Mise en page 1 - de l`Université libre de Bruxelles

Ninth International Congress
on Catalysis and
Automotive Pollution Control
APoC
C
9
Brussels, August 2012
Second Circular
Programme
August 29th - 31st, 2012
Brussels, Belgium
Registration
Registration and accommodation arrangements should be made
online :
http://capoc.ulb.ac.be
June 15th, 2012: Early bird registration deadline.
The registration fee includes:
• Wednesday reception at the « Palais des Académies »
• morning and afternoon coffee breaks
• lunch
• book of preprints (which will be distributed at the beginning of
the symposium)
• students may register at a reduced fee if at the same time a staff
member of their laboratory is present at full fee.
• accompanying persons not participating in the scientific
sessions are free of charge, but must register.
Proceedings
The proceedings of CAPoC9 will appear as a special volume of the
journal “Topics in Catalysis”. It is intended to publish all accepted
papers with no distinction between oral and poster form.
Hotel accommodation
is being handled by « Resotel ». Rooms have been reserved in
several hotels in the centre of Brussels.
Accommodation can only be guaranteed to those participants
who have filled in the enclosed accommodation form and sent it
directly to:
Resotel
6, avenue van Nieuwenhuyse, B-1160 Brussels, Belgium
Tel: +32 (0)2 779 39 39
Email: [email protected]
Url: www.resotel.be/capoc9
Venue
The Congress will be held at the « Institut de Sociologie – Salle
Dupréel »
Av. Jeanne 44 - 1050 Brussels (on the University « Campus
Solbosch » )
(see map ULB Campus Solbosch – at the end of this booklet)
There is frequent public transport service (bus 71, tram 93, 94)
between campus and city centre. Large multilevel parking facilities
are available next to the “Institut de Sociologie”
Arrival
The registration desk will be open on Tuesday August 28th, from
16h00 to 19h00, and during the congress starting on Wednesday
August 29th at 8h00 a.m..
2
Language
Presentations, discussions and proceedings will be exclusively in
English.
Social Programme
• Wednesday, August 29th
A reception will be held in the evening at the « Palais des
Académies ». It is free of charge for all registered participants and
accompanying persons, however, you have to register.
• Thursday, August 30th
The symposium dinner will take place in the evening at the
« Crowne Plaza Hotel ». The cost is of 80 Euro per head. Payment
should be made together with the registration fee.
Enquiries
N. Kruse, Executive Chairman
Tel. 32-2 650 57 14
Email : [email protected]
T. Visart de Bocarmé, Co-Chair
Tel. 32-2-650 57 24
Email : [email protected]
J-M. Bastin, Treasurer
Fax 32-2-650 57 08
Email : [email protected]
A. Desantoine, Conference Secretary
Fax 32-2-650 57 08
Email : [email protected]
3
4
Wednesday August 29th
INTRODUCTORY SESSION
08h00 Opening of the registration desk
09h00 Welcome Address
09h30 Towards completing Euro6 in the lab and for the real
world
L1
N. Steininger
European Commission, Enterprise Directorate - General – ENTR.D5,
Automative Industries, BREY 10/46, B-1049 Brussels, Belgium
10h15 Ceramic wall flow particulate filter material to meet
Euo6 emission standards and low CO2 targets
L2
C.D. Vogt
NGK Insulators Ltd., Japan
11h00 Coffee Break – Poster Session – General Overview
11h30 DeNOx catalysis in automative pollution control :
present and future
L3
M. Twigg
Caxton, Cambridge CB23.3PQ, U.K.
12h15 Lunch – Poster Session – NOX control and
mechanisms
5
ORAL SESSIONS
Session « NOx control »
13h45 DeNOx performance and reaction mechanism of the
DiAir system
K1
M. Inoue
Advanced Engine Technology Development Div., R&D Group 2, Toyota
Motor Corporation, 1200 Mishuku Susono-Shi, Shizuoka 410-1193,
Japan
14h15 Location, nature and coincidence of reactions and
influencing parameters within operating monolithic
SCR catalysts
O1
W. Partridge1, X. Auvray2, L. Olsson2, J. Pihl1, J.-S. Choi1,
A. Yezerets3, K. Kamasamudram3, N. Currier3
1
Fuels, Engines & Emissions Research Center, Oak Ridge National
Laboratory; Oak Ridge, TN, USA
2 Chalmers University of Technology; Gothenburg, Sweden
3
Cummins Inc; Columbus, IN, USA
14h35 Combination of Ag/Al2O3 and Fe-BEA for high-activity
and sulphur-tolerant catalyst for H2-assisted NH3-SCR
of NOx for light-duty diesel car applications
S. Fogel1,2, D.E. Doronkin2, J.W. Høj1, P. Gabrielsson1, S. Dahl2
O2
1
Haldor Topsøe A/S, Kgs. Lyngby, Nymøllevej 55, DK-2800 Denmark
CINF, Technical University of Denmark, Fysikvej 307, Kgs. Lyngby,
DK-2800 Denmark
2
14h55 Very high activity at low temperatures of mechanically
ball-milled Ag/Al2O3 catalysts for the Selective
Catalytic Reduction of NOx by hydrocarbons
O3
R. Burch, S.R.F. Taylor, S. Chansai, U. Kamolphop,
C. Hardacre, S.L. James
Centre for the Theory and Application of Catalysis, CenTACat, School
of Chemistry and Chemical Engineering, Queen’s University Belfast,
Belfast, N. Ireland, U.K.
15h15 Catalysts for low-temperature SCR in marine
applications
O4
H. Kannisto and H.H. Ingelsten
Competence Centre for Catalysis (KCK), Chalmers University of
Technology, Göteborg, SE-41296, Sweden
15h35 Coffee break – Poster Session – « NOx Control »
16h30 Labelled 15NO study on N2 and N2O formation over
Pt-Ba/Al2O3 LNT catalysts
K2
L. Lietti, N. Artioli, L. Righini, L. Castoldi, P. Forzatti
Politecnico di Milano, Laboratory of Catalysis and Catalytic Processes,
Dipartimento di Energia, Piazza L. da Vinci, 32 - 20133 Milano, Italy
17h00 Discussion of posters « NOx Control and mechanisms»
18h00 Departure by bus to the reception
19h00 Reception
6
Thursday August 30th
Session « NOx Control - mechanisms »
8h30 Dual layer catalysts for lean reduction of NOx by in situ
generated ammonia
K3
Y.Liu, M. P. Harold, D. Luss
Department of Chemical and Biomolecular Engineering, University of
Houston, Houston, TX 77204-4004 USA
09h00 Experimental study of the reaction of NO oxidation to
NO2 for the identification of the rate determining step
of the standard SCR reaction
O5
M.P. Ruggeri, I. Nova, E. Tronconi
Laboratory of Catalysis and Catalytic Processes, Dipartimento di
Energia, Politecnico di Milano, Piazza L. da Vinci 32, 20133 Milano,
Italy
09h20 NO oxidation inhibition – reaction between product
