA in 2013, has led to the submission of 54 projects in 20 portfolios, over half of which involve at least one intra-EMRA partnership. The results have just come as the report on these activities goes to press, rewarding the joint effort of the teams of EMRA partners, with over 70% of projects earmarked for an expected success rate of one third on submission in May 2014. The transformation of our unincorporated association into a non-profit organisation, made necessary by the amendment of the decree on support for research, development and innovation in Wallonia in early 2014, has been called into question by the election of a new European Parliament. The public authorities have deemed the added value of this change to be negligible when compared with that of the strong association itself. The important point is to provide better legibility/visibility of the activity of accredited Research Centres, both in Wallonia and internationally. They have therefore decided to promote associations, provided that they make sense and without making it compulsory to formalise them. This change in approach has not dulled the enthusiasm of EMRA partners to move forward together in order to be prepared to face the new challenges awaiting them. The work of research centres is going to have to adapt to the move towards an intelligent strategy of specialisation that favours each centre's efforts having a more immediate impact on economic development, an open-mindedness towards the international scene and in a context of an economy of means. Both the nature of calls for projects (guidance, collective research, etc.) and their scope are undergoing changes, the European dimension having become inescapable. Our teams have already been preparing themselves for some time by stepping up participation in European, transregional and industrial projects (Marshall plan, C-WALITY, ERA-NET, etc.). 252 COLLABORATORS 109 R&D PROJECTS 141 NEW BUSINESSES ASSISTED IN 2014 Of course, there is still work to be done, but that would be our motivation even without major challenges on the horizon! V. LARDOT et T. RANDOUX EMRA Coordinators 1 Activities Report EMRA - 2014 Activities Materials (Bio)polymers Ceramics Electrolytic depositions Geopolymers Refractory materials Nanomaterials Nanocomposites Cement phases Inorganic and hybrid coatings Organic and hybrid coatings Rocks and minerals Glass Processes Reactive extrusion Sintering of inorganic materials Intensification of chemical processes Mineral processing Inorganic materials processing Rapid prototyping Laser technology Thermal treatments Environment Air Biotechnology Energy conversion "Cradle to Cradle" Energy saving Energy efficient processes Quality labelling Energy recovery Recycling inorganic materials Recycling organic materials Soil Biomass valorisation Waste valorisation 2 Activities Report EMRA - 2014 RESEARCH & DEVELOPMENT Materials : From the origin of raw materials to their second life ONGOING PROJECTS Projects BLACKCOATING MICROPACK Innovative materials for super-black lowweight/cost baffles Development of a micro-structured composite material with high barrier properties for food preservation using existing machines A micro-system integration platform fit for PIMI- REMANOS industrial use and capable of solving the majority of problems linked to packaging Partners Industrial, CRPGabriel Lippmann, Luxembourg, Materia Nova Funding ESA Certech, Celabor, Carah Convergence ULg, Sirris, CEWAC, Materia Nova Convergence Production of barrier layers for applications related to food Development of optically active organic components UMONS, Materia Nova, ULB UMONS, Materia Nova, ULB RF - SURFACE Station for profilometry and surface analysis of thin films. UMONS, Materia Nova Convergence SINOPLISS POLYTISS Development of thermoplastics, thermosetting products and composites of renewable origin Materia Nova, ULg, UMONS Convergence Certech, Materia Nova, CTP Convergence INISMa, CSTC, ULg Convergence RF - EVERWALL RF – SMARTFILM TECHNOPOLY T-REXMORECAR CREEPREEF MUNACOR Polymer technology, implementation, formulation, characterisation and recycling Modelling rheological properties of refractory concretes Development of new methods to measure and characterize the creep behavior of refractory materials Update of protection system based on nanofiller paint with a view to reducing the number of layers and providing optimum durability for materials CRIBC, FGF Materia Nova, CoRi, Fraunhofer Institute Convergence Convergence Cornet Cornet SELFREPCOAT Update of protective paints offering self-healing capabilities for paints and metals Materia Nova, CoRi, Fraunhofer Institute Cornet SELECTPERM Food packaging materials with O2 / CO2 selective permeability CBIMO, Certech, Celabor, Fraunhofer IVV & LBF, PTS Cornet Materia Nova, Fraunhofer UMSICHT Cornet ANTIAD Anti-Adhesion Surfaces for High Temperature Applications 3 Activities Report EMRA - 2014 ALTI2DE Alternative coatings to cadmium and hard chromium with potential for second generation developments Materia Nova, CRM Group, Institute Fraunhofer Cornet BIOCOAT Cost-effective biopolymer interior coatings Materia Nova, CoRi, Fraunhofer Institute, IMPIB Cornet NEWGEN New Generation Biomimetic and Customized Implants for Bone Engineering CRIBC and European Laboratories COST ZEROCO Development of clay composites for sustainable construction solutions (ZERO CO2 Emissions) Industrial partnership, INISMa C-WALity HYLIFE Durable materials for Hydrogen-air PEM fuel cell Materia Nova, ULg, ULB, UNamur, INP Grenoble ENERGINSERE UMONS, Materia Nova, Industrial partnership ERA-NET MATERA CRIBC, UNamur, Politecnico di Torino First DoCA PNOXIDES CEROPT FIMCOTEL BYEFOULING Transparent semi-conductor oxides for the perfecting of transparent p-n junctions Transparent polycristalline ceramics for optical applications densified by SPS Manufacture of thin transparent conductive films based on liquid inks Development of new methods for treating marine biofouling Materia Nova, UMONS, Linköpigns University Materia Nova, 19 partners from 11 European countries First DoCA FP7 UNISA, Materia Nova, 8 other partners from 6 European countries FP7 Review and improvement of testing Standards for Refractory products CRIBC, 13 European partners FP7 Self-cleaning, anti-frost and anti-reflective nanocomposites applied, by means of a completely green process, to glass panels for solar energy capture applications UCL, ULg, UNamur, Certech Greenomat Development of lasting production chains for construction materials formed of hemp and flax in northwest Europe. DLO, Materia Nova, Celabor, CREPIM, Inagro, Brunel University, ZonneWinDT, DVL Plant, ITA Interreg IV Research and development of thin layer sol-gel HYBRIPROTECH type coatings for the protection of metallic surfaces and treatment of stone Certech, CRITTMDTS, GEGENA2 Interreg IV IASS RESTAR CLEANOPTIC GROW2BUILD Improving the aircraft safety by self healing structure and protecting nanofillers PRISTIMED Inter-regional partnership in research, innovation and technical support in materials for the medical sector CRIBC, Sirris, UVHC, UPJV Interreg IV PRISTIMAT² Inter-regional partnership in research, innovation and technical support in thermal materials CRIBC, Sirris, UVHC, UPJV, CREPIM Interreg IV 4 Activities Report EMRA - 2014 Certech, ULg, Agro-BIOTECH,CRIT T-MDTS, INRA, VALBIOM,CHANVR ECO Interreg IV Certech, VKC, CREPIM Interreg IV Development of natural vegetable oil-based composites Industrial partnership, Certech, UCL-BSMA, CSTC Plan Marshall Pôle GreenWin Super-insulating window, including ultra-thin vacuum-sealed double glazing in a very high performance thermal frame Industrial partnership, Materia Nova, UMONS, UCL Plan Marshall Pôle GreenWin super hydrophobic powders Industrial partnership, UMONS, Certech Plan Marshall Pôle GreenWin Recycling Applied to Minor Metals and Rare Earths used in new Technologies Industrial partnership, Sirris, CTP, Certech Plan Marshall Pôle GreenWin Recycling and purification of cullet and study of the potential for the recycling of other alternative materials in the flat glass sector Industrial partnership, CTP, ULB Plan Marshall Pôle GreenWin Development of new types of construction materials obtained by carbonation, using industrial fumes and steel slag fractions that are hard to recycle Industrial partnership, CTP, CRR, CSTC, ISSeP, UCL Plan Marshall Pôle Mecatech OLED MIRAGE II Industrial partnership, Materia Nova, UCL, ULg, UNamur Plan Marshall Pôle Mecatech Development of a new treatment for surfaces on pre-painted steel for the external cladding of buildings so that the original look of the building can be preserved over time Industrial partnership, Materia Nova, Sirris Plan Marshall Pôle Mecatech BEETPACK Development of multi-component organicallysourced food packaging Industrial partnership, Materia Nova, UMONS Plan Marshall Pôle Wagralim WAL-AID Promoting competition and durability for the Walloon food industry by creating an interdisciplinary platform of different skills to encourage interaction Industrial partnership, CELABOR, CRA-W, UNamur, Materia Nova, UCL, ULg Plan Marshall Pôle Wagralim UMONS, Materia Nova Programme d’Excellence Materia Nova, UCL Recherche collective POLYCHANVRE Cross-border development of polymer-hemp composite materials RECY-POLYMER The recycling and valorisation of thermoplastics from a cross-border perspective COMPONAT FRENSIS PSH RARETE RECYGLASS CARMAT MIR2OLED DAO OPTI2MAT ANOSTEM APERROUT Materials with specific properties optimised using thin organic coatings and procurement procedures Development of skills in determining anodising coatings Improvement of performances of recycled materials in the road sector by optimising treatment units CRR, CTP, ULg Recherche collective 5 Activities Report EMRA - 2014 OPTHELCO Acquisition of outstanding equipment and the specific skills necessary for implementing a platform for defining electrical, thermal and optical properties suitable for materials in thin films Materia Nova, UCL Recherche collective MATOSOL Evaluation of methods for measuring the soil content of organic materials CRIBC, CRR Recherche prénormative NEW PROJECTS ALTI2DE AlTi2De aims at preparing the second generation of environmentally-compliant coatings for steel components in the aeronautic sector, which is the most demanding in terms of safety and quality management. Thus, the results are a benchmark for other sectors, such as automotive, infrastructure and transporting, provided that the production costs are kept in mind. Strategically, it is proposed to develop technical coatings which have the potential to act as substitutes for both critical coating processes/materials by achieving the appropriate levels of wear and corrosion resistance simultaneously. In order to accomplish these aims, different coating processes and materials will be investigated and combined for optimum results. As Cadmium substitutes, Al and AlMn based coatings, produced by thermal spraying, galvanic deposition, PVD and CVD techniques, will be developed as more environmental solution for Cd in order to provide long lasting corrosion protection to the underlying steel parts. The substitution of hard Cr from Cr(VI) electrolytes on steel components, submitted to wear constraints, will be developed via thermal spraying of carbides embedded in a “green” Co-free matrix, via electrodeposition of Cr from Cr(III) electrolytes and via thin film techniques generating carbides, nitrides and DLC coatings. ANTIAD Corrosion, erosion and caking are wide spread problems in power plants, caused by aggressive flue ashes with corrosive components such as sulfur, chlorine, alkali based low melting point salts. The innovative concept proposed in this research project combines structured (gradient of composition and porosity) thermal sprayed coatings with a covering sol-gel layer to be used in energy power plants. NiCr- and FeCralloys based thermal sprayed coatings including targeted hard materials like Crcarbides will provide a suitable corrosion and erosion protection whereas the thin sol-gel layer combined with the structure of thermal sprayed coatings will reduce the sticking ability of aggressive liquid or liquid/solid flue ashes. 