NO2 and/or surface nitrates and hydrocarbon species
O6
W.S. Epling, H. Oh, J.-Y. Luo
Department of Chemical Engineering, University of Waterloo,
Waterloo, Ontario, N2L 3G1, Canada
09h40 Effective model for prediction of N2O formation during
the NOx storage catalyst regeneration with H2, CO and
hydrocarbons
O7
P. Kočí1, Š. Bártová1, D. Mráček1, M. Marek1, J.-S. Choi2,
J. A. Pihl2, C.S. Daw2, W.P. Partridge2
1 Institute of Chemical Technology, Prague, Technická 5, CZ16628,
Czech Republic
2 Oak Ridge National Laboratory, Fuels, Engines & Emissions
Research Center, 2360 Cherahala Blvd., Knoxville, TN 37932, USA
10h00 Analysis of the coupling of HC-SCR by ethanol and
NH3-SCR on real engine emissions
O8
A. Frobert1, S. Raux1, S. Rousseau2, G. Blanchard2
1 IFP Energies nouvelles, Rond-point de l’échangeur de Solaize, BP 3,
69360 Solaize, France
2 PSA Peugeot Citroën, Route de Gisy, 78943 Vélizy-Villacoublay
Cedex, France
Session « sorption – mechanisms - ageing »
10h20 Coffee Break – Poster Session – « mechanisms –
sorption – ageing »
11h20 Discussion of posters « mechanisms – sorption –
ageing »
12h20 Lunch
7
13h30 Insight into the active sites in the NH3-SCR reaction
on Cu-SSZ-13
O9
I. Lezcano-Gonzalez,1,2 U. Deka,1,2
B.M. Weckhuysen1,A.M. Beale1
1
Department of Inorganic Chemistry and Catalysis, Utrecht University,
The Netherlands
2 Materials innovation institute (M2i), Delft, The Netherlands
13h50 The effects of P-poisoning of CexZr1-xO2 on the
transient oxygen storage and release kinetics
O10 S.Y. Christou, A.M. Efstathiou
Heterogeneous Catalysis Lab, Chemistry Department, University of
Cyprus, P.O. Box 20537, 1678 Nicosia, Cyprus
14h10 The active phase of palladium during methane
oxidation: a combined DFT and surface X-ray
diffraction study
O11
A. Hellman1, A. Trinchero1, J. Gustafson2, E. Lundgren2,
J.N. Andersen2, H. Grönbeck1
1
Department of Applied Physics and Competence Centre for
Catalysis, Chalmers University of Technology,SE-41296, Göteborg,
Sweden
2 Division of Synchrotron Radiation Research, Lund University, Box
118, SE-221 00 Lund, Sweden
14h30 Modulation excitation spectroscopy (MES) coupled
with XAS and XRD to capture dynamic structural
changes in supported Pd catalysts
O12
D. Ferri1, M.A. Newton2, M. di Michiel2, Y. Lu1,
M. Santhosh Kumar1, A. Eyssler1, P. Hug1, A. Weidenkaff1
1
Empa, Lab. for Solid State Chemistry and Catalysis,
Ueberlandstrasse 129, Dübendorf 8600, Switzerland
2 European Synchrotron Radiation Facility, Grenoble 38043, France
Session « fuel alternatives – innovative
technologies - TWC »
14h50 Coffee Break – Poster Session – « fuel alternatives –
innovative technologies – TWC » and « Particulate
matters »
15h50 Overview: Status of the microwave-based automotive
catalyst state diagnosis
K4
R. Moos1, G. Beulertz1, S. Reiß1, G. Hagen1,
G. Fischerauer1, M. Votsmeier2, J. Gieshoff2
1 University of Bayreuth, Bayreuth Engine Research Center, Bayreuth,
Germany
2 Umicore AG & Co. KG, Hanau-Wolfgang, Germany
8
16h20 A multifunctional converter for the purification of
diesel exhaust gas equipped with a self heat
exchanging function
O13
A. Obuchi, A. Ohi, S. Hirata, J. Uchisawa, T. Nanba
Research Center for New Fuels and Vehicle Technology, National
Institute of Advanced Industrial Science and Technology (AIST), 16-1
Onogawa, Tsukuba 305-8569, Japan
16h40 Enhanced methane conversion under periodic
operation over a Pd/Rh based TWC in the exhausts
from NGVs
O14
D. Bounechada1, G. Groppi1, P. Forzatti1, K. Kallinen2,
T. Kinnunen2
1
2
Dipartimento di Energia, Politecnico di Milano, Milano, 20133 Italy
Ecocat Oy, Typpitie 1, Oulu, 90620 Finland
20h00 Symposium Dinner
Friday August 31st
Session « particulate matters »
09h00 Integrated DeNOx-DeSoot catalytic system with
improved low-temperature performance
K5
A. Yu. Stakheev1, G. N. Baeva1, G. O. Bragina1,
A.L. Kustov2, M. Grill2, J.R. Thøgersen2
1
Zelinsky Institiute of Organic Chemistry, Leninsky Pr. 47, Moscow,
119991, Russian Federation
2
Haldor Topsoe A/S, Nymøllevej 55, DK-2800 Lyngby, Denmark
09h30 Diesel soot catalyzes the selective catalytic reduction
of NOx with NH3
O15
M. Mehring, M. Elsener, O. Kröcher
Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
09h50 Soot oxidation over CeO2–Ag catalyst with a unique
‘Rice–ball’ morphology
O16 K. Yamazaki, F. Dong, T. Kayama, H. Shinjoh
Toyota Central R&D Laboratories Inc., Nagakute, Aichi 480-1192,
Japan
10h10 Coffee Break – Poster Session – « particulate
matters »
10h25 Discussion of posters « particulate matters » and
« fuel alternatives- inovative technologies – TWC »
9
11h25 Investigation of exhaust aftertreatment systems for
removal of particulate emissions from gasoline direct
injection engines
K6
S. Spiess, K.-F. Wong, J.-M. Richter, R. Klingmann
Umicore AG & Co KG, Hanau-Wolfgang 63457 Germany
11h55 Characterization of particulate matter from direct
injected gasoline engines
O17
C. Wang-Hansen1, P. Ericsson2, B. Lundberg1,
M. Skoglundh1, P.-A. Carlsson1, B. Andersson1
1
Department of Chemical and Biological Engineering and
Competence Centre for Catalysis, Chalmers University of Technology,
S-412 96 Göteborg, Sweden
2 Saab Automobile Powertrain AB, Trollhättan, S-461 80 Sweden
12h15 Cerium oxide-catalyzed DPF regeneration in a real
diesel engine exhaust.
O18 M. Valencia1, E. López1, S. Andrade1, M.L. Iris1, N. GuillénHurtado2, V. Rico-Pérez2, A. García-García2, C. SalinasMartínez de Lecea2, A. Bueno-López2
1
Galician Automotive Technology Center,Testing Labs. Pol. Industrial
A Granxa P.O. 36400 Parcela 249-250 Porriño-Pontevedra, Spain
2
Inorganic Chemistry Department. University of Alicante. Ap. 99
E03080 Alicante,Spain
12h35 Concluding remarks
12h45 Symposium End - Lunch
10
POSTER SESSIONS
Session « NOx Control »
P1
Novel ammonia precursor solutions for selective
catalytic reduction of NOx and their catalytic
decomposition
D. Peitz, M. Elsener, O. Kröcher
Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
P2
Active and hydrothermally stable WO3/ZrO2-Ce1-xZrxO2
(x = 0.3, 0.32) catalysts for Selective Catalytic
Reduction of NO with NH3
T. Baidya and O. Kröcher
Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
P4
Autoignition of n-decane could it be a benefit for the
selective catalytic reduction of NO?
C. Petitto1, G. Delahay1, A. Lahougue2, C. Hamon2
1
Institut Charles Gerhardt Montpellier UMR 5253, CNRS-UM2-ENSCMUM1, MACS research team, Ecole Nationale Supérieure de Chimie, 8
rue Ecole Normale, 34296 Montpellier Cedex 5, France
2
IRMA - Parc technologique de Soye - 9 rue de Galilée - BP 64 56274 Ploemeur, France
P5
Non-hydrolytic sol-gel preparation of silver alumina
based catalysts for the HC-SCR of NOx
C. Petitto1,2, P. H. Mutin1, G. Delahay2
Institut Charles Gerhardt Montpellier UMR 5253, CNRS-UM2-ENSCMUM1
1 CMOS research team, Université Montpellier 2, Place Eugène
Bataillon, 34095 Montpellier Cedex 5, France
2 MACS research team, Ecole Nationale Supérieure de Chimie, 8 rue
Ecole Normale, 34296 Montpellier Cedex 5, France
P6
Characterisation of a commercial automotive urea-SCR
copper-zeolite catalyst
C. Kieffer1, J. Lavy1, E. Jeudy1, N. Bats1, G. Delahay2
1
IFP Energies nouvelles, BP3, 69360 Solaize, France
Institut Charles Gerhardt, UMR 5253; Equipe “Matériaux Avancés
pour la Catalyse et la Santé”, ENSCM, 8 rue de l’Ecole Normale, 34296
Montpellier cedex, France
2
P7
Mono- and bimetallic Rh and Pt NSR-catalysts
prepared by controlled deposition of noble metals on
support or storage component
R. Büchel1,2 S. E. Pratsinis1, A. Baiker2
1 Particle Technology Laboratory, Department of Mechanical and
Process Engineering, ETH Zurich, Sonneggstrasse 3, CH-8092 Zurich,
Switzerland
2 Department of Chemistry and Applied Biosciences, ETH Zurich,
Hönggerberg, HCI, CH-8093 Zurich, Switzerland
11
P8
Activity evaluation of palladium supported on
dealuminated Y-zeolite by using N2O reduction by NH3
H. Najar1, M. Saïd Zina1, G. Delahay2, A. Ghorbel1
1
Laboratoire de Chimie des Matériaux et Catalyse, Département de
chimie, Faculté des Sciences de Tunis, Campus Universitaire 2092 El
Manar, Tunis, Tunisia
2
Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM2ENSCM-UM1, Eq. “Matériaux Avancés pour la Catalyse et la Santé”,
ENSCM (MACS - Site la Galéra), 8, rue Ecole Normale, 34296
Montpellier Cedex 5, France
P9
On the efficiency of SCR-NH3 for heavy duty vehicles
running on CNG
D. Adouane 1, S.Capela2, P. Da Costa1
1 Université Pierre et Marie Curie (Paris VI), Institut Jean le Rond
d’ALEMBERT, CNRS UMR 7190, 2 Place de la Gare de Ceinture 78210
Saint Cyr l’Ecole, France
2
GDF-SUEZ 361, avenue du Président Wilson, BP 33 -93211 Saint
Denis La Plaine Cedex, France
P10 Effect of flow distribution in automotive converter on
performance deterioration of LNT catalysts
K. Bawolak-Olczak, D. Adouane, H. Dutilleul, P. Guibert,
P. Da Costa
Université Pierre et Marie Curie, Institut Jean Le Rond d’Alembert CNRS (UMR 7190), 2 place de la gare de ceinture, 78210 Saint-Cyrl’Ecole, France
P11 Nanofiber alumina supported lean NOx trap - improved
sulfur tolerance and simultaneous soot and NOx
removal
I. S.Pieta1,2, M. García-Diéguez2, M.A. Larrubia2,
L.J. Alemany2, W.S. Epling1
1
Department of Chemical Engineering, University of Waterloo,
Waterloo, Ontario, N2L 3G1, Canada
Department of Engineering Chemistry, University of Malaga, E29071 Malaga, Spain
2
P12 Zeolite catalysts in structured reactors for NH3-SCR of
NOX from biogas engines: active center design
J. Ochoǹska1,2, A. Rogulska1,2, D. McClymont3, B. Gil1,
W. Roth1, P. Jodłowski1, A. Kołodziej2 , S. Kolaczkowski3,
J. Łojewska1
1Jagiellonian
University, Faculty of Chemistry, Ingardena 3, 30-060
Kraków, Poland
2Institute of Chemical Engineering of the Polish Academy of Sciences,
Bałtycka 5, 44-100 Gliwice, Poland
3Department of Chemical Engineering, University of Bath, Claverton
Down, Bath BA27AY, UK
12
P13 Influence of sulfur dioxide on the ammonia adsorption
in a marine SCR catalyst
H.H. Ingelsten1, M. Magnusson2, H. Kannisto1, E. Fridell2,3
1
Competence Centre for Catalysis, Chalmers University of Technology,
SE-412 96 Göteborg, Sweden
2
Shipping and Marine Technology, Chalmers University of Technology,
SE-412 96 Göteborg, Sweden
3Swedish Environmental Research Institute (IVL), Box 53021, SE-400
14, Göteborg, Sweden
P14 Impact of biodiesel-based Na on the selective catalytic
reduction of NOx by NH3 over Cu-zeolite
D.W. Brookshear1, T.J. Toops2, K. Nguyen1, B.G. Bunting2
1
University of Tennessee, Knoxville, Tennessee 37996, USA
Oak Ridge National Laboratory, 2360 Cherahala Blvd. Knoxville,
Tennessee 37932, USA
2
P15 Promoting role of Rh on the NSR performance of BaObased NOx storage catalysts under lean-burn
conditions
S. Andonova1, V. Marchionni2, M. Borelli2, R. Nedyalkova1
L. Lietti2, L. Olsson1
1
Competence Centre for Catalysis, Chalmers University, 412 96
Gothenburg, Sweden
2 Politecnico di Milano, P.zza Leonardo Da Vinci, 32, 20133 Milano,
Italy
P16 Dispersion aspects of NH3 delivery strategies for NH3based SCR systems
A. Lundström1, H. Ström2, M. Skoglundh1
1
Competence Centre for Catalysis, Chalmers University of Technology,
Göteborg, SE-412 96, Sweden
2 Department of Applied Mechanics, Chalmers University of
Technology, Göteborg, SE-412 96, Sweden
P17 Influence of hydrothermal treatment on the ammonia
storage capacity for Fe-BEA as an NH3-SCR catalyst
S. Shwan1, J. Jansson2, J. Korsgren2, R. Nedyalkova 1,
L. Olsson1, M. Skoglundh1
1
Competence Centre for Catalysis, Chalmers University of Technology,
SE-412 96 Gothenburg, Sweden
2 Volvo Powertrain AB, SE-40508 Gothenburg, Sweden
P18 Abatement of NO with CO on Cu, Fe or Co-ZrO2 catalysts
prepared through a unique sol-gel synthesis step
C.A. Sierra-Pereira, A.V.S. Neto, E.A. Urquieta-González
Laboratory of Catalysis, Department of Chemical Engineering, Federal
University of Sao Carlos, C. Postal 676, CEP 13.565-905, São Carlos-SP,
Brazil
P19 The effect of NO2 on the NH3-SCR performance of fresh
and hydrothermal aged Fe-ZSM-5
X. Shi, F. Liu, W. Shan, L. Xie, H. He
Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
13
P20 Lean NOx trap chemistry under lean-gasoline exhaust
conditions: impact of high temperature and high NOx
operation
J.A. Pihl, J. E. Parks, T.J. Toops
Oak Ridge National Laboratory, 2360 Cherahala Blvd., Knoxville, TN
37932, USA
P21 A study of the NOx selective catalytic reduction with
ethanol and its by-products.
A. Flura, X. Courtois, F. Can, S. Royer, D. Duprez
Laboratoire de Catalyse en Chimie Organique, UMR 6503 CNRSUniversité de Poitiers, Bâtiment B27, 4 rue Michel Brunet, 86022
Poitiers cedex, France
Session « NOx – Control – Mechanisms »
P22 Novel details of catalytic urea decomposition
A. M. Bernhard, D. Peitz, M. Elsener, O. Kröcher
Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
P23 Are the RNOx compounds active or spectators in the
C3H6-SCR of NOx on WOx-ZrO2-based catalysts?
N. El Kolli, C. Potvin, C. Thomas
UPMC, UMR 7197, Laboratoire de Réactivité de Surface, 4 Place Jussieu,
Paris, F-75005, France
P24 Temperature-programmed reactivity of ad-NOx species
with n-C10: an informative tool on the low-temperature
HC-SCR mechanism on Ag-Al2O3?