6 Activities Report EMRA - 2014 The combination of porous and rough thermal spray layer with a composite sol gel/particles top layer will result in the formation of a bimodal roughness and an anti-adhesive lotus effect : the roughness at a micrometer range will avoid sticking of large particles and a submicron roughness to avoid sticking of fines. Furthermore erosion at these coatings will not lead to a loss of function. Indeed a rather thick interphase will be created as the sol gel will penetrate the thermal sprayed layer porosity. This will provide a kind of reservoir which will allow maintaining the anti-adhesive properties despite erosion. BIOCOAT Due to the climate change debate and the awareness of the finite nature of fossil fuels, organic polymer materials based on fossil fuels are intended to be increasingly substituted by polymers based on renewable resources. The goal of this project is to check out, in which field of coating application which biopolymers could substitute conventional polymers considering costeffectiveness. Since coatings for interior application (e.g. wall paints) do not have to correspond to the highest performance level, the probability to meet economic as well as functional demands by substituting the polymer basis is best for such paints. Thus this project focuses on the development of some cost-effective biopolymer matrices, which will be used for formulating coatings for different interior applications. These coatings will be characterized and optimized regarding their use-oriented demands considering cost-effectiveness. The project intends to generate prototypical coatings by two work processes. One process aims at the biopolymer material itself, its selection and its modification. The latter implies potentially necessary purifications or fractionations as well as reactions with other reasonably priced compounds. This could result in an applicable biopolymer material meeting the demands of interior coating matrices regarding mechanical and chemical stability, adhesion and compatibility with pigments and additives to be introduced. BLACK-COATING In response to ESA ITT N° AO7739, CRPGabriel Lippmann, Materia Nova and Thales Alenia Space submitted to ESA a joined proposal regarding the developpement of innovative materials for superblack lowweigth/cost baffles. The main EMRA knowledge to the development of the project are : Formulation of sol-gel coatings (water or solvent based) for different applications, background related with the functionalization and dispersion of nanoparticles, formulation of composite sol gel coatings through the incorporation of nanoparticles into a sol-gel matrix for different applications (depending on the type of nanoparticles), techniques related to surface structuration for different applications as photonic surfaces, adhesives, easy-to-clean or self-cleaning surfaces, optical strategy for developing of Black and Super-Black coating. 7 Activities Report EMRA - 2014 HYLIFE SELECTPERM Storage and electrochemical energy restitution is one of best management routes of energy resources. Indeed, in a context of rarefaction of fossil fuels and of renewable energy development, the ability to store electrical energy and return it with strong returns appears as a long-term solution to sustainable development. Among all the types of existing cells, solid polymer electrolyte cells (Proton Exchange Membrane, or PEM) hydrogen / air At present, micro- and nano-perforated plastic films, as well as high-barrier materials, are used to package foodstuffs. None of these materials is optimised for foodstuffs that need to breathe, such as vegetables, fruit and some cheeses. Perforated materials do not allow for selectivity or control of gas exchange, while the modified atmosphere used with highbarrier materials does not account for the breathability of foodstuffs, which are therefore at risk of anoxia. SELECTPERM's goal is to develop packaging with selective O2/CO2 permeability for the packaging of fresh products. are one of the most versatile, and therefore suitable for both mobile and stationary applications. The project is based on previous results obtained in the INNOPEM project. HYLIFE project will adress all elements of the fuel cell. Thus, regarding the catalyst, the focus will be on changing the chemistry / surface crystallinity of the materials and manufacturing core-shell bimetallic catalysts (Co-Pt, basically). Regarding membranes, polystyrene membranes sulfonated highly fluorinated, may have a chemical resistance superior to existing materials. This will be optimized and the deposition method adapted. Finally, the bipolar plates coated steel, research leave the results with PVD coatings (type CrxN) whose resistance to deformation and corrosion after drawing will be a comparison reference. The complementary approach, concerns the steel filing polymeric films (possibly doped conductive nanoparticles) by electro-polymerization. The literature has shown that such an approach is feasible, even if the films deposited by this approach are not yet perfect. The materials used in the project will be biosourced and/or recyclable materials, with a view to developing durable packaging materials: paper coated with selectively permeable film and materials made entirely from polymers (multilayer and polymer blend). 8 Activities Report EMRA - 2014 RESEARCH & DEVELOPMENT Process : From lab scale to pre-industrialisation ONGOING PROJECTS Project RF HAINOLASE Hainaut-based platform dedicated to laser surface treatments RF CLEARZINC Development of a new anticorrosion process to replace galvanising RF - LASESURF Improving the wear properties of materials by laser treatment Partners Funding CRIBC Convergence CoRi, CRM,UMons, INISMa-CRIBC, ULB, Materia Nova Convergence CRIBC, UMons Convergence Materia Nova, ULB, FUSAGx Convergence SINOPLISS BIOTISS Implementation of innovative processes for biomass valorisation and high added value molecule production SINOPLISS EXTRUDISS Reactive extrusion: an environmentally compliant process for biomaterial production Materia Nova Convergence T-REXCERAPIDE Industrial validation of an innovative technology for rapid densification by sintering high added value ceramics and cermet products under a pulsed electrical field CRIBC, CTP, UMons, SIRRIS Convergence T-REXEQUIDER Fast densification Equipement like Spark Plasma Sintering CRIBC Convergence Certech + Industrial partnership C-Wality UMons, CRIBC, UVHC, ICV First DoCA INTENSE4AL Development of an intensive process for lasting continuous production of boehmites with large crystallites ECOPOR Environmentally-friendly manufacturing process for ceramic structures with oriented porosity ABBEADS Development of bactericidal coatings on glass microbeads using low pressure plasma techniques Materia Nova, UMons First DoCA INNOREX Development of new sustainable process for PLA Materia Nova and international partners FP7 CATARR Use of a catalyser for moderating conditions of molecule production Materia Nova, UMons, USTL Interreg IV PRISTIFLEX Inter-regional partnership in research, innovation and technical support for the characterization of coatings by flexible interdigital sensors CRIBC, SIRRIS, UPJV, UMONS Interreg IV University of Belfast, Belfast township, TCBB, SEAI, Ulg, AREBS, CTP, Val+, CUAS, UCL Interreg IV B RENEW REsource Innovation Network for European Waste SPINTRONICS Industrial single pass inkjet printing technology for high added value printed electronics CRIBC + Industrial partnership IWT RECYSTERIL Separation and valorisation of previously decontaminated hospital waste CTP, RECYWALL + Industrial partnership Plan Marshall 9 Activities Report EMRA - 2014 PHOSBIOL2 PHOEBUS EDILCO Production of a second generation of bioethanol from renewable or recycled material by an innovative technology Certech, Ulg, Industrial partnership Plan Marshall Greenwin Development of an optimal energy recovery process of synthetic fuels producted from Solid Waste Industrial partnership, Certech Plan Marshall Mecatech ULB, Materia Nova Programme mobilisateur Greenomat Electrodeposition in ionic liquid medium for connectors SMARTSPRAY Manufacture of low cost electrochrome windows by ultrasonic pyrolyse spray ULg, FUNDP, INISMa Programme mobilisateur Greenomat INNOHU Innovative materials and sensors design for relative humidity monitoring in harsh operative conditions CRIBC + Industrial partnership Programme Recherche d'intérêt général "MANUNET" CYTOFOOD Rapid detection of allergens and chemical contaminants in foodstuffs, by flow cytometry CER, ULg, Certech Recherche collective DEPOLAIR Reduction, in ambient air, of organic pollutants content by catalytic oxidation Certech, UCL Recherche collective FSW-PME Friction-stir welding of high melting point materials of SMES CEWAC, CRIBC, Ulg, Industrial partnership Recherche collective CRIBC, UMons Recherche collective LAMAC Laser machining of unfired ceramics MOULFRIT Manufacture of refractory ceramic molds by additive manufacturing for small series of metals and alloys casting CRIBC, CRM, ULg Recherche collective NoChromeVI Development of an electronic process, alternative to the current hard-chrome plating procedure Materia Nova, CRM, FUNDP Recherche collective INISMa, Certech, UMons Recherche collective INISMa, ULg Recherche collective CRIBC, CRR Recherche prénormative (SPFEconomie/NBN) CRIBC Recherche prénormative (SPFEconomie/NBN) OPTIDRY Optimisation and control of drying of installations in refractory concretes SHAPESPS Direct production, from ceramic and powder metallurgy of "near-net-shape" parts by SPS technology CARACEC CARActerization of the CEC (cation exchange capacity) of soils and clay materials: Development of a simple and robust measurement protocol suitable for any type of soils Tensile resistance determination of refractory materials RESISTRACT by splitting tests (Brazilian Tests) 10 Activities Report EMRA - 2014 NEW PROJECTS CARACEC The aim of this project is to develop a procedure allowing a simple, effective and inexpensive characterization of the clay fraction of the grounds and sedimentary rocks whatever the content and the nature of the clay. A characterization of clay materials is essential both in civil engineering, in the ceramic industry and also in the environmental field. The qualitative and quantitative characteriz ation of clays helps to understand and therefore to provide essential properties such as the potential of shrinkage/swelling, the plasticity and the impermeability. This project targets an easy methodology available for a large number of laboratories adapted to the great variability of the grounds and sediments and whose results would be precise and relevant. Our study will be based on the cation exchange capacity (CEC), a technique reliable with the mineralogical composition and some important properties like the shrinkage/swelling and plasticity of clays according to their humidity amount. In addition to the variability of soils that have to be characterized, the challenge of CARACEC lies in the difficulty of combining the various procedure steps without including any modifications of the CEC by the batch sampling and the sample pretreatments. MOULFRIT Traditionally, processes used to manufacture ceramic molds for metal casting require several and long stages. These processes are therefore unadapted or too expensive for small series or prototyping. This can be a limitation for users, such as SMEs or development units, bound to use only mechanical machining in this field. Additive manufacturing of ceramics enables faster (by the reduction of intermediate stages) but also more complex mold production. This technology could be a real benefit for the ceramic mold production as it gives the possibility to control precisely the mold shape in order to ensure a good mechanical support and to manage thermal tranfers which, if uncontrolled, might generate residual defects in the casting parts. The purpose of this project is to get the best from both processes - metal casting (large choice of casting alloys, saving of material and machining) and additive manufacturing of ceramics (near-net shaping of complex parts, faster than traditional machining) - leading to a positive impact for the environment by saving energy and raw materials. SHAPESPS The SPS technology knows an increasing interest in recent years. It provides an ultra-fast consolidation of ceramic and / or metallic powders by combining pressure and heat treatment by Joule effect (high intensity pulsed current passing through die and punches). The rapidity of the process (average cycle time of 30 min) leads, in most cases, to a maintain of a fine microstructure for a bulk density close to the theoretical density of the materials and to a reduction of the power consumed per unit of produced material, in the order of 60-75%. More powerful equipments with an improved productivity and offering hybrid heating modes are now available to sinter large parts but with relatively simple shapes, limiting the use of this disruptive technology in an industrial environment. 