K. Malinger, J. Blanchard, C. Thomas
UPMC, UMR 7197, Laboratoire de Réactivité de Surface, 4 Place Jussieu,
Paris, F-75005, France
P25 On the detrimental effect of tungstates on the n-C10-SCR
of NOx of Ag-Al2O3
J. Blanchard, H.-Y. Law, C. Thomas
UPMC, UMR 7197, Laboratoire de Réactivité de Surface, 4 Place Jussieu,
Paris, F-75005, France
P26 Selective catalytic reduction of NO by NH3 over mixed
oxides MoO3-TiO2 and V2O5-MoO3-TiO2 aerogels
catalysts: effect of sulfate groups
J. Arfaoui1, A. Ghorbel1, G. Delahay2
1Laboratoire de Chimie des Matériaux et Catalyse, Département de
Chimie, Faculté des Sciences de Tunis,Campus universitaire, 2092 El
Manar Tunis, Tunisia
2Matériaux avancés pour la catalyse et la santé, Institut Charles Gerhardt
Institut Charles Gerhardt Montpellier, UMR 5253, Université Montpellier
2, CC 1700 Place Eugène Bataillon, 34095 Montpellier Cedex 5, France
P27 Selective catalytic oxidation of ammonia over zeolite
supported ruthenium dioxide catalyst
S. Heylen, N. Delcour, C.E.A. Kirschhock, J.A. Martens
Center for Surface Chemistry and Catalysis, Katholieke Universiteit
Leuven, Kasteelpark Arenberg 23, 3001 Heverlee, Belgium
14
P28 Kinetic modeling of lean NOx trap regeneration by CO
and H2
N. Rankovic1,2 , A. Nicolle1, D. Berthout1, P. Da Costa2
1
IFP Energies nouvelles, 1 et 4 avenue de Bois-Préau, 92852 Rueil
Malmaison Cedex, France
2
Institut Jean Le Rond d’Alembert, Université Pierre et Marie Curie –
CNRS UMR 7190, Saint-Cyr-l’Ecole, France
P29 Correlations for faster model parameterization of
differently aged NOx storage catalysts
K. Hauff, U. Tuttlies, G. Eigenberger, U. Nieken
Institute of Chemical Process Engineering, University Stuttgart, Böblinger
Straße 78, 70199 Stuttgart, Germany
P30 Confirmation of isolated Cu2+ ions in SSZ-13 as active
sites in NH3-SCR
U. Deka1,2, I. Lezcano-Gonzalez1,2, B.M. Weckhuysen1,
A.M. Beale1
1Department
of Inorganic Chemistry and Catalysis, Utrecht University,
The Netherlands
2
Materials innovation institute (M2i), Delft, The Netherlands
P31 Effect of silver loading on the lean NOx reduction with
methanol over Ag-Al2O3
M. Männikkö, M. Skoglundh, H.H. Ingelsten
Competence Centre for Catalysis, Chalmers University of Technology, 412
96 Göteborg, Sweden
P32 Reaction pathways for ammonia formation on lean NOx
trap/reduction system: a spectroscopic infrared
investigation
A. Kouakou1, C. Dujardin1, F. Fresnet2, P. Granger1
1Unité
de Catalyse et de Chimie du Solide UMR 8181, Université de
Lille1, 59650 – Villeneuve d’Ascq, France
2Renault S.A.S., 1, avenue du golf, 78288 Guyancourt, France
P33 Promising stability of gold-based catalysts prepared by
direct anionic exchange for DeNOx applications in learn
burn conditions
D.-L. Nguyen1, C. Dujardin1, J.-S. Girardon1, C. Lancelot1,
M.-K. Dongare2, S. Umbarkar2, P. Granger1
1Université
Lille Nord de France, UCCS UMR CNRS 8181, 59650
Villeneuve d’Ascq, France
2National Chemical Laboratory, Dr. Homi Bhabha Road, Pune - 411008,
India
P34 Insight into the role of electropositive promoters in
emission control catalysis: an in situ DRIFTS study of NO
reduction by C3H6 over Na-promoted Pt/Al2O3 catalysts
M. Konsolakis, I.V. Yentekakis
Laboratory of Physical Chemistry and Chemical Processes (PCCP),
Department of Sciences, Technical University of Crete, University
Campus, 73100, Chania, Greece
15
P35 Enhanced SCR of NOx with decane over combination of
Ag/Al2O3 and metal supported ZSM-5 catalysts
A. Sultana, M. Sasaki, H. Hamada
National Institute of Advanced Industrial Science and Technology (AIST),
Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
P36 Spillover phenomena for H2 assisted NO oxidation over
Ag-Al2O3
M.M. Azis1, D. Creaser1, H.H. Ingelsten2
1Chemical
Engineering, Department of Chemical and Biological
Engineering, Chalmers University of Technology, Gothenburg, 41296,
Sweden
2
Competence Centre for Catalysis, Department of Chemical and
Biological Engineering, Chalmers University of Technology, Gothenburg,
41296, Sweden
P37 A modeling study of NH3 slip catalysts: analysis of
SCR/PGM interactions
M. Colombo1, I. Nova1, E. Tronconi1, G. Koltsakis2
1LCCP, Dipartimento di Energia, Politecnico di Milano, Piazza Leonardo
da Vinci 32, 20133, Milano, Italy
2Laboratory of Applied Thermodynamics, Aristotle University
Thessaloniki, 54124 Thessaloniki, Greece
P38 SCR of NOx by NH3 over V-W/TiO2 catalysts: possible
equilibrium NO conversion constraints
S. Castillo1, R. Camposeco1, G.A. Fuentes2 and I. Mejia1
1Molecular
Engineering Program, Mexican Institute of Petroleum,
México, D.F., 07730, México
2Dep. of Process Engineering, Universidad A. Metropolotana-Iztapalapa,
México, D.F., 09340, México
P39 Ammonia oxidation on structured composite catalysts
S. Shrestha1, M.P. Harold1, K. Kamasamudram2, A. Yezerets2
1
Dept. of Chemical and Biomolecular Engineering, University of Houston,
Houston, TX 77204-4004, USA
2Cummins Inc., 1900 McKinely Av., MC50197, Columbus, IN 47201, USA
P40 Contribution of NO3-surface reduction to the overall
mechanism of H2-assited C6H14-DeNOx over Ag/Al2O3
N.A. Sadokhina1, A.V. Bukhtiyarov2, A.I. Mytareva1, R.I. Kvon2,
V.I. Bukhtiyarov2, A.Yu. Stakheev1
1Zelinsky Institute of Organic Chemistry RAS, Leninsky Prosp. 47,
Moscow, 119991 Russia
2Boreskov Institute of Catalysis SB RAS, Prosp. Lavrentieva 5,
Novosibirsk, 630090 Russia
P41 FTIR and transient reactivity experiments of the
reduction by H2, CO and HCs of NOx stored over PtBa/Al2O3 LNTs
L. Lietti1, L. Righini1, L. Castoldi1, P. Forzatti1, S. Morandi2,
G. Ghiotti2
1
Politecnico di Milano, Laboratory of Catalysis and Catalytic Processes,
Dipartimento di Energia, Piazza L. da Vinci, 32 - 20133 Milano, Italy
2Università di Torino, Dipartimento di Chimica IFM and NIS, Centre of
Excellence, Via P. Giuria 7, 10125 Torino, Italy
16
P42 Characterization of active species in Cu-BEA by
temperature-programmed reduction mass spectrometry
(TPR-MS)
J. Li1, N. Wilken2, K. Kamasamudram1, N.W. Currier1,
L. Olsson2, A. Yezerets1
1Cummins
Inc., 1900 McKinley Ave, MC 50183, Columbus, IN 47201, USA
Competence Centre for Catalysis, Chalmers University of Technology,
41296 Gothenburg, Sweden
2
P43 Urea decomposition and HNCO hydrolysis studied over
inert cordierite, titanium dioxide, Fe-Beta and alumina
using micro calorimetry
A. Lundström1, T. Snelling1, P. Morsing2, P. Gabrielsson2,
E. Senar2, L. Olsson1
1Competence
Centre for Catalysis, Chalmers University, 412 96
Gothenburg, Sweden
2
Haldor Topsøe, Nymoellevej 55, 2800 Kgs. Lyngby, Denmark
P44 Iron sites and mechanism study of Fe/HBEA catalyst for
SCR of NOx with ammonia
L. Ma, J. Li, H. Chang, L. Fu
School of Environment, Tsinghua University, Beijing, China
P45 Effect of acid-base properties on the catalytic activity of
Pt/Al2O3 based catalysts for diesel NO oxidation
M. Sasaki1, K. Suzuki1, S. Asima1, M. Haneda2, H. Hamada1
1
National Institute of Advanced Industrial Science and Technology
(AIST), Tsukuba, Ibaraki 305-8565, Japan
2Ceramics Research Laboratory, Nagoya Institute of Technology, Tajimi,
Gifu 507-0071, Japan
P46 A mechanistic study of the NH3-SCR on Fe-zeolites under
transient conditions
M. Liebeck1, A. Schuler2, M. Votsmeier2, A. Drochner1,
H.Vogel1
1Technische
Universität Darmstadt, Ernst-Berl-Institut für Technische und
Makromolekulare Chemie, Petersenstr. 20, 64287 Darmstadt, Germany
2Umicore AG & Co. KG; 63457 Hanau, Germany
P47 Comprehensive study on synthetic gas bench : On SCR
catalyst using metal-exchanged zeolites based catalyst
with gaseous NH3
B. Jarry1, M. Buton2, M. Partouche2, I. Louis-Rose2, N.Moral2
1Safran Engineering Services, 10 rue du Fort de Saint-Cyr, 78180
Montigny Le Bretonneux, France
2Renault S.A ; 1 Allée Cornuel, 91510 Lardy, France
P48 Screening of Fe- Cu-zeolites prepared by different
methodology for application in NSR-SCR combined
DeNOx systems
U. De La Torre, B. Pereda-Ayo, M.P. González-Marcos,
J.R. González-Velasco
Department of Chemical Engineering, Faculty of Science and
Technology, University of the Basque Country P.O. Box 644, E-48080
Bilbao, Spain
17
P49 Plasma-assisted diesel oxidation catalyst on bench
scale: focus on light-off temperature and NOx behavior
A. Leray1,2, A. Guy4, M. Makarov2, K. Lombaert3, J.M. Cormier1,
A. Khacef1
1GREMI,
PolyTech’Orléans, 14 rue d’Issoudun, BP 6744, 45067Orléans
Cedex 02, France
2
RENAULT S.A.S, FR TCR RUC T 62, 1 avenue du Golf, 78288 Guyancourt,
France
3
RENAULT S.A.S, CTL L16 1 41, 1 Allée Cornuel, 91510 Lardy, France
4SAFRAN Engineering, 10 rue du Fort de Saint Cyr, 78180 Montigny-leBretonneux, France
P50 Experimental and modeling study of a dual-layer NH3
slip monolith catalyst for automotive SCR aftertreatment
systems
M. Colombo1, I. Nova1, E. Tronconi1, L. Zimmermann2,
V. Schmeisser2, B. Bandl-Konrad2
1
LCCP, Dipartimento di Energia, Politecnico di Milano, P.zza Leonardo da
Vinci 32, 20133, Milano, Italy
2DAIMLER AG, 019-G206 – GR/APE, 70546 Stuttgart, Germany
Session « Sorption – Mechanisms - Ageing »
P51 Preventing sulfur poisoning of Ag hydrocarbon SCR
catalysts by using an easily regenerated SOx trap.
R. Burch, S. Chansai, C. Hardacre
Centre for the Theory and Application of Catalysis, CenTACat, School of
Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast,
N. Ireland, U.K.
P52 Effect of Pt dispersion on the catalytic activity of
supported Pt catalysts for diesel hydrocarbon oxidation
M. Haneda1, M. Sasaki2, H. Hamada2, M. Ozawa1
1
Ceramics Research Laboratory, Nagoya Institute of Technology, Tajimi,
Gifu 507-0071, Japan
2National Institute of Advanced Industrial Science and Technology
(AIST), Tsukuba, Ibaraki 305-8565, Japan
P53 Mesoporous CeO2 supported Cu-Mn mixed oxide
catalysts for auto-exhaust application
D. Valechha1, P. Doggali1, S. Rayalu1, Y. Teraoka2,
N. Labhsetwar1
1Environmental
Materials Division, National Environmental Engineering
Research Institute, (NEERI-CSIR), Nehru Marg, Nagpur, 440020 India
2Department of Energy and Material Sciences, Faculty of Engineering
Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
P54 Oxygen storage capacity of low-loaded Pt-CeO2ZrO2
after H2 reduction at 1473 K
N. Kakuta, M. Shibata, H. Ohkita, T. Mizushima
Graduate school of Environmental and Life Sciences, Toyohashi
University of Technology, Tempaku, Toyohashi 441-8580, Japan
18
P55 Regeneration of aged commercial Three-Way Catalysts
using Cl-containing reagents
S.Y. Christou, J.L. G. Fierro, A.M. Efstathiou
Heterogeneous Catalysis Lab, Chemistry Department, University of
Cyprus, P.O. Box 20537, 1678 Nicosia, Cyprus
P56 Effects of thermal ageing and catalyst composition
(PGM/ Ba/ Ce loading) on structural changes and
performances of commercial Lean NOx Trap
D. Adouane1, P. Da Costa1, P. Darcy2
1
Université Pierre et Marie Curie (Paris VI), Institut Jean le Rond
d’Alembert, CNRS UMR 7190, 2 Place de la Gare de Ceinture 78210 Saint
Cyr l’Ecole, France
2Technocentre Renault, 1 avenue du Golf, 78288 Guyancourt Cedex,
France
P57 Comparative study between impact of thermal and
engine ageing on a fully formulated commercial lean
NOx Trap
D. Adouane1, K. Bawolak-Olczak1, H. Dutilleul1, P. Da Costa1,
P. Darcy2, P. Guibert1
1Université Pierre et Marie Curie (Paris VI), Institut Jean le Rond
d’Alembert, CNRS UMR 7190,2 Place de la Gare de Ceinture 78210 Saint
Cyr l’Ecole, France
2
Technocentre Renault, 1 avenue du Golf, 78288 Guyancourt Cedex,
France
P58 Elaboration of an accelerated oven CNG heavy duty
vehicles catalyst ageing for road ageing simulation
M. Adamowska1, V. Lauga2, P. Da Costa1
1
Institut Jean Le Rond d’Alembert, Université Pierre et Marie Curie, UPMC
Paris 6, CNRS UMR 7190, 2 place de la gare de ceinture, 78210 Saint Cyr
L’Ecole, France
2Volvo Powertrain France, 1 rue Henri Germain, 69802 Saint-Priest
Cedex France
P59 Support effect on the catalytic oxidation of propene over
monometallic Pd and Au catalysts
M. Ousmane1, L.F. Liotta2, G. Pantaleo2, A.M. Venezia2,
L. Retailleau1, A. Giroir-Fendler1
1Université de Lyon, Lyon, F-69003, France, Université Lyon 1,
Villeurbanne, F-69622, CNRS, UMR 5256, IRCELYON, 2 avenue Albert
Einstein, Villeurbanne, F-69622, France
2Istituto per Lo Studio dei Materiali Nanostrutturati (ISMN)-CNR via Ugo
La Malfa, 153, 90146 Palermo, Italy
P60 Three Way Catalysis performed with noble metal doped
LaFeCo-perovskites – new active sites for NO reduction
S. Heikens1, G. Mondragon-Rodriguez2, B. Saruhan2,
W. Grünert1
1Laboratory
2DLR,
of Industrial Chemistry, Ruhr-University Bochum, Germany
Institute of Materials Research, Cologne, Germany
19
P61 The use Na, Li, K cations for modification of ZSM-5
zeolite to control hydrocarbon cold-start emission
V. Golubeva1, A. Korableva1, O. Anischenko1, L. Kustov2,
G. Kapustin2, V. Nissenbaum2, U.S. Rohatgi3, M.B.Viola4
1
Russian Federal Nuclear Center, RFNC-VNIIEF, 37, av. Mira, Sarov, Nizhny
Novgorod region, 607190, Russia
2
Institute of Organic Chemistry of Russian Academy of Sciences, 47, av.
Leninsky, Moscow, 119991, Russia
3
Brookhaven National Laboratory, US NNSA DOE, William Floyd Parkway,
County Road, 46, Long Island, Upton, 11973-5000, NY, USA
4
Fuel and Emissions Treatment Systems, GM,GM R&D Center, RMB 172,
48090, Warren, MI, USA
P62 Short-channel structured reactor as a catalytic
afterburner
M. Iwaniszyn1, J. Ocho ska1, A. Gancarczyk1, A. Kołodziej1,2,
J. Łojewska3, A. Knapik3
1
Institute of Chemical Engineering, Polish Academy of Sciences,
Bałtycka 5, 44-100 Gliwice, Poland
2Opole University of Technology, Faculty of Civil Engineering, Katowicka
48, 45-061 Opole, Poland
3
Jagiellonian University, Faculty of Chemistry, Ingardena 3, 30-060
Kraków, Poland
P63 TAP investigation of NO adsorption on Pd/Al2O3 : effect
of thermal aging
F. Dhainaut1, Y. Renème1, S. Pietrzik1, Y. Shuurman2,
C. Mirodatos2, P. Granger1
1
Unité de Catalyse et de Chimie du Solide, UMR CNRS 8181, Université
de Lille, Cité scientifique, Bâtiment C3, 59650 – Villeneuve d’Ascq,
France
2 Ircelyon, UMR CNRS 5256, 69626 Villeurbanne, France
P64 Deactivation mechanisms of catalytic support materials:
preventing the sintering of transition aluminas
M. Schöneborn, D. Niemeyer, F. Alber
Sasol Germany GmbH, Anckelmannsplatz 1, 20537 Hamburg, Germany
P65 Bridging the gap between lab scale and full scale
catalysis experimentation
J. Sjöblom
Applied Mechanics, Chalmers University of Technology, SE 412 96
Gothenburg, Sweden
P66 Effect of hydrothermal ageing on physical and chemical
properties of a commercial NSR catalyst
D. Chan2, O. Deutschmann1
1Karlsruhe
Institute of Technology (KIT), 76128 Karlsruhe, Germany
for Chemical Technology and Polymer Chemistry, 76131
Karlsruhe, Germany
2Institute
20
P67 Estimation of local aging effects of Three-Way-Catalysts
by analysis of their spatial temperature and CO
conversion profiles
C. Hauck1,2, N. Mladenov1,2, S. Tischer1,3, O. Deutschmann1,4
1
Karlsruhe Institute of Technology, Karlsruhe, 76128, Germany
Institut für Technische Chemie und Polymerchemie (ITCP), KIT,
Karlsruhe,76131, Germany
3
Institut für Kern- und Energietechnik (IKET), KIT, EggensteinLeopoldshafen,76344, Germany
4
Institut für Katalyseforschung und Technologie (IKFT), KIT, EggensteinLeopoldshafen,76344, Germany
2
P68 Improved sulfur resistance of noble metal catalyst for
lean burn natural gas applications
N.M. Kinnunen, K.o Kallinen, T.-J.J. Kinnunen
Ecocat Oy, Typpitie 1, FI-90620, Oulu, Finland
P69 Effect of aging atmosphere on the thermal sintering of
modern commercial Pd only and Rh-only TWCs
S.B. Kang1, S.J. Han1, S.B. Nam1, I.-S. Nam1, B.K. Cho1,
C.H. Kim2, S.H. Oh2
1
Department of Chemical Engineering/School of Environmental Science
& Engineering, Pohang University of Science and Technology (POSTECH),
San 31, Hyoja-dong, Nam-gu, Pohang 790-784, Korea
2
General Motors Global R&D Center, Warren MI 48090-9055, USA
P70 New methodology for transient engine rig experiments