11 Activities Report EMRA - 2014 The SHAPESPS project aims at offering a viable solution for the consolidation by Spark Plasma Sintering of new products (ceramics or materials from the powder metallurgy) presenting complex shapes. The proposed solution to be developed will allow benefiting from the advantages of this technology without any modification of the SPS equipment. The deliverable of the project will be guidelines to the attention of industries allowing a proper selection of the raw materials, the determination of the optimal design for green parts and the assessment of the acceptable degree of complexity in order to obtain, after sintering, an object with the desired dimensions for types of materials that can hardly be sintered in another way than by SPS. Otherwise, a dedicated software will also be developed to optimize the preparation of complex shapes for sintering. tensile test which requires a perfect alignment of all setting load line and a machining of the sample with particular design. Concerning the splitting test, already standardized in the civil engineering sector, is widely used to quantify the tensile strength of concretes in this field. This test is easy to implement and enables a more reliable determination of the tensile strength than bending tests. Therefore this test method could usefully complement the standard framework dedicated to refractory materials. The goal of this pre-standardized project is to establish a robust protocol of splitting test applicable to refractories. The manufacturers could improve their data sheets on mechanical resistances and installers / users could enhance their choice criteria for one material compared to another one in terms of mechanical strength. PHOEBUS RESISTRACT A good knowledge of mechanical properties of refractory materials is necessary to ensure the safety and sustainability of systems submitted to severe and multiple conditions. Currently, the mechanical behavior of these materials is characterized by standardized tests of compression and bending. The weakness of this approach is the determination of the tensile strength through bending tests. During such a test, the stress field is non uniform in the material, so not really representative of that present in a pure tensile test. However, the material destruction is achieved when this material is subjected to a higher stress than its tensile strength. The bending test is widely used because its implementation is easier than those of a pure The transformation of organic ultimate waste (plastics, rubbers, foams , etc.) into synthetic fuels is an area of growing interest in the continuous search for alternative energy solutions. The development of this new business is supported by the creation of industrial production units. The current quality of those synthetic fuels only allows their dilution with crude oil to supply the petrochemical industry. Based on the results generated by the Phoenix project (Marshall Plan), the Phoebus project targets the production of higher quality fuels through an integrated process including a purification step (patented innovation). The improved fuels quality will make them appropriate to be directly injected into co-generation engines specifically modified to optimize the energy consumption (higher net electrical efficiency of about 45%) and to minimize the environmental impact (low emissions). This Phoebus project was submitted to Mecatech competitiveness pole by Comet Traitements SA and Coretec engineering SA in partnership with Certech and ULB. 12 Activities Report EMRA - 2014 RESEARCH&&DEVELOPMENT DEVELOPMENT RESEARCH Environnement : Helping to make the environment a healthier, safer place ONGOING PROJECTS Projets Partenaires Financement Use of materials for REFIOM (Résidus d'Épuration des Fumées d'Incinérateur d'Ordures Ménagères - Residues from domestic waste incineration fume purification) CTP, ULB, CRIBC Convergence REFIOMPurification Establishment of perennial valorisation channels for REFIOM CTP, ULB Convergence SOLINDUS Integrated sustainable solutions for sediments and similar materials CTP, ISSeP, INISMa, (DG02) Convergence VALSOLINDUS Validation and valorisation of integrated and sustainable solutions for sediments and similar materials ISSeP, Carah, CTP, UMons Convergence Sustainable management of cross-border sediment ARMINES, BRGM, INERIS, CTP, ISSeP Development of new AFNOR XP B44-13- compliant materials with photocatalytic activity for air purification Certech MINERVE Characterisation and optimisation of the mineralisation process of buried wastes within engineered landfill sites and uncontrolled dumps, with the aim of reducing the ecological footprint by the valorisation of associated renewable energy (biogas) and residual materials. CTP, UCL, ULg, Industrial partnership Plan Marshall Greenwin CO2Green Synthesis of new bio and CO2-sourced polymers for elaborating isolating materials obtained from CO2 foaming ULg, Materia Nova Programme mobilisateur Greenomat NOSENS Automobile pollution and atmospheric pollutant detection and measurement UMons, Materia Nova, UCL Programme mobilisateur Greenomat Design and sizing of a bi-layer planted filter for nitrogen reduction Cebedeau, UCL, CTP, IRSTEA Recherche collective Development of a technique for solidifying and stabilising soils contaminated with both heavy metals and organic pollutants CTP, UCL, ISSeP Recherche collective Development of a platform for quantification of bio-sourced carbon Materia Nova, UCL, Celabor Recherche collective Sensors for measuring the VOC polluted indoor air UMONS, UCL, Materia Nova, Certech WBGreen Use of REFIOM Materials GEDSET NORMACAT FILTRA-N MODES PLACBIO CAPTINDOOR Interreg IV Labélisé par le Cluster AXELERA 13 Activities Report EMRA - 2014 VALAVAL WATERPOP Development of a technology for stabilising and solidifying soils severely contaminated by heavy metals, a technology originally based on the joint use of a hydraulic binder and a geopolymer ULg, CTP Photodegradation of persistent organic pollutants in natural water or urban waste water treated by traditional UMONS, Certech processes. WBGreen WB-Health NEW PROJECTS CAPTINDOOR FILTRA-N The aim of the project is the VOCs detection – particularly formaldehyde and acetaldehyde – in order to quantify indoor air quality. In this context, the partners will elaborate microsensors for measuring those pollutants, which could help to make arrangements in order to limit passive exposure (choice of building materials) or active exposure (ventilation, filtration systems installation). The sensor should give both an optical and electrical response. The transduction method will be based on using a periodic array of out-of-plane metallic microcantilevers. This method is inspired from the microblind® system developed by the National Research Council of Canada and used for producing opaque or transparent windows at will. The micro-beams are covered by a sensible coating whose volume or weight can be changed by gases adsorption or absorption: their curvature can be therefore modified and by the same, their spacing from the substrate. Wastewater treatment companies are increasingly often choosing cleaning technologie called “extensive” (natural treatments without mechanical intervention) instead of “intensive” technologies. The choice of these «extensive» technologies allows reducing investment and operating costs. Moreover, it is robust and easy to operate technologies. Vertical and horizontal flow reed bed filters occupy an important position in the market for "extensive" processes. The vertical flow reed bed filter is singularly known for nitrification performance while the horizontal flow filter is distinguished by its ability to denitrificate. Studies regarding combination of these two filters (such as serial connection with/without internal recirculation, etc.) have been conducted. 14 Activities Report EMRA - 2014 The FILTRA-N project’s goals are to design and validate a filter consisting of a superposition of a vertical flow reed bed filter above a horizontal flow filter (reducing the floor space required in comparison to other configurations) and having good purification performances (in accordance with directive 91/271 to <10 000 per capita). WATERPOP The project targets the improvement of the water quality during or at the end of purification treatments, by the implementation of an advanced oxidation process. It is part of an environmental and public health policy for the abatement of persistent organic micropollutants having a known "endocrine disrupters" effect. The process is based on the mineralization of traces of organic micropollutants such as pesticides (groundwater) or active pharmaceutical ingredients (surface water) and uses the photocatalytic properties of TiO2 (anatase). This approach should allow the degradation of (a)polar molecules resistant to conventional wastewater treatments with activated carbon for example, or requiring the use of nanofiltration, expensive and energy intensive. 15 Activities Report EMRA - 2014 SERVICES FOR BUSINESSES EMRA assists companies in developing and promoting technological innovation. Concrete solutions, in-depth assistance and technical advice are provided by teams with recognised skills and knowledge. Technological platforms are also made available to companies. The EMRA teams are the first points of contact for firms wishing to improve their processes or develop new products. Business assistance projects include feasibility studies, support and collaboration on research projects, the transfer of technologies or new processes, help with writing up new specifications etc. In 2014, a patent for a technology for laser machining unfired ceramics (PCT/EP2012/060261) was transferred to operations in Wallonia. The provided services consist of technological audit of problems associated with processes or products, and guidance on obtaining technological skills. This guidance is supported by technology forecasting, which enables experts to stay permanently up to date on the scientific and technical progress made within their fields which present a high potential for industrial innovation. The working group specifically formed to help businesses is tasked with promoting collaboration synergies. Joint participation in certain trade shows and joint meetings with manufacturers have made it possible to offer a broader range of resources and services in EMRA's three areas of expertise. Since 2010, 1076 businesses have received support, including 138 from at least two EMRA partner centres. Half of these businesses are very small enterprises or SMEs. One hundred and fortyone new businesses received support with their innovation process in 2014. Distribution of requests: 47 % Materials 19 % Process 34 % Environment In 2014, 20 business guidance and recognition projects were supported by public funds (guidance funded by the Walloon Region, FPS Economy of Belgium and ERDF). These projects cover EMRA’s three areas of activity (Materials, Processes and the Environment). 