for efficient parameter estimation
B. Lundberg1, J. Sjöblom2, Å. Johansson3, B. Westerberg4,
D. Creaser1
1
Department of Chemical and Biological Engineering, Chemical Reaction
Engineering, Chalmers University of Technology, Göteborg, SE-412 96,
Sweden
2Department of Applied Mechanics, Division of Combustion, Chalmers
University of Technology, Göteborg, SE-412 96, Sweden
3Johnson Matthey AB, Västra Frölunda, SE-421 31, Sweden
4
Scania AB, Södertälje, SE-151 87, Sweden
P71 Structure-activity relationship of iron oxide-based
catalysts
A. Pacher, S. Kureti
Technical University of Freiberg, Department of Energy Process
Engineering and Chemical Engineering, D-09599 Freiberg, Germany
P72 Mechanistic study of CO oxidation on aluminasupported Fe2O3 catalysts
D. Reichert, I. Grünert, S. Kureti
Department of Energy Process Engineering and Chemical Engineering,
TU Freiberg, D-09596, Germany
21
P73 CO oxidation aver manganese and cerium oxides
supported on ɣ-Al2O3
M. Tepluchin1, A. Boubnov1, J.-D. Grunwaldt1, S. Kureti2
1
Karlsruhe Institute of Technology, Institut für Technische Chemie und
Polymerchemie (ITCP) 76131 Karlsruhe, Germany
2
Technical University Bergakademie Freiberg, Department of Energy
Process Engineering and Chemical Engineering, D-09596 Freiberg,
Germany
P74 Using rate mapping methods for model reduction in the
simulation of catalytic converters
T. Nien1, R.E. Hayes1, M. Votsmeier2
1
Department of Chemical and Materials Engineering, University of
Alberta, Edmonton, T6G 2G6 Alberta, Canada
2
Umicore, Automotive Catalysis Division, Research and Development,
Hanau, Germany
P75 Dual layer automotive ammonia oxidation catalysts:
experiments and computer simulation
A. Scheuer 1,2, M. Votsmeier 2, J. Gieshoff 2, A. Drochner 1,
H. Vogel 1
1
Technische Universität Darmstadt, Ernst-Berl-Institut, Petersenstr. 20,
64287 Darmstadt, Germany
2Umicore AG & Co. KG, Rodenbacher Chaussee 4, 63403 Hanau,
Germany
P76 Synthesis of highly dispersed Pt supported catalysts for
Three-Way Catalysis: arc plasma deposition method
K.N. Rao, Y.E. Jeong, H.P. Ha
Interfacial Engineering Research Center, Korea Institute of Science and
Technology, Cheongryang, Seoul 130-650, Republic of Korea
P77 Particle size effect in CH4 oxidation over noble metals:
comparison of Pt and Pd catalysts
A. Yu. Stakheev1, A.M. Batkin1, I.E. Beck2, N.S. Teleguina1,
G.O. Bragina1, V.I. Zaikovsky2, Yu. V. Larichev2,
V.I. Bukhtiyarov2
1
Zelinsky Institute of Organic Chemistry RAS, Leninsky Prosp. 47,
Moscow, 119991 Russia
2Boreskov Institute of Catalysis SB RAS, Prosp. Lavrentieva 5,
Novosibirsk, 630090 Russia
P78 Spectrokinetic analysis of the NOx storage over a PtBa/Al2O3 LNT catalyst
C.G. Visconti1, L. Lietti1, P. Forzatti1, F. Manenti1, S. Pierucci1,
M. Daturi2
1Politecnico
di Milano, Laboratory of Catalysis and Catalytic Processes,
Dipartimento di Energia, Piazza L. da Vinci, 32 - 20133 Milano, Italy
2CNRS, Universitè de Caen, ENSICAEN, Laboratoire Catalyse et
Spectrochimie, 6 Bd. Maréchal Juin, 14050 Caen, France
P79 The effect of gas composition during thermal aging on
the dispersion and NO oxidation activity over a Pt/Al2O3
catalyst
X. Auvray and L. Olsson
Competence Centre for Catalysis, Chalmers University, 412 96
Gothenburg, Sweden
22
P80 Investigation of the effect of accelerated hydrothermal
aging on the Cu sites in a Cu- HBEA catalyst for NH3-SCR
applications
N. Wilken1, R. Vedaiyan2, K. Kamasamudram2, N.W. Currier2,
J. Li2, A. Yezerets2, L. Olsson1
1Competence Centre for Catalysis, Chalmers University of
Technology,41296 ,Gothenburg, Sweden
2
Cummins Inc., Columbus, 47201, IN, USA
P81 Hydrothermal ageing-induced changes in washcoats of
commercial Three-Way Catalysts
A. Fathali1,2, L. Olsson2, F. Ekström1, B. Andersson2
1
Saab Automobile Powertrain AB, SE-46180 Trollhättan, Sweden
Chalmers University of Technology, SE-412 96 Göteborg, Sweden
2
P82 Simulated fuel-cut ageing of commercial Three Way
Catalysts
A. Fathali 1,2, L. Olsson2, P. Ericsson1, B. Andersson2
1Saab
Automobile Powertrain AB, SE-46180 Trollhättan, Sweden
Chalmers University of Technology, SE-412 96 Göteborg, Sweden
2
P83 The impact of aging environment on the evolution of Pt
nanoparticles on alumina and NO oxidation activity
S.K. Matam1, M. Aguirre1, P. Hug1, D. Rentsch2, A. Winkler3,
A. Weidenkaff1, D. Ferri1
1Empa, Swiss Federal Laboratories for Materials Science and
Technology, Laboratory for Solid State Chemistry and Catalysis,
Ueberlandstrasse 129, CH–8600 Duebendorf, Switzerland
2
Laboratory for Functional Polymers, Ueberlandstrasse 129, CH–8600
Duebendorf, Switzerland
3Internal Combustion Engines Laboratory, Ueberlandstrasse 129,
CH–8600 Duebendorf, Switzerland
P84 Studies on phosphorous induced deactivation of model
three-way catalysts for CNG vehicle exhaust
applications
S.K. Matam1, A. Winkler2, A. Ulrich3, F. Wen4, J. Gieshoff4,
C. Bach2, A. Weidenkaff1, D. Ferri1
1Empa, Lab. for Solid State Chemistry and Catalysis, Ueberlandstrasse
129, CH–8600 Duebendorf, Switzerland
2Internal Combustion Engines Lab., Ueberlandstrasse 129, CH–8600
Duebendorf, Switzerland
3Lab. for Analytical Chemistry, Ueberlandstrasse 129, CH–8600
Duebendorf, Switzerland
4Umicore AG & Co. KG, 63457 Hanau-Wolfgang, Germany
P85 Effect of hydrothermal aging on structure and activity of
alumina and ceria-zirconia supported Pd Three-Way
Catalysts
O. Korsak1, F. Wen2, M.S. Kumar1, J. Gieshoff2, P. Hug1,
A. Weidenkaff1, D. Ferri1
1Empa, Lab. for Solid State Chemistry and Catalysis, Ueberlandstrasse
129, Dübendorf, 8600 Switzerland
2
Umicore AG & Co. KG, Hanau-Wolfgang, 63457 Germany
23
P86 Flame spray synthesis of palladium supported
perovskite-type Three-Way Catalysts for exhaust after
treatment of natural gas engines
Y. Lu1, K. Michalow-Mauke2, A. Winkler3, A. Heel4,
S. K. Matam1, P. Hug1, A. Weidenkaff1, D. Ferri1
1Laboratory for Solid State Chemistry and Catalysis, Empa, Swiss Federal
Laboratories for Materials Science and Technology, Ueberlandstrasse
129, CH-8600 Dübendorf, Switzerland
2
Laboratory for High Performance Ceramics, Empa, Swiss Federal
Laboratories for Materials Science and Technology, Ueberlandstrasse
129, CH-8600 Dübendorf, Switzerland
3Internal Combustion Engines Laboratory, Empa, Swiss Federal
Laboratories for Materials Science and Technology, Ueberlandstrasse
129, CH-8600 Dübendorf, Switzerland
4
Marketing, Knowledge and Technology Transfer, Empa, Swiss Federal
Laboratories for Materials Science and Technology, Ueberlandstrasse
129, CH-8600 Dübendorf, Switzerland
P87 A DFT-based micro-kinetic model for methane oxidation
over Pd and Pt
A. Trinchero, A. Hellman, H. Grönbeck
Department of Applied Physics and Competence Centre for Catalysis,
Chalmers University of Technology, Göteborg, SE-412 46, Sweden
P88 Nanosized M-doped (M = Pr, Tb and Hf) ceria solid
solutions: promotional effect of dopant on CO oxidation
P. Sudarsanam, L. Katta, B. Mallesham, B.M. Reddy
Inorganic and Physical Chemistry Division, Indian Institute of Chemical
Technology, Uppal Road, Hyderabad – 500 607, India
P89 Sulfur promoted methane oxidation over supported
platinum catalysts
P.-A. Carlsson1, S. Fouladvand1, D. Bounechada2,
L. Kylhammar1, J. Gustafson3, E. Lundgren3, M. Skoglundh1
1Competence Center for Catalysis, Chalmers University of Technology,
412 96 Götenborg, Sweden
2
Diparimento di Energia, Politecnico di Milano, 20133 Milano, Italy
3Division of Synchrotron Radiation Research, Lund University, Lund,
Sweden
P90 Low-temperature methane oxidation over single crystal
Pd(100)
J. Gustafson1, A. Hellman2, A. Resta3, S. Blomberg1,
N. Martin1, R. van Rijn3, O. Balmes3, P.A. Carlsson2,
H. Grönbeck2, M. Skoglund2, J.N. Andersen1, E. Lundgren1
1Division of Synchrotron Radiation Research, Lund University, Box 118,
SE-221 00, Lund, Sweden
2Competence Center for Catalysis, Chalmers University of Technology,
SE-41296 Göteborg, Sweden
3ESRF 6, rue Jules Horowitz, 38000 Grenoble, France
P91 Noble metal doped perovskite BaCe1-xPtxO3-δ as efficient
water gas shift catalyst
T. Rajesh, C.S. Gopinath, R. Nandini Devi
Inorganic Chemistry and Catalysis Division, National Chemical
laboratory, Pune-411008, India
24
P92 CFD Simulation of exhaust gas reforming of propane in
a heat exchange integrated microchannel reactor
I. Sen, M. Karakaya, A.K. Avci
Department of Chemical Engineering, Bogazici University, Bebek
34342, Istanbul, Turkey
P93 Preparation, testing and characterization of Pt-based
DOC-catalysts
S. Conrad1, A. Boubnov1, M. Tepluchin1, M. Casapu1,
J.-D. Grunwaldt1
Karlsruhe Institute of Technology, Institute for Chemical Technology and
Polymer Chemistry, 76131 Karlsruhe, Germany
P94 Fuel gas upgrading of over La1-xCexCoO3 with toluene as
model compound
K. Soongprasit1,2, D. Aht-Ong1,2, V. Sricharoenchaikul3,
D. Atong4
1
Department of Materials Science, Faculty of Science, Chulalongkorn
University, Bangkok 10330 Thailand
2Research Unit of Advanced Ceramics and Polymeric Materials, National
Center of Petroleum, Petrochemicals, and Advanced Materials,
Chulalongkorn University, Bangkok 10330, Thailand
3Department of Environmental Engineering, Faculty of Engineering,
Chulalongkorn University, Bangkok 10330, Thailand
4National Metal and Materials Technology Center, Thailand Science Park,
Pathumthani 12120, Thailand
P95 Characterising bimetallic catalysts for emission control
using quantitative infrared spectroscopy
S.B. Campbell, R.P.K. Wells, J.A. Anderson
Surface Chemistry and Catalysis Group, University of Aberdeen,
Aberdeen AB24 3FX, Scotland
P96 Detailed mechanism for reduction of N2O by CO over
rhodium in automotive exhaust
Q. Su, S. Wang, Y. Li
Institute of Internal Combustion Engines, Dalian University of
Technology, Dalian, 116024, China
P97 On the effect of reduction and ageing on the TWC
activity of Pt/Ce0.68Zr0.32O2 under simulated automotive
exhausts
M.P. González-Marcos, B. Pereda, U. de la Torre,
J.R. González-Velasco
Dept. Chemical Engineering, Fac. Science and Technology, the University
of the Basque Country, UPV/EHU, E-48940, Leioa, Spain
P98 Characterization of catalytically-active Pt-alloy surfaces
and core-shell nanoparticles using atom probe
tomography
Tong Li1, P.A.J. Bagot1, E.A. Marquis2, S.C.E.Tsang3, G.D.W. Smith1
1Department of Materials, Oxford University, Parks Road,
Oxford OX1-3PH, United Kingdom
2
Department of Materials Science and Engineering, University of
Michigan, Ann Arbor, MI 48109, USA
3
Chemistry Research Laboratory, Oxford University, 12 Mansfield Road,
Oxford OX1-3TA, U.K.
25
P99
Influence of the preparation method of NiMo catalysts
supported on silica, silica-titania and silica-zirconia in
the activity to thiophene hydrodesulfurization
Alano Viera da Silva Neto, Ernesto A. Urquieta-González
Laboratory of Catalysis, Department of Chemical Engineering, Federal
University of Sao Carlos, C. Postal 676, CEP 13.565-905, Sao Carlos-SP,
Brazil
Session « Fuel alternatives – Innovative
technologies - TWC »
P100 New advanced materials for most efficient automotive
TWC catalysts
S. Ifrah1, O. Larcher1, R. Marques2, R. Rohe1, E. Rohart1
1
RHODIA Rare Earth Systems GBU - ZI, 26 rue Chef de Baie, 17041 La
Rochelle Cedex, France
2RHODIA Rare Earth Systems GBU - 52 rue de la Haie Coq, 93308
Aubervilliers, France
P101 Glycerol ethers production and engine performance
with diesel/ethers blend
F. Frusteri1, C. Cannilla1, G. Bonura1, L. Spadaro1,
A. Mezzapica1, C. Guido2, C. Beatrice2
1CNR-ITAE,
Istituto di Tecnologie Avanzate per l’Energia “Nicola
Giordano”, Via S. Lucia 5, 98126 – Messina, Italy
2CNR-IM, Istituto Motori, Via Marconi 8, 80125, Napoli, Italy
P102 Evaluation of the photocatalytic potential of TiO2
nanopowders for selective catalytic oxidation of
ammonia and selective catalytic reduction of NOx using
ammonia
S. Heylen, S. Smet, K. Laurier, M. Roeffaers, C. Kirschhock,
J.A. Martens
Center for Surface Chemistry and Catalysis, Katholieke Universiteit
Leuven, 23 Kasteelpark Arenberg 3001 Heverlee, Belgium
103
Nickel-Alumina aerogels as Three-Way Catalysts
B.A. Bruno1, J.E. Madero1, S.J. Juhl2, J. Rodriguez1,
N.J.H. Dunn2, M.K. Carroll2, A.M. Anderson1
1Department of Mechanical Engineering, Union College, Schenectady
NY, 12308, USA
2Department of Chemistry, Union College, Schenectady NY, 12308, USA
104
Microstructured reactor as a pre-turbo catalytic
converter
M. Iwaniszyn1, J. Ocho ska1, A. Gancarczyk1,
A. Kołodziej1,2, J. Łojewska3, P. Jodłowski3
1Institute of Chemical Engineering, Polish Academy of Sciences,
Bałtycka 5, 44-100 Gliwice, Poland
2Opole University of Technology, Faculty of Civil Engineering, Katowicka
48, 45-061 Opole, Poland
3
Jagiellonian University, Faculty of Chemistry, Ingardena 3, 30-060
Kraków, Poland
26
P105 Wire gauze structured catalysts for CO removal from
biogas fuelled engines: modeling and testing
P.J. Jodłowski1, R. Gołąb1, J. Ochońska1, A. Kołodziej2,4,
S.T. Kolaczkowski3, J. Łojewska1
1
Jagiellonian University, Faculty of Chemistry, Ingardena 3, 30-060
Kraków, Poland
2
Opole University of Technology, Faculty of Civil Engineering, Katowicka
48, 45-061 Opole, Poland
3
Department of Chemical Engineering, University of Bath, Claverton
Down, Bath BA27AY, UK
4
Institute of Chemical Engineering of the Polish Academy of Sciences,
Bałtycka 5, 44-100 Gliwice, Poland
P106 Steam reforming of CH4 and microstructure of
BaTi(1-x)RhxO3
G.C. Mondragón Rodríguez, Y. Gönüllü and B. Saruhan
German Aerospace Center (DLR), Institute of Materials Research, Dept.