16 Activities Report EMRA - 2014 BUSINESS GUIDANCE AND VALORISATION PROJECTS PROJECT AVATAR BIOMEDHELP GUIDEMB IMMUNOHELP AdVanced Assembling Technologies and Additive manufactuRing Support in the development of diagnosis and quality control for the biomedical sector Provision of expertise in the food packaging sector, covering aspects of barrier materials, implementation and transformation processes, and methods for improving foodstuff preservation Immunochemical guidance service focussing on the production of polyclonal antibodies, the characterization and the purification of antibodies and ELISA kit MATECDUR Sustainable Technical Materials REVETACT Guidance on active coatings SOLESITE SUREMAT Technical support for entities treating polluted sites and soil in Wallonia Guidance on surface treatments and multi-purpose coatings TETREF-O-R Technologies for water and air treatment in an industrial environment VALODECH Valorisation of industrial waste VALOWALL Recycling of industrial waste and reclamation of contaminated lands and sites in Wallonia MICROPACK Transfert de Technologie Barrier materials for food packaging REFIOM (Valorisation) SINOPLISS VALORISS SOLINDUS (valorisation) TECHNOPOLY (promotion) T-REX PROM RF - VALOMAT 2014 Ceramics and Glass Standards Department 2014 Nanomaterials Standards Department Establishment of continual valorisation systems for residues from domestic waste incineration fume purification (REFIOM) To reinforce the integrated and structuring effect of the SINOPLISS project portfolio Integrated and sustainable solutions for sediments and similar materials (valorisation section) Polymer technology, implementation, formulation, characterization and recycling Promotion of available technological services as part of the T REX and Functional Coatings portfolios To reinforce the integrated and structuring effect of the FUNCTIONAL COATINGS project portfolio Promoting and raising awareness of standards and technical rules Awareness of SME in terms of standards and using those standards PÄRTNERS Sirris, CRIBC, IBS, CEWAC CER, Certech, ImmuneHealth FUNDING Guidance RW Guidance RW Certech, Celabor Guidance RW Certech, CER Guidance RW CRIBC, Celabor, Centexbel, CTP, Certech, INISMa, Materia Nova CRM, CoRI, Materia Nova CTP, Celabor CRM, Materia Nova, CoRi, CSTC, CTIB Cebedeau, CEWAC, Celabor, Certech, CTP RECYWALL, CRR, CTP Recywall, CRIBC, CELABOR, Certech, CRIC, CRR, CRM, CSTC, CTP, INISMa Guidance RW Guidance RW Guidance RW Guidance RW Guidance RW Guidance RW Guidance RW Certech, Celabor, Carah Convergence CTP, CRIBC Convergence Materia Nova Convergence CTP, ISSeP, INISMa, (DG02) Certech, CTP, MateriaNova Convergence Convergence INISMa, CRIBC Convergence Materia Nova Convergence CRIBC NBN/SPF Economie SIRRIS, CRIBC NBN/SPF Economie 17 Activities Report EMRA - 2014 EMRA’S PARTICIPATION IN TECHNICAL STANDARDISATION COMMITTEES This know-how is supported by the participation of national, European, and international technical standards committees. The expertise of EMRA members is also based on research activities which enable them to become involved in pre-normative projects and technical committees dealing with subject areas such as the environment, geotechnology, wall and floor coverings, roadway hydrocarbons, refractories and more. EMRA members help industry professionals to : Understand the aspects linked with technical and scientific standardisation and regulations Stay up to date with methods and trends in standardisation and regulations in the relevant sectors Implement the standards in their daily activities National level (Belgique) E067 Ceramic Tiles E129 Glass in Building National level (France) AFNOR B44/A VOC and odors, photocatalytic materials, chamber recycling test European level CEN/TC 129 Glass in Building CEN/TC 184 Advanced technical ceramics CEN/TC 187 Refractory products and materials CEN/TC 264 Air quality CEN/TC 351 Construction products: Assessment of release of dangerous substances CEN/TC 352 Nanotechnologies CEN/TC 386 Photocatalyse International level ISO/TC 33 Refractories ISO/TC 63 Glass containers ISO/TC 146 Air quality ISO/TC 166 Ceramic ware, glass ware and glass ceramic ware in contact with food ISO/TC 206 Fine ceramics ISO/TC 229 Nanotechnologies 18 Activities Report EMRA - 2014 FINANCIAL SUPPORTS FOR BUSINESSES Technology cheques : Technology cheques Available since 1st January 2009, the Technology Cheque is a financial assistance tool for SMEs seeking technological expertise on a specific topic. This assistance may be in relation to any of the following: preliminary testing, calculations and analysis, carrying out all or part of the design and/or adaptation of products, processes or services, or the resolution of technical problems related to the quality and compliance of newlydeveloped products, processes and services. In 2014, for EMRA… 571 technology cheques 35 companies involved What you need to know Who can benefit from them? Any SME established as a trading company which has its headquarters located in Wallonia. Who pays and how much? Each Technology Cheque has a face value of EUR 500 (up to a maximum of EUR 20,000 per year). The company only has to pay 25% of its value. The remaining 75% is covered by the Walloon Region and ERDF. What can the cheques be used for? Technology Cheques can be used to pay for services provided by approved Research Centres or those attached to a higher school in the French-speaking Community of Belgium. Who organises it all? The AEI (Agency for businesses and innovation) through its website: www.innovons.be Technical Feasability Innovation financial aid mechanism for SMEs Designed to help SMEs to develop their ideas, the technical feasibility projects supported by the Walloon Region, are generally carried out prior to the development of a product or service. This assistance enables companies to use external research organisations to carry out technical services. EMRA supports SMEs in submitting projects. The notification of the Walloon authorities is given within the 3 months following the submission of the application. In 2014, 14 research and innovation projects were carried out by EMRA in order to assist SMEs in their preliminary steps in industrial research and the experimental development of new products or processes. Research tax credit (France) In the European era, the EMRA members cannot allow their activities to be limited to just Belgian territory. It is in this spirit that they requested and obtained French research tax credit approval for all of their activities. 19 Activities Report EMRA - 2014 LABELS & STANDARDISATION ISO (The International Organization for Standardization) is the world's largest developer of voluntary international standards. EMRA is participating in work on TC206 and TC063. www.iso.org CEN : European Committee for Standardisation Through these services, it provides a platform for the development of European standards and other technical specifications. EMRA is present and active on TC129, 184, 187, 264, 352 & 386. www.cen.eu CE : The "CE" mark indicates a product's conformity with European Community requirements for manufacturers. The "Glass and Components" department is the recognised body for marking (Id.No.1174) according to article 18 of the Construction Products Directive CPD 89/106/EEC Benor "Compliance label" for construction products in Belgium. Belgian Union for Technical Approval of Construction: The UBA is the technical approvals institution for construction materials, products, and systems and for installers in Belgium. The "Glass and Components" department is a subcontracted laboratory for UBAtc for the windows for buildings sector. BQA : Belgian Quality Association System and environment certification body accredited by BELAC. EMRA provided this association with the sector's leading auditors for carrying out quality (ISO 9000) and environmental (ISO 14001 and EMAS) audits. http://www.bqa.be AIB - Vinçotte EMRA is approved by AIB-Vinçotte for OK-compost quality labelling. http://www.okcompost.be The "Glass and Components" department is a sub-contracted laboratory for AIB Vinçotte International for the car windscreen sector. AMECA : Automotive Manufacturers Equipment Compliance Agency Inc. (USA) The "Glass and Components" department is an AMECA accreditation laboratory for car windscreen approval tests. 20 Activities Report EMRA - 2014 STUDIES & TESTS EMRA carries out tests, analysis and expert reports on work in various fields, using experienced teams with state-of-the-art laboratories and a stock of high-performance equipment. Efficient coordination of the various departments enables them to maintain and develop an essential asset for their work in industry: the capacity to offer a comprehensive solution to their needs or isolated problems. MATERIALS Synthesis, formulation, transformation, application, production and recycling, characterization (Bio)polymers and nanocomposites : performance and environmental impact improvements, controlled structures, lightweight materials production, use of bio-sourced products, fillers compatibilization, properties (fine)tuning, reactive extrusion. Organic electronics : fabrication and characterization of optoelectronic devices (organic LEDs, organic solar cells, transparent electrodes). Measurement of the electrical conductivity by local probe microscopy. Modelling: ab initio and semiempirical methods, molecular modelling. Electrolytic coatings : anodic oxidation (conversion) on aluminum and titanium, surface preparation (degreasing, polishing), metal coatings (hard chromium, nickel, and silver plating), alternative to the toxic ionic liquid baths for electroplating (cyanide bath), substitution of hard chromium VI. Ceramics and ceramic-metal composites : development, simulation and characterization for domestic, building and technical applications or using their functional properties (piezoelectricity, thermoelectricity,...). Organic, inorganic and hybrid coatings : sol-gel, laser cladding, plasma technologies for the protection or the functionalization of surfaces on a wide range of materials. Improvement of optical, thermal, mechanical, electrical, antibacterial, antiadhesion and selfcleaning properties, improvement of corrosion resistance, improvement of barrier properties, adhesion and biocompatible layers,... Geopolymers : formulation, use of industrial byproducts, performance improvement, sustainability measurement. Cementitious phases : chemistry, formulation and application of cements, rheology. 21 Activities Report EMRA - 2014 superhydrophobic powders. ceramics and composites. Nanostructured Rocks and minerals : identification, physical, chemical and mineralogical characterizations, microscopic studies, mineral processing (separation, concentration, stabilization, passivation and activation, hydrometallurgy,...). Refractory materials : development and characterization of shaped or unshaped (concrete, mortar,...) refractory materials. Industrial linings: casting optimization, aging/wear monitoring, post-mortem diagnosis, reverse-engineering, repair techniques, improvement of reactors. Glass : development (color, brightness,...), raw materials and final products characterizations (photoenergetical properties, coated glass durability, defect analysis,...), process improvements. Assessment tests for insulating and safety glass, laminated and tempered glass. Nanomaterials : chemistry of oxides with high specific surface (SiO2, zeolites, TiO2,...), ENVIRONMENT Towards sustainable development Air quality : diagnostic, risk assessment and remediation (environmental air pollution at emission and immission, industrial fumes, diffused sources,...), workplace exposure, ambient air, confined space. Chemical, sensorial , biological, particules analysis. Energy conversion : low temperature conversion of waste by catalytic pyrolysis into liquid hydrocarbons and recoverable byproducts, development of materials with thermoelectric properties or piezoelectric actuators. Soil characterization and treatment : monitoring and analysis of groundwater, geotechnical characterization (probing, drilling, soil strength measurements,...), environmental audits. Chemical, physical or physicochemical soil treatments (decontamination, stabilization of pollutants ...). Biotechnology : substitution of chemical processes by biotechnological processes. Fermentation, analysis and genetic modification of stems, proteomics, down-stream processing and purification. Extraction of molecules, bacterial and fungal biopolymers. Immobilization of enzymes. Antimicrobial and antifungal tests (ISO certified and screening tests). Energetic efficiency of processes : diagnosis, analysis and modelling of industrial facilities. Storage and production equipments and processes (fuel cells, biomass, bio-refinery, CO2 capture,...). Materials efficiency : high performance materials (eco-efficiency, lightweight, recycling,...). Energy recovery and conversion 22 Activities Report EMRA - 2014 (thermoelectric materials, heat exchangers, phase change materials, heat vectors, materials with anisotropic thermal conductivity). Labelling : construction products labelling for emission of volatile organic compounds. Tests of air purifying equipments and materials. Labels associated with biodegradable plastics (OK compost). CE marking for glazing and BENOR marking for stoneware pipes. Recycling of materials : grinding, separation, decontamination / purification, formulation and processing. Evaluation of recycled materials properties. Energy recovery and materials in compliance with environmental legislation. Biomass valorisation : transformation of byproducts or waste into bio-sourced and high added value molecules. Solvolysis technologies (high temperature and pressure chemical "cracking") and biotechnological transformations. Waste recovery : characterization of new minings and recoverable materials. Development of treatment and recovery technologies for strategic metals, development of recovery processes of new raw materials (NRM). Cradle to cradle : analysis of potential C2C product development, assessment of components toxicity and recycling processes, life cycle analysis (LCA). PROCESS From laboratory scale to pilot plan Reactive extrusion : development of new environment-friendly materials (solvent-free, low reaction volume) and performance improvement (functionalization, grafting, copolymerization, chemical modification, active fillers or functional additive incorporation,...). Sintering of inorganic materials : optimization of drying, de-binding, sintering and post-treatment (annealing) cycles. Natural or under controlled atmosphere sintering, uniaxial or isostatic hot pressing and SPS (Spark Plasma Sintering), posthiping. Selective laser sintering and laser cladding. Chemical processes intensification : development of continuous chemical processes through smaller, faster, cleaner and energyefficient technologies. Organic and inorganic synthesis (from gram to kg scale), catalysis, high throughput experimentation with automated synthesis stations. Mineral processing : development of schemes for the treatment of ores and industrial minerals (crushing, grinding, classification, hydrometallurgy, concentration, separation, heat treatment,...). Development of schemes for the treatment and recovery of secondary raw materials and industrial by-products. Design and construction of treatment pilot plants. 23 Activities Report EMRA - 2014 polymers, composites. Development of functional layers and components (decorative marking, traceability ...). Laser machining of ceramics. Shaping of inorganic materials : formulation and processing (grinding, mixing, granulation) of powders, suspensions or pastes (traditional and advanced ceramics, refractory materials, glass). Shaping by casting, pressing, extrusion, melting, rapid prototyping, machining and coating techniques. Plastic materials processing : pilot testing equipments for the industrial process simulation: drying, mixing, pelletizing, compounding, extrusion, co-extrusion, physical or chemical foaming, blow molding, injection molding. Laser technologies : "additive" (by adding material) and "subtractive" (ablation of material) processes on ceramics, glass, metals, organic Heat treatment : optimization of drying and/or calcination parameters and upscaling. Materials synthesis from raw and secondary matter. Development of thermochemical processes. Cold plasma technologies : high vacuum technology (PVD, PECVD, PCVD), plasma microwave (activation of stable molecules, metal coatings, plasma polymerization, grafting of chemical functions). 24 Activities Report EMRA - 2014 WE PARTICIPATE IN Organisms www.accord-wallonie.be www.bcers.be www.ecers.org www.beswa.be www.cd2e.com index.aspxindex.aspx www.efce.info www.gis3sp.fr www.vloot.be www.sf2m.asso.fr www.gbee.be www.impc2014.org www.lasim.org www.centexbel.be/ucrc/ www.gfec.net/ www.gfp.asso.fr/ www.vom.be/ www.suschem.org/ http://mr.gnmeba.free.fr www.src.be/ www.gis-surfaces.be/ www.belgianpolymergroup.be www.uwe.be www.essenscia.be 25 Activities Report EMRA - 2014 Clusters http://clusters.wallonie.be http://clusters.wallonie.be http://clusters.wallonie.be http://clusters.wallonie.be Centres of competitive excellence www.greenwin.be www.biowin.org/biowin/fr/5408home.html www.wagralim.be/ www.polemecatech.be www.skywin.be www.iar-pole.com www.up-tex.fr/ www.plastipolis.fr/ www.team2.fr www.matikem.com 26 Activities Report EMRA - 2014 WE ARE STAKEHOLDERS IN ACENIS SCRL Sole point of contact for meeting needs related to the characterisation of soil and subsoil contamination (including underground water) and the remediation to be applied. http://www.acenis.be LABOMOSAN SA Labomosan carries out the majority of tests, either in the laboratory or on site, needed before, during and after production to ensure that all building, civil engineering structures and road construction projects are carried out properly or under its control. Labotour SA The specialist in characterisation of road and construction products. http://www.labotour.com/ Lasedesign SA Specialist in enamel laser sintering for the purpose of marking, personalising or functionalising objects and substrates of any kind. http://www.lase-design.be/ Mineral X Real estate company with a view to expanding the CTP's real estate. NaNo4 Company working in the synthesis of organic nanocomposites to order. VALORE Company working in the production and marketing of formulated speciality products. RECYWALL Economic interest group. The purpose of this group, both in Belgium and abroad, is to carry out any operation relating to the research, study and execution of projects in the field of waste, recycling and recovery, as well as the use of matter or materials, without limits as to the technologies used. IONICS Société active dans le domaine des revêtements de surface (électrochimie, sol-gel ou plasmas), Ionics est un levier pour accélérer le transfert technologique. www.ionics.be 27 Activities Report EMRA - 2014 KEY FIGURES 2014 RESULTS (k€) Products Charges 2011 2012 2013 2014 Customer invoicing and subscriptions 12.108 11.905 11.858 10.881 Operating grants 9.360 9.302 9.532 9.746 Other products 1.636 1.829 2.133 2.001 TOTAL 23.104 23.036 23.522 22.628 Purchases and Services 5.437 5.367 5.258 4.866 Payroll 15.469 15.791 16.041 15.270 Depreciation of Share Capital and provisions 951 1.140 1.464 1.358 Other charges 197 166 234 621 22.054 22.464 22.996 22.115 1.050 572 526 513 3.115 1.647 1.523 1.334 0.54 0.58 0.56 0.56 TOTAL Résults Investments Investment grants (equipment and buildings) Autofinancement R Coefficient* * The R coefficient, as defined by the Public Service of Wallonia's Directorate-General for the Economy, Employment and Research (SPW-DGO6), shows that EMRA fulfils the criterion for accreditation in Wallonia with regard to its self-funding capacity. 23.036 11.905 2012 23.522 11.858 2013 22.628 10.881 Chiffre d'Affaires (k€) Turnover Contrats industriels Industrial Contracts (k€) 2014 28 Activities Report EMRA - 2014 MEETINGS & COUNCILS Certech Industrials Macq Benoit Bailly Christian Pardoen Thomas Gaigneaux Eric Schneider Yves-Jacques Burteau Nathalie Ministre d’état Busquin Philippe Comet Traitements Bareel Pierre-François x Umicore Scoyer Jean x Veolia Benanou David x Nanocyl Massin Francis x Solvay Marechal Gisèle x Private investor, Consultant Degroof Jean-Jacques x BMF Consult Beguin Michel x Grando Charlier Yves x Guest Randoux Thierry Managing Director Service Public de Wallonie DGO6 Villers Pierre Observer Sopartec Durieux Philippe Chairman Board meeting General assembly UCL 29 Activities Report EMRA - 2014 NGK Ceramics Europe Wauters André NGK Ceramics Europe Rennotte Jacques Lebailly De Bruycker Daniel Neoceram Lemaire Michel UMons Conti Calogero Wienerberger – Division Tuileries du Hainaut Willain Bernard Eeckman Jean-Pierre Honorary Chairman Cambier Francis Managing Director Guests Chairman Board meeting General assembly INS Ceramag Steinzeug - Keramo NV Megaceram Wienerberger - Division Aalbeke The Directors of EMRA partners are invited to participate in the respective boards of directors/general meetings of the other EMRA members. 30 Activities Report EMRA - 2014 CRIBC Industrials Wauters André FGTB De Nooze Alain SPF Economie, PME, Classes Moyennes Collette Renaud Neoceram Lemaire Michel x NGK Ceramics Europe Rennotte Jacques x Wienerberger - Division Tuileries du Hainaut Willain Bernard x Cambier Francis Managing Director Eeckman Jean-Pierre Honorary Chairman Wienerberger Chambart Hilde x NGK Ceramics Europe Dewitte Carine x Lebailly SA Flament Pierre Service Public de Wallonie DGO6 Gillin Alain UMONS Gonon Maurice Lebailly Jonniaux Henri x Steinzeug - Keramo Venken Heidi x FGTB Hilami Brahim UVHC-LMCPA Leriche Anne Wienerberger - Division Aalbeke Maertens Michael IWT - Vlaams Gewest Otte Dirk Vesuvius Belgium Schaubroeck Lieve x Wienerberger Van der Biest Johan x KULeuven Van der Biest Omer Usines & Carrières Ernest Lebailly SA Lebailly Jean x NGK Ceramics Europe Veys Jean-Noël x CSC Mons-La Louvière Zara Rico General meeting Guests Chairman x Permanent Committee NGK Ceramics Europe Co-opted Co-opted x Co-opted The Directors of EMRA partners are invited to participate in the respective boards of directors/general meetings of the other EMRA members. 31 Activities Report EMRA - 2014 INISMa NGK Ceramics Europe Rennotte Jacques Chairman x NGK Ceramics Europe/INS Wauters André Vice Chairman x UMons Conti Calogero FIV de Clippele Guy IDEA Dessily Daniel UMons Lazzaroni Roberto Neoceram Lemaire Michel UMons Olivier Marjorie UMons Snyders Rony AGC Glass Europe Van den Neste Marc Wienerberger - Division Willain Tuileries du Hainaut Service Public de Wallonie Gillin DGO6 Co-opted x x Co-opted Bernard x x Alain Observer Cambier Francis Managing Director UMons Damman Pascal FGTB /IDEA De Nooze Alain UMons Dehombreux Pierre UMons/FPMs Delaunois Fabienne UMons Dubois Philippe IDEA Sakas Achille Guest Board meeting General assembly Industrials The Directors of EMRA partners are invited to participate in the respective boards of directors/general meetings of the other EMRA members. 