High Temperature and Functional Coatings, 51147, Cologne Germany
P107 Pd supported on LaFeO3±δ as potential catalyst for
methane oxidation
A. Eyssler, M. Santhosh Kumar, Y. Lu, P. Hug, A. Weidenkaff,
D. Ferri
Empa, Lab. for Solid State Chemistry and Catalysis, Ueberlandstrasse
129, Dübendorf, 8600 Switzerland
P108 In-situ Three-Way-Catalyst characterization for a
laboratory test bench
G. Beulertz1, M. Fritsch1, G. Fischerauer1, F. Herbst2,
J. Gieshoff2, M. Votsmeier2, G. Hagen1, R. Moos1
1University
of Bayreuth, Bayreuth Engine Research Center, Bayreuth,
Germany
2
Umicore AG & Co. KG, Hanau-Wolfgang, Germany
P109 Methane oxidation over Pd supported on ceria-alumina
S. Fouladvand1, S. Schernich2, J. Libuda2, H. Grönbeck1,
M. Skoglundh1, P.-A. Carlsson1
1Competence Centre for Catalysis, Chalmers University of Technology,
41296 Göteborg, Sweden
2Lehrstuhl für Physikalische Chemie II, University Erlangen-Nuremberg,
Germany
P110 Effects of hydrothermal ageing and reducing agent on
the lean NOx reduction over Ag-Al2O3 catalysts
F. Gunnarsson1, J.-Y. Zheng1, H. Kannisto1, C. Cid1,
A. Lindholm2, M. Milh2, M. Skoglundh1, H.H. Ingelsten1
1Competence Centre for Catalysis, Department of Chemical and
Biological Engineering, Chalmers University of Technology, SE-412 96
Göteborg, Sweden
2Volvo Technology Cooperation, SE-412 88 Göteborg, Sweden
P111 Photocatalytic removal of air pollutants from diesel
engines
M. Smits, T. Tytgat, B. Hauchecorne, S. Lenaerts
University of Antwerp, Groenenborgerlaan 171, 2020 Antwerpen,
Belgium
27
P112 Monolithic catalysts with low Pt-Pd content for diesel
vehicle emission control
S.A. Yashnik1, Z.R. Ismagilov1, S.P. Denisov2,
N.M. Danchenko2
1
Boreskov Institute of Catalysis, Prosp. Akad. Lavrentieva, 5,
Novosibirsk 630090, Russia
2
Ural Electrochemical Integrated Plant, Novoural’sk, Russia
P113 Characterization and catalytic performance of cobalt
chromites on methane combustion at low temperature
J. Chen, J. Li
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, Tsinghua University, Beijing 100084,
China
P114 Spatiotemporally-resolved OFDR-based measurements
of transient temperature distributions within operating
monolithic catalysts
J. Yoo, J.S. Choi, W.P. Partridge
Fuels, Engines, and Emissions Research Center, Oak Ridge National
Laboratory, Tennessee, USA
P115 Heat-integrated exhaust purification for monovalent
CNG engines
M. Rink1, U. Nieken1, G. Eigenberger1, M. Weibel2, T. Rappe2,
A. Fürhapter3, M. Certic3, F. Ayad4
1University of Stuttgart, Institute of Chemical Process Engineering, D70199 Stuttgart, Germany
2Daimler AG, Dept. Combustion & Emission Control, Mercedesstraße
137, D-70546 Stuttgart, Germany
3AVL List GmbH, Hans-List-Platz 1, A-8020 Graz, Austria
4
Delphi Thermal Systems, Avenue de Luxembourg, L-4940 Bascharage,
Luxemburg
Session « Particulate matters »
P116 Improved synthesis of BaRuO3 barium ruthenate and
its catalytic activity for diesel soot oxidation
N. Labhsetwar1, P. Doggali1, S. Rayalu1, O. Cadora2,
F. Grasseta2, Y. Teraoka3
1Environmental Materials Division, National Environmental Engineering
Research Institute, (NEERI-CSIR), Nehru Marg, Nagpur 440020, India
2UMR Science Chimiques de Rennes UR1-CNRS 6226, Université de
Rennes 1, Campus de Beaulieu, CS74205, F-35042 Rennes Cedex,
France
3Department of Energy and Material Sciences, Faculty of Engineering
Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
P117 Bench scale experiments of diesel soot oxidation using
Pr0.7Sr0.2K0.1MnO3 perovskite type catalyst coated on
ceramic foam filters
P. Doggali1, H. Khusaba2, S. Rayalu1, Y. Teraoka2,
N. Labhsetwar1
1Environmental Materials Division, National Environmental Engineering
Research Institute, (NEERI-CSIR), Nehru Marg, Nagpur, 440020 India
2Department of Energy and Material Sciences, Faculty of Engineering
Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
28
P118 Ag promoted ceria catalysts: effect of surface area and
pore characteristics on catalytic soot oxidation
P. Doggali1, P. Mungse1, J. Subart4, S. Rayalu1, Y. Teraoka2,
T. Mitsuhashi3, N. Labhsetwar1
1
Environmental Materials Division, National Environmental
Engineering Research Institute, (NEERI-CSIR), Nehru Marg, Nagpur,
440020 India
2
Department of Energy and Material Sciences, Faculty of Engineering
Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
3
National Institute for Materials Science,1-1, Namiki, Tsukuba Ibaraki
3050044, Japan
4
Institute of Inorganic Chemistry, Academy of Sciences of the Czech
Republic,-250 68 ež, Czech Republic
P119 Oxidation of carbonaceous deposit over Me2+Fe2O4
spinel type catalysts
Z. Sarbak
Laboratory of Adsorption and Catalysis in Environmental Protection,
Department of Chemistry, Adam Mickiewicz, University, Grunwaldzka 6,
60-780 Pozna , Poland
P120 Effect of biofuels on catalyzed diesel particulate filter
regeneration
N. Lamharess1, L. Starck2, C.N. Millet1, P. Da Costa3
1IFP
Energies nouvelles, Rond-point de l’échangeur de Solaize, BP 3,
69360 Solaize, France
2
IFP Energies nouvelles, 1-4 avenue de Bois-Préau, 92852 RueilMalmaison, France
3
Institut Jean le Rond d’Alembert, université Pierre et Marie Curie, 2
place de la gare de ceinture 78210 Saint Cyr l’École, France
P121 Soot combustion catalysed by ceria and ceria-zirconia
mixed oxides prepared from two different cerium
precursors
N. Guillén-Hurtado, A. Bueno-López, A. García-García
MCMA Group. Department of Inorganic Chemistry. Faculty of Sciences.
University of Alicante. Carretera San Vicente del Raspeig s/n. San
Vicente del Raspeig, Alicante, Spain
P122 Evaluation and treatment of carbonyl compounds and
fine particles emitted by combustion of biodiesel in a
generator
A.-F. Cosseron1, T. Jean Daou2, V. Tschamber1
1Laboratoire
Gestion des Risques et Environnement, Université de
Haute Alsace, 3B rue Alfred Werner 68093 Mulhouse, France
2Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des
Matériaux de Mulhouse (IS2M), LRC CNRS 7228-UHA, 3, rue Alfred
Werner, 68093 Mulhouse Cedex, France
P123 Ag incorporated SiO2 as diesel soot oxidation catalyst:
Effect of metallic Ag in Ag/SiO2 for diesel soot
oxidation
G. Corro, U. Pal, E. Vidal, E. Ayala, F. Bañuelos
Benemerita Universidad Autonoma de Puebla,4 sur 104, Puebla 7200,
Mexico
29
P124 Mechanism of the catalytic soot oxidation on Fe2O3
S. Wagloehner, S. Kureti
Department of Energy Process Engineering and Chemical Engineering,
TU Freiberg 09596, Germany
P125 