32 Activities Report EMRA - 2014 CTP Industrials UCL ALC Pierre Mercier Daniel Thimus Jean-François Chairman Bodson Michel Secretary/Treasurer Lorant Régis x Polet Jean-Pierre x Dupont Laurent x Luyten Philippe x Vandewattyne Pierre Boucher Serge ULB Degrez Marc Neirynck Stéphane Managing Director Villers Pierre Observer Duquesne Xavier Laduron Dominique Lucion Christian Thimus Jean-François Mercier Daniel Dumortier Armel Delbar Gonzague Luyten Philippe Seynhaeve Frédéric IDETA Vandewattyne Pierre ALC UMons Couëlle Bruno Busquin Philippe Calozet Michel Bodson Michel Polet Jean-Pierre Boucher Serge x Vice- Chairman UMons Guest Service Public de Wallonie – DGO6 UCL General assembly x Board meeting IDETA Germain Chairman Vice- Chairman Secretary/Treasurer ULB Roggeman Yves The Directors of EMRA partners are invited to participate in the respective boards of directors/general meetings of the other EMRA members. 33 Activities Report EMRA - 2014 MateriaNova Thales Alenia Space Belgium Bekemans Marc x Vandeputte Oleochemicals Deherrripon Cédric x Solvay Goldberg Anne x Galactic Bogaert JeanChristophe x UMons Conti Calogero Dehombreux Pierre Dubois Philippe Coulon Michel IMBC Belle JeanSebastien Politique Scientifique Fédérale Mettens Philippe ULB Di Stefano Patrick Ionics Beguin Michel x Cosucra Groupe Warcoing Crahay Jacques x AGC Flat Glass Europe Van Den Neste Marc x UCB Denis Laurence x Langer Luc Villers Pierre ULB Roggeman Yves Idea Dessilly Daniel Igretec Debois Marc Hoccinvest Pattyn Dominique UMons Delaunois Fabienne UMons Olivier Marjorie Ideta Vandewattyne Pierre Guest Service Public de Wallonie DGO6 Chairman Board meeting General assembly Industrials Vice-Chairman Observer The Directors of EMRA partners are invited to participate in the respective boards of directors/general meetings of the other EMRA members. 34 Activities Report EMRA - 2014 PUBLICATIONS A Detailed Description of the Chemistry of Thiol-based Plasma Polymer Films, D. Thiry, R. Francq, D. Cossement, M. Guillaume, J. Cornil, and R. Snyders, Plasma Processes and Polymers, vol.11, pp.606-615 (2014) Are bioplastics « green » plastics?, O. Talon , Environmental Impact of polymers, Ed. T. Hamaide, R. Deterre, J.F. Feller, John Wiley & Sons (2014) Assessing the Suitability of a Green Solvent for GPC and TREF Analyses of Polyethylene, A Boborodea, A. Luciani, LC GC Europe, vol.27 (2014), pp.621-623 Assessing the Suitability of a Green Solvent for GPC and TREF Analyses of Polyethylene, A. Boborodea, A. Luciani, LC GC North America, vol.32, n° 5, pp.364–367 (2014) Bronsted acids in ionic liquids: how acidity depends on liquid structure, J.A. McCune, P. He, M. Petkovic, F. Coleman, J. Estager, J.D. Holbrey, K.R. Seddon, M. Swadzba-Kwasny, PCCP , vol.16(42), pp.2323323243 (2014) CHAPTER 1 : Bio-based Polymers and Materials, N. Berezina, S.M. Martelli, Renewable Resources for Biorefineries, ISBN:978-1-78262-018-1, p.46753 (2014) Characterization of the compressive creep behaviour of clay refractory materials, according to EN 993-9 and ISO 3187 standards. Development of a viscoelastic model, P. Pascal, V. Lardot, F. Cambier, Proc. 57th International Refractory Colloquium in Aachen; 24-25 september 2014 Combining Mass Spectrometry Diagnostic and Density Functional Theory Calculations for a Better Understanding of the Plasma Polymerization of Ethyl Lactate, S. Ligot, M. Guillaume, P. Gerbaux D. Thiry, F. Renaux, J. Cornil, Ph. Dubois and R. Snyders, Journal of Physical Chemistry B , vol.118, pp.4201-4211 (2014) Convenient and solventless preparation of pure carbon nanotube/polybenzoxazine nanocomposites with low percolation threshold and improved thermal and fire properties, C. Zuniga, L. Bonnaud, G. Lligadas, J.C. Ronda, M. Galia, V. Cadis, Ph. Dubois, Journal of Materials Chemistry A, vol.2, pp.68146822 (2014) Corrosion protection of clad 2024 aluminum alloy anodized in tartaric-sulfuric acid bath and protected with hybrid sol–gel coating, V.R. Capelossi, M. Poelman, I. Recloux, R.P.B. Hernandez, H.G.de Melo, M.G. Olivier, Electrochimica Acta, vol.124, pp.69-79 (2014) Elaboration of poly(lactic acid)/halloysite nanocomposites by means of water assisted extrusion: structure, mechanical properties and fire performance, G. Stoclet, M. Sclavons, B. Lecouvet, J. Devaux, P. Van Velthem, A. Boborodea, S. Bourbigo and N. Sallem-Idrissi, RSC Advances, vol.4, n°101 (2014), pp.57553-57563 Elution temperatures of polyethylene copolymers in temperature rising elution fractionation (TREF): comparison in xylene and trichlorobenzene diluents, A. Boborodea, F. Mirabella, International Journal of Polymer Anal. Charact., vol.19, n° 5, pp.468-473 (2014) 35 Activities Report EMRA - 2014 Enzymatic surface treatment of poly (3-hydroxybutyrate) (PHB), and poly (3-hydroxybutyrate-co3-hydroxyvalerate) (PHBV), N. Berezina, B. Yada, T. Godfroid, T. Senechal, R. Wei, W. Zimmermann, Journal of Chemical Technology & Biotechnology, DOI : 10.1002/jctb.4513 (2014) Fast analytical temperature rising elution fraction (ATREF) method, A. Boborodea, A. Luciani, J. Michel, International Journal of Polymer Anal. Charact., vol.19, n° 2, pp.124–129 (2014) Formation–structure–properties of niobium-oxide nanocolumn arrays via self-organized anodization of sputter-deposited aluminum-on-niobium layers, A. Mozalev, R.M. V´azquez, C. Bittencourt, D. Cossement, F. Gispert-Guirado, E. Llobet and H. Habazaki, Journal of Materials Chemistry C, vol.2, pp.4847-4860 (2014) Free radical generation and concentration in a plasma polymer: the effect of aromaticity, A. Ershov, F. Khelifa, V. Lemaur, J. Cornil, D. Cossement, Y. Habibi, Ph. Dubois, R. Snyders, ACS Applied Materials & Interfaces, vol.6, pp.12395-12405 (2014) Gas permeability properties of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate, J. Vandewijngaarden, I.M. Murariu, Ph. Dubois, R. Carleer, J. Yperman, P. Adriaensens, S. Schreurs, N. Lepot, R. Peeters, M. Buntinx, SpringerPlus, vol.22, pp.501-507 (2014) Grafted D/L-lactide to cellulose acetate by reactive melt processing: its role as CA/PLA blend compatibilizer, R. Quintana, O. Persenaire, Y. Lemmouchi, L. Bonnaud, Ph. Dubois, European Polymer Journal,vol.57, pp.30-36 (2014) Grinding of vegetal fibers to micrometer size, B.J. Marin, H. Deleu, Chemical Engineering Technology, vol.37, pp.888-890 (2014) Halometallate ionic liquids – revisited, J. Estager, J.D. Holbrey and M. Swadzba-Kwasny, Chem. Soc. Rev., vol.2014, 43(3), pp.847-886 High performance benzoxazine/CNT nanohybrid network - An easy and scalable way to combine attractive properties, L. Dumas, L. Bonnaud, M-G. Olivier, M. Poorteman, Ph. Dubois, European Polymer Journal, vol.58, pp.218-225 (2014) In situ polymerised polyamide 6/sepiolite nanocomposites : effect of different interphases, E. Bilotti, E. Duquesne, H. Deng, R. Zhang, F. Quero, N. Savvas, R. Fischer Hartmut, Ph. Dubois, T. Peijs, European Polymer Journal, vol.56, pp.131-139 (2014) In tobacco BY-2 cells xyloglucan oligosaccharides alter the expression of genes involved in cell wall metabolism, signalling, stress responses, cell division and transcriptional control, L. González-Pérez, L. Perrotta, A. Acosta, E. Orellana, N. Spadafora, L. Bruno, B.M. Bitonti, D. Albani, J.C. Cabrera, D. Francis, H.J. Rogers, Molecular Biology Reports, vol. 41 (10), pp. 6803-6816 (2014) Investigation of the creep behaviour of a SiC containing refractory castable, E. Brochen, C. Dannert, P. Pilate, Proceeding 57th International Refractory Colloquium in Aachen, 24-25/09/2014 L’intensification des procédés chimiques, une approche radicale, C. Henneuse, J.C. Monbaliu, Athena, vol.n°301 Mai 2014, pp.18-21 La diffraction des rayons X : une technique puissante pour résoudre certains problèmes industriels et technologiques, F. Serna, J. Lagneau, J.-M. Carpentier, Chimie Nouvelle, vol.116 (2014) 36 Activities Report EMRA - 2014 Les bioplastiques sont-ils des plastiques verts ?, O. Talon, Impact environnemental des matières plastiques. Solutions et perspectives., Ed. T. Hamaide, R. Deterre, J.F. Feller, Hermes – Lavoisier (2014) Modification of the Adhesive Properties of Silicone based-Coatings by Block Copolymers, N. Thi Chinh, R. Kalinova, D. Cossement, E. Hennebert, R. Mincheva, R. Snyders, P. Flammang, Ph. Dubois, R. Lazzaroni,P. Leclère, Langmuir, vol.30, pp.358-368 (2014) Nod factor detection in B. elkanii ICA 8001 Culture medium influence, M.C. Nápoles García, J.C. Cabrera, El. Luyten, B. Dombrecht, J. Vanderleyden, J. Hormaza , A.R. Alfonso, Cultivos Tropicales , vol.35, pp.92-99 (2014) Optical characterization of a microwave pulsed discharge used for dissociation of CO2, T. Silva, N. Britun, T. Godfroid and R. Snyders, Plasma Sources Science and Technology, vol.23, pp.25009-25021 (2014) Photocatalytic activity of TiO2 nanodome thin films, M. Grandcolas, L. Yonge, O. VanOverschelde, R. Snyders, Ceramics International - Science Direct, vol.40 B, pp.12939-12946 (2014) Piezoelectric characterisation of macroporous BaTiO3 substrates, N. Maury, V. Sciamanna, G. Jean, D. Hautcoeur, V. Lardot, M. Gonon, Proceeding CIEC14, Stuttgart (DE) - 08/09/2014-10/09/2014 PLA/Halloysite nanocomposites films : water vapor barrier properties and specific key characteristics, G. Gorrasi, R. Pantani, I.M. Murariu, Ph. Dubois, Macromolecular Materials and Engineering, vol.299, pp.104-115 Polyaniline nanofibers for in situ MAO-catalyzed polymerization of ethylene, N.R. De Souza Basso, F. Oliveira, A.P. Grabin, C. Moura Stein, F.F. De Carvalho, G. Barrera Galland, L. Bonnaud, O. Murariu, Ph. Dubois, Journal of Applied Polymer Science, vol.131, pp.1-7 Production and structural characterization of water soluble exo-polysaccharide from Syncephalastrum racemosum, a strong inducer of plant defence reactions, E. Valepyn, J.C. Cabrera, A. Richel, M. Paquot, Carbohydrate Polymers, vol.101 (30), pp.941-946 (2014) Progress on fast analytical temperature rising elution fractionation (ATREF) technique for practical applications, A. Boborodea, A. Luciani, International Journal of Polymer Anal. Charact., vol.19, n° 6, pp.475-481 (2014) Reactive compatibilization of poly(L-lactide)/poly(butylene succinate) blends through polyester maleation : from materials to properties, O. Persenaire, R. Quintana, Y. Lemmouchi, J. Sampson, M. Stuart, L. Bonnaud, Ph. Dubois, Journal of the Society of Chemical Industry, vol.63, pp.1724-1731 (2014) Segmented bimorph mirrors for adaptive optics: segment design and experiment, R. Bastaits, D. Alaluf, M. Horodinca, I. Romanescu, I. Burda, G. Martic, G. Rodrigues, A. Preumont, Applied Optics, vol.53(29), pp.6635-6642 (2014) Shaping of ceramic parts by selective laser melting of powder bed, E. Juste, F. Petit, V. Lardot, F. Cambier, Journal of Materials Research, vol.29(17), pp.2086-2094 (2014) Signals in Rhizobium leguminosarum-common bean (Phaseolus vulgaris L.) interaction, M.C. Nápoles, J.C. Cabrera, R. Onderwater, R. Wattiez, I. Hernández, L. Martínez, M. Núñez, Cultivos Tropicales (2014) 37 Activities Report EMRA - 2014 Simple method for gas temperature determination in CO2-containing discharges, T. Silva, N. Britun, T. Godfroid, R. Snyders, Optics Letters, vol.39 (21), pp.6146-6149 (2014) Structure/transport property relationships within nanoclay-filled polyurethane materials using polycaprolactone-based masterbatches, S. Benali, G. Gorrasi, L. Bonnaud, Ph. Dubois, Composites Science & Technology, vol.90, pp.74-81 (2014) Synthesis of oligo(butylene succinate)-based polyurethanes : influence of the chemical structure on thermal and mechanical properties, L. Poussard, A. Mecheri, J. Mariage, I. Barakat, L. Bonnaud, J.-M. Raquez, Ph. Dubois, Journal Renew Materials, vol.2, pp.13-22 (2014) Synthesis of poly (butylene succinate) through oligomerization-cyclization-ROP route, C. Labruyère, O. Talon, N. Berezina, E. Khousakoun, C. Jérôme , RCS Advances, vol.4, pp.38643-38648 (2014) Systemic activation of defensive enzymes and protection in tobacco plantlets against Phytophthora nicotianae induced by oligosacchrins, A.B. Falcón-Rodríguez, D. Costales, J.C. Cabrera, R. Wattiez, M.A. Martínez-Téllez, American Journal of Plant Sciences, vol.5 (21) (2014) Tailoring polylactide (PLA) properties for automotive applications : effect of addition of designed additives on main mechanical properties, D. Notta-Cuvier, J. Odent, I.-M. Murariu, F. Lauro, J.-M. Raquez, B. Bennani, Ph. Dubois, Polymer Testing, vol.36, pp.1-9 (2014) Thermal curing study of bisphenol a benzoxazine for barrier coating applications on 1050 aluminum alloy , J. Escobar, M. Poorteman, L. Dumas, L. Bonnaud, P. Dubois, M-G. Olivier, Organic Coatings, vol.79, pp.53-61 (2014) Towards a Unified Description of the Charge Transport Mechanisms in Conductive Atomic Force Microscopy Studies of Semiconducting Polymers, D. Moerman, N. Sebaihi, S.E. Kaviyil, P. Leclère, R. Lazzaroni, O. Douhéret, Nanoscale, vol.6, pp.10596-10603 (2014) Trajectories in laser machining ceramics: thermal model to control remove rate, A. Demarbaix, F. Ducobu, E. Rivière-Lorphèvre, E. Filippi, F. Petit, N. Preux, MM Science Journal - Special Issue - 11th International Conference on High Speed Machining, September 11-12, 2014, Prague, Czech Republic Valorisation des REFIOM d'incinérateur d'OM, S. Marquis, N. Gineys, Ph. Descamps, H. Bréquel, Recyclage et Valorisation, vol.44, pp.66-72 (2014) Well defined thermostable cellulose nanocrystals via two-step ionic liquid swelling-hydrolysis extraction, J. Lazko, T. Sénéchal, N. Landercy, L. Dangreau, J.-M. Raquez, Ph. Dubois, Cellulose, vol.21, pp.4195-4207 (2014) Lighter tableware ceramic by controlling porosity: Effect of porosity on mechanical properties, B. Verhaeghe, C. Courtois, F. Petit, F. Cambier, J-D. Guérin, A. Leriche, S. Hampshire, Ceramics International ; 40 ; (2014) ; pp 763–770 38 Activities Report EMRA - 2014 CONFERENCES AND POSTERS Optical NO2 Sensing Based on Mesoporous Sol–gel Impregnated with Lutetium Bis-phthalocyanine, D. Lahem, M. Debliquy, A. Van Baekel, M. Bouvet, International Meeting for Chemical Sensors IMCS2014, Buenos Aires (AR), 16-19/03/14, poster Influence de la granulométrie et de la morphologie des particules de renforts céramiques dans des composites à matrice métallique déposés par cladding laser, D. Deschuyteneer, F. Petit, M. Gonon, F. Cambier, Journées Annuelles du GFC 2014, Lyon (FR), 18-20/03/14, poster Mise en forme de substituts osseux par différentes techniques dans le cadre de la coopération BCRCLMCPA (UVHC), F. Cambier, S. Hocquet, A. Leriche, J.-C. Hornez, Journée thématique "Biocéramiques Fonctionnalisées et Reconstruction Osseuses", Lille (FR), 28/03/14, oral presentation Présentation des débouchés à la suite des études de bio-ingénieurs, ULB, Bruxelles (BE), 01/04/14, oral presentation Endoscopy and ceramic welding: suitable tools for refractory lining preventive maintenance of hot blast stoves, J. Tirlocq, O. Di Loreto, 1st European Steel Technology & Application Days + 31st JSI, Paris (FR), 07-08/04/14, oral presentation Reduction of emissions of coke ovens: FIBS International current results, J. Tirlocq, O. Di Loreto, 1st European Steel Technology & Application Days + 31st JSI, Paris (FR), 07-08/04/14, oral presentation Shaping of ceramics by selective laser melting of powder, E. Juste, F. Petit, V. Lardot, F. Cambier, The 3rd International Symposium on Materials Processing Science with Lasers as Energy Sources, Berlin (DE), 21-24/04/14, oral presentation Influence of reinforcement particles size and morphology in MMC coatings made by laser cladding, D. Deschuyteneer, F. Petit, M. Gonon, F. Cambier, The 3rd International Symposium on Materials Processing Science with Lasers as Energy Sources, Berlin (DE), 21-24/04/14, oral presentation Shaping of bone substitutes by several techniques, F. Cambier, 1st NEWGEN Workshop - Dental ceramics and bioactive materials, Nantes (FR), 07-08/05/14, oral presentation Problématique de la stabilisation des sols pollués, S. Marquis, BTP Expo, Liège (BE), 09/05/14, oral presentation Synthesis of non-isocyanate polyurethanes based on aminated resin and carbonated soybean oil, L. Poussard, J. Mariage, B. Grignard, C. Jérôme, J.-M. Raquez, Ph. Dubois, ICBMC, Montreal (CA), 1316/05/14, oral presentation Comparative studies on the structure, properties and applicability of commercial chitosan from crustaceans and fungi, J.C. Cabrera, M. Viseur, M. Jakobczyk, G. Wégria, L. Poussard, J. Mariage, J. De Winter, P. Gerbaux, R.C.A. Onderwater, R. Wattiez, International Conference on Bio-based Materials and Composites ICBMC’14, Montreal (CA), 13-16/05/14, oral presentation Synthesis and characterization of sol-gel coatings nanofilled with zinc oxide deposited on metal substrates, A. Nicolay, B. Ruelle, M. Poelman, Ph. Dubois, M. Olivier, BPG annual meeting, Ghent (BE), 19-20/05/14, poster 39 Activities Report EMRA - 2014 Synthesis and functionalization of a benzoxazine monomer for application in aeronautic, H. Boma Uke’Mfum, L. Dumas, L. Bonnaud and Ph. Dubois, BPG annual meeting, Ghent (BE), 19-20/05/14, poster PRISTIMAT2 : Partenariat en Recherches, Innovations et Supports Techniques Interrégionaux en MATériaux et Thermique, S. Hocquet, Journée thématique: "Nouveaux matériaux hautes performances: les composites à matrice métallique/céramique", Liège (BE), 20/05/14, oral presentation Identification d’opportunités pour le secteur chimique dans le cadre d’Horizon 2020, T. Randoux, Horizon 2020: Quelles opportunités pour nos PME, info PME-IDEA, Mons (BE), 20/05/14, oral presentation La chimie verte appliquée: une vision durable pour nos partenaires industriels, J. Estager, Journées chimie verte, Gembloux (BE), 21/05/14, oral presentation New trends in the field of biopolymers: 2. Polylactide (PLA) – graphite nanocomposites as materials for engineering applications, M. Murariu, Y. Paint, J.-M. Raquez, L. Bonnaud, Ph. Dubois, 11th NanoWal Meeting "Bio-inspired synthetic functional molecules, ULg, Liège (BE), 21/05/14, poster Dispersion and confinement of nanoparticles within polymeric matrices, L. Bonnaud, UNICAMP, Campinas (BR), 26/05/14, oral presentation Composites polymère-fibres naturelles – POLYCHANVRE, un projet transfrontalier, F. Cordenier, B. Goffin, B. Kurek, C.El Mazry, J. Beaugrand, B. Cauwe, M. Boudifa, Les fibres naturelles pour les architectes, Namur (BE), 27/05/14, oral presentation Dispersion and confinement of nanoparticles within polymeric matrices, L. Bonnaud, USP, Sao-Paolo (BR), 27/05/14, oral presentation Dispersion and confinement of nanoparticles within polymeric matrices, L. Bonnaud, UFRJ, Rio de Janeiro (BR), 29/05/14, oral presentation Dispersion and confinement of nanoparticles within polymeric matrices, L. Bonnaud, PUCJ, Rio de Janeiro (BR), 30/05/14, oral presentation Cell wall derived oligosaccharides as plant biostimulants: recent advances in their biological activities and applications, L. González-Pérez, M.C. Napoles, A. Falcón, D. Costales, E. Diosdado, S. González, G. González, H.J.Rogers, G. Cabrera, J. De Winter, P. Gerbaux, G. Wégria, R.C.A. Onderwater, R. Wattiez, J.C. Cabrera, II Congreso Internacional de Biotecnología y Biodiversidad CIBB-2014, Guayaquil (EC), 06/2014, oral presentation Synthesis and characterization of sol-gel coatings nanofilled with zinc oxide deposited on metal substrates, A. Nicolay, B. Ruelle, M. Poelman, P. Dubois, M. Olivier, 4th International Colloids Conference: Surface Design & Engineering, Madrid (ES), 15-18/06/14, poster Ceramic-metal composites from ceramic preforms prepared by ice templating method, D. Hautcoeur, A. Leriche, M. Gonon, V. Lardot, F. Cambier, 1ère journée des Chercheurs de l'Institut Matériaux, UMONS, Mons (BE), 02/07/14, oral presentation Current progress in the production of PLA -ZnO nanocomposites, M. Murariu, S. Benali, Y. Paint, J.-M. Raquez, L. Bonnaud, Ph. Dubois, 1ère journée des Chercheurs de l'Institut Matériaux, UMONS, Mons (BE), 02/07/14, poster 40 Activities Report EMRA - 2014 Effect of cBN and Co content on densification, microstructure, mechanical properties and wear performance of spark plasma sintered cBN/WC-Co composites, L. Boilet, J.-P. Erauw, F. Cambier, V. Lardot, 3rd International Workshop on Spark Plasma Sintering, Toulouse (FR), 16-18/07/14, oral presentation Shaping of ceramics by selective laser melting of powder and fast laser machining of green bodies, 2 processes for rapid prototyping, F. Cambier, E. Juste, F. Petit, C. Ott, V. Lardot, 5th International Congress on Ceramics- ICC5, Beijing (CHN), 17-21/08/14, oral presentation Minimizing temperature gradients during FAST sintering of large volume components by hybrid heating, J.-P. Erauw, V. Dupont, M. Cambier, V. Lardot, F. Cambier, Sintering 2014, Dresden (DE), 2428/08/14, oral presentation Field assisted sintering of cBN/WC-Co composites : effect of cBN and Co content on densification behaviour, microstructure and resulting mechanical properties, L. Boilet, J.-P. Erauw, F. Cambier, Sintering 2014, Dresden (DE), 24-28/08/14, poster Field assisted (reactive) sintering of Fe2VAl-based thermoelectric compounds, J.-P. Erauw, V. Dupont, C. Van der Rest, P. Jacques, F. Cambier, Sintering 2014, Dresden (DE), 24-28/08/14, oral presentation Controlled Swelling of Cellulose Fibres in Ionic Liquids : Impact on Cellulose Nanocrystals Extraction and Properties, J. Lazko, T. Sénéchal, A. Bouchut, Y. Paint, L. Dangreau, J.-M. Raquez, Ph. Dubois, BiPoCo, Visegrád (HU), 24-28/08/14, poster Problématique de l’odeur pour les fibres naturelles, C. Henneuse, Assemblée générale du projet SINFONI (structuration des filières chanvres et lin pour les applications matériaux), Paris (FR), 05/09/14, oral presentation Laser shaping of ceramics - challenges and opportunities, F. Petit, E. Juste, Workshop on Rapid Prototyping and Laser Formation of Ceramic, Cracovie (PL), 07-10/09/14, oral presentation invitée Piezoelectric characterization of macroporous BaTiO3 substrates, N. Maury, V. Sciamanna, G. Jean, M. Gonon, D. Hautcoeur, CIEC14: European Inter-Regional Conference on Ceramics, Stuttgart (DE), 08-10/09/14, oral presentation Aides financières à l'innovation pour l'industrie extractive : vers une valorisation optimale des ressources, B. Grymonprez, Séminaire Fediex, Louvain-la-Neuve (BE), 19/09/14, oral presentation Characterization of the compressive creep behaviour of clay refractory materials, according to EN 993-9 and ISO 3187 standards development of a viscoelastic model, P. Pilate, V. Lardot, F. Cambier, E. Brochen, 57th International Refractory Colloquium in Aachen, Aachen (DE), 24-25/09/14, oral presentation Investigation of the creep behaviour of a SiC containing refractory castable, E. Brochen, C. Dannert, P. Pilate, 57th International Refractory Colloquium in Aachen, Aachen (DE), 24-25/09/14, oral presentation Thermic and catalytic characterization of three fungal laccases and their application, A. Tanghe, N. Berezina, G. Castel, G.A. Jimenez-Tobon, C. Jaspers, R. Onderwater, 4th International Conference on Novel Enzymes, Ghent (BE), 10/2014, poster 41 Activities Report EMRA - 2014 Mise en forme de céramique par fusion sélective laser, E. Juste, F. Petit, V. Lardot, F. Cambier, Journée technique "Fabrication additive numérique céramique", Limoges (FR), 02/10/14, invited oral presentation Projet Interreg IV POLYCHANVRE : Bilan et perspectives, B. Goffin et al., Journée Transfrontalière Chanvre et Agro-matériaux, Charleville-Mézières (FR), 09/10/14, oral presentation POLYCHANVRE : Development of polymer-hemp composites via a crossborder project, F. Cordenier, B. Goffin, B. Kurek, C.El Mazry, J. Beaugrand, B. Cauwe, M. Boudifa, Les polymères et les composites, quels renforts biosourcés?, Alençon (FR), 15-16/10/14, oral presentation Study of the potential action of metallic phytate as bio-based flame retardant additives for polylactide, L. Costez, F. Laoutid, S. Brohez, Ch. Delvosalle, Ph. Dubois, 2nd International FRConference, Ghent (BE), 16-17/10/14, oral presentation Public-Private Partnerships Information Day Brokerage event, H2020-Spire7 Metal recovery, 21/10/14, oral presentation Recyclage des réfractaires - considérations générales, méthodologie de démantèlement - Possibilités de recyclage des plaques rotatives de poche, P. Pilate, Journée thématique GFC-SF2M : Recyclage réfractaire, Orléans (FR), 22/10/14, invited oral presentation Le recyclage des matériaux réfractaires. Les acteurs, les paramètres, les possibilités, méthodologie de démantèlement, P. Pilate, Journée thématique GFC-SF2M : Recyclage réfractaire, Orléans (FR), 22/10/14, oral presentation Mechanical behaviour of porous anisotropic ceramics obtained by freeze casting : porosity gradient effect , D. Hautcoeur, A. Leriche, C. Baudin, M. Gonon, V. Lardot, F. Cambier, Journée annuelle de la BCerS, Ghent (BE), 23/10/14, oral presentation Monitoring tools coupled to a numerical model dedicated to a faster drying of refractory concrete linings, S. Abdelouhab, G. Martic, M. Cambier, M. Gonon, V. Lardot, F. Cambier, Journée annuelle de la BCerS, Ghent (BE), 23/10/14, oral presentation Anisotropic porous ceramic : from structure to applications, D. Hautcoeur, A. Leriche, E. Meurice, M. Gonon, V. Lardot, F. Cambier, Journée annuelle de la BCerS, Ghent (BE), 23/10/14, oral presentation NO2 optical fiber sensor based on TFBG coated with LuPc2, A. Bueno-Martinez, M. Debliquy, D. Lahem, A. Van Baekel, P. Mégret, C. Caucheteur, IEEE Sensors Conference, Valencia (ES), 0205/11/14, oral presentation Recent developments in advanced biomaterials for implants, F. Cambier S. Hocquet, A. Leriche, Workshop 50 aniversario del Instituto de Cerámica y Vidrio, Madrid (ES), 03/11/14, oral presentation Témoignage des Centres de recherches, Le soutien technologique wallon aux PME , S. Neirynck, C. Henneuse, Brunch Info LME-IDEA, La Louvière (BE), 04/11/14, oral presentation Greening the life cycle of polylactide : why we need transparency in LCA, O. Talon, B. Bergmann, 4th international conference on Life Cycle approaches, Lille (Fr), 05-06/11/14, oral presentation Evaluation of the influence of innovative antifouling solutions on the environmental impact of maritime transportation, S. Dropsit, N.H. Vlachou, A.F.A. Trompeta, C.A. Charitidis, O. Talon, 4th international conference on Life Cycle approaches, Lille (Fr), 05-06/11/14, oral presentation 42 Activities Report EMRA - 2014 Elaboration de composites céramique-métal à gradient de propriétés pour la gestion de flux thermiques, Y. Lorgouilloux, R. Dubois, S. Hocquet, M. Cambier, O. Rigo, N. Ferguen, W. Leclerc, C. Pelegris, G. Capon, C. Courtois, V. Lardot, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Modélisation et caractérisation des propriétés thermiques de composites céramique-métal pour la gestion de flux thermique, S. Hocquet, Y. Lorgouilloux, R. Dubois, M. Cambier, O. Rigo, N. Ferguen, W. Leclerc, C. Pelegris, G. Capon, C. Courtois, V. Lardot, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Comportement mécanique en compression de céramiques poreuses anisotropes élaborées par congélation orientée: relation microstructure et déformation, D. Hautcoeur, A. Leriche, C. Baudin, M. Gonon, V. Lardot, F. Cambier, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Etude de revêtements sol-gel hybrides comportant des nanocharges pour la protection de l'acier doux, P. Aubry, C. Delmotte, V. Lardot, F. Cambier, M. Poelman, M.-G. Olivier, M. Wenkin, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Modification de la surface de microbilles de verre par dépôt d'oxyde en phase aqueuse (Liquid Phase Deposition - LPD) de TiO2 photocatalytique, G. Bister, N. Nutal, M. Poelman, C. Motte, B. Kartheuser, V. Lardot, F. Cambier, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Couches de MMC anti-usure déposées par cladding laser: influence de la granulométrie et de la morphologie des particules de renforts céramiques, D. Deschuyteneer, F. Petit, M. Gonon, F. Cambier, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Structure macroporeuse en phosphate de calcium: comparaison des techniques de mise en forme, S. Chamary, J-C. Hornez, F. Cambier, M. Descamps, D. Hautcoeur, G. Nolens, A. Leriche, V. Lardot, Matériaux 2014, Montpellier (FR), 24-28/11/14, oral presentation Des solutions technologiques en matière de recyclage et valorisation de déchets, C. Henneuse, La gestion des produits chimiques en entreprise, Les ateliers de l'environnement, UCM-Certech, Seneffe (BE), 09/12/14, oral presentation 43 Activities Report EMRA - 2014 COURSES Cours LMAPR2647 et LMAPR2648 "Sustainable treatment of industrial and domestic waste", O. Noiset, UCL, Louvain-la-Neuve (BE), 2014 Cycle de vie d’un produit et Ecoconception – Introduction à l’ACV, O. Talon, Cefochim, Seneffe (BE), 06/01/14 Introduction à l’Analyse de Cycle de Vie - Réflexions sur l’ACV des bioplastiques et sur la communication environnementale, O. Talon, INSA, Rouen (FR), 20/01/14 Cours "La minéralurgie au service de l'environnement", B. Grymonprez, UVHC, Valenciennes (FR), 02/03/14 Introduction à l’ACV, O. Talon, UMons, Mons (BE), 12/03/14 Cours "Advanced Ceramics", M. Gonon, A. Leriche, S. Hocquet, F. Cambier, UMONS, Mons (BE), 1012/14 Cours (Greentechs project) "analyse de rejets dans l'air", O. Noiset, L. Bilteryst, P. Le Maitre, S. Moro, Cefochim, Seneffe (BE), 2-3-8-9/10/14 Cycle de vie d’un produit et Ecoconception – Introduction à l’ACV, O. Talon, Cefochim, Seneffe (BE), 17/10/14 Cycle de vie d’un produit et Ecoconception – Introduction à l’ACV, O. Talon, Cefochim, Seneffe (BE), 27/10/14 Cours LTAP "Techniques d'échantillonnage en hygiène industrielle", L. Bilteryst, S. Moro, UCL, Louvain-la-Neuve (BE), 18/11/14 Etat de l’art des Agro ressources, J. Lazko, Ghislenghien, 09/12/14 STANDS Salon des mandataires, Marche-en-Famenne (BE), 13-14/02/14 Forum de déchets - économie circulaire - écologie , Lille (FR), 18/02/14 Séminaire WAGRALIM, Les Isnes (BE), 24/03/14 16th Workshop Odour und Emissions of Plastic Materials, Kassel (DE), 24-25/03/14 Environord, Lille (FR), 11-12/06/14 Pollutec, Lyon (FR), 2-6/12/14 JEC Composites, Paris (FR), 10-13/03/14 44 Activities Report EMRA - 2014 VISITORS, FAIRES, SHOWS, CONFERENCES Bio-based Industries Consortium Extraordinary General Assembly, Bruxelles (BE), 5/02/14 B2B Mission for growth 2014 , La Louvière (BE), 18-19/02/14 Mecatech Day, Louvain-La-Neuve (BE), 19/02/14 JEC Composites, Paris (FR), 11-12-13/03/14 5. Sitzung des Expertenkreises "Field Assisted Sintering Technique / Spark Plasma Sintering", Freiberg (DE), 13/03/14 Reconversion des friches urbaines polluées, Paris (FR), 25-26/03/14 1/2 journée thématique sur la pierre - projet Hybriprotech, Seneffe (BE), 27/03/14 Final conference of the MACPoll project , Delft (NL), 13-14/05/14 Journées Sol-Gel édition 2014 , Tours (FR), 13-15/05/14 Rendez-vous du Pôle de compétitivité TEAM² sur le thème «Comment la chimie peut aider au recyclage des plastiques ?», Loos en Gohelle (FR), 15/05/14 Pyro 2014, Birmingham (UK), 19-23/05/14 ACV et écoconception, Limoges (FR), 21-22/05/14 EIHA 2014, Wesseling (DE), 21-22/05/14 Caspeo 10 ans - Grinding circuit survey and metallurgical accounting, Orléans (FR), 21-22/05/14 Caspeo 10 ans - Application of modelling & simulation approaches to the waste & biomass treatment, Orléans (FR), 22/05/14 GFSV 2014, Paris (FR), 21-23/05/14 World Metrology Day, Bruxelles (BE), 23/05/14 Workshop "factories of the Future: préparation de l'appel à projet 2015 Horizon 2020", Wavre (BE), 03/06/14 Congrès SFIP - Matériaux polymères et industrie automobile : "Les solutions composites pour alléger les véhicules de demain" , Nantes (FR), 11-12/06/14 Suschem event 2014, Bruxelles (BE), 11-12/06/14 8th International Symposium on Modern Principles for Air Monitoring and Biomonitoring (AIRMON), Marseille (FR), 15–19/06/14 Colloque "Prévention et gestion des déchets industriels", Moulin de Beez (BE), 19/06/14 CPE : EXPLOITATION DES SPECTRES VIBRATIONNELS IR, NIR et RAMAN pour la caractérisation et le dosage de constituants, Lyon (FR), 23-26/06/14 Groupe de Travail « BIC » (Industries de la Chimie Biobasée) en Wallonie, Gosselies (BE), 16/06/14 Green Week 2014 conference, Bruxelles (BE), 05/08/14 45 Activities Report EMRA - 2014 XXVII International Mineral Processing Congress, Santiago (CI), 20-24/08/14 Biobased global summit 2014, Bruxelles (BE), 9-10/09/14 VOC seminar 2014 for manufacturers. New Belgian regulation, and revisions of LEED (Eurofins), Bruxelles (BE), 23/09/14 Gestion et requalification des sites et sols dégradés - Expérience en Nord Pas-de-Calais, Villeneuve d'Ascq (FR), 25-26/09/14 Journée Technique de la SIM : Vingt ans de recyclage des déchets de construction. Quels défis ?, Lives-sur-Meuse (BE), 26/09/14 Workshop - Les bétons recyclés, Luxembourg (LU), 07/10/14 Studienamiddag "Normering bij Additive Manufacturing", Heverlee (BE), 8/10/14 Journée scientifique de la société royale de chimie: nanochimie réalisations et perspectives, Namur (BE), 09/10/14 SEMINAIRE ‘INTERIEUR’ : le nouveau cadre législatif belge pour les MATERIAUX DE CONSTRUCTION en matière d’environnement et de santé (Essenscia), Vilvoorde (BE), 09/10/14 15ème journée de l'ABCAL (Atelier nanotechnologies), Feluy (BE), 16/10/14 XXVII International Mineral Processing Congress, Santiago (CI), 20-24/10/14 Rendez-vous du Pôle de compétitivité TEAM² sur le recyclage des composites issus du transport, Loos en Gohelle (FR), 23/10/14 European Conference - Standards : your innovation bridge, Bruxelles (BE), 30/10/14 Solarcycle : quand les panneaux photovoltaïques redeviennent des matières premières, Liège (BE), 05/11/14 Réunion plénière cluster Plastiwin "Plasturgie et économie circulaire", Bouge (BE), 06/11/14 Réunion annuelle Essenscia Wallonie: modèle pour une réindustrialisation forte de la Wallonie, Louvain-La-Neuve (BE), 06/11/14 Agrocomposites 2014, St Quentin (FR), 10/11/14 Rencontre GT Pneus - Greenwin, Gosselies (BE), 13/11/14 Groupe de travail de la SIM : Bilan de l'application de liants hydrauliques pour la valorisation des déchets, Paris (FR), 13/11/14 Innovative Solid Waste Valorization, Liège (BE), 17/11/14 3D Printshow, Paris (FR), 17/11/14 Matinée thématique sur les Matériaux Réfractaires: Caractérisation et Optimisation de Procédés/Produits, Mons (BE), 18/11/14 Session d'information sur les Biocarburants Avancés (Pôle IAR), Paris (FR), 25/11/14 Polymer Stabilisation and Analysis (intertek), Basel (CH), 26/11/14 GN MEBA : "La Basse énergie en MEB et Microanalyse", Paris (FR), 4-5/12/14 46 Activities Report EMRA - 2014 European Conference on Standardization for Nanotechnologies and Nanomaterials, Bruxelles (BE), 16/12/14 PATENTS Ceramic particle mixture, and method for manufacturing ceramic parts from such a mixture, WO/2012/164025, F. Petit, V. Lardot, C. Ott, E. Juste, F. Cambier Extincteurs à réservoirs pour additifs, EP 2 425 876 B1, S. Rachidi, H. Damsir 47 Activities Report EMRA - 2014 BCRC (INISMa-CRIBC-INS) Avenue du Gouverneur Cornez, 4 7000 Mons Belgique BCRC (INISMa – CRIBC) Rue de la Bruyère, 31 6680 Bertrix Belgique Certech Rue Jules Bordet Zone industrielle C 7180 Seneffe Belgique CTP Chaussée d’Antoing, 55 7500 Tournai Belgique Materia Nova Siège principal Avenue Nicolas Copernic, 1 7000 Mons Belgique Materia Nova Rue des Foudriers,1 7822 Ghislenghien Belgique [email protected] www.emra.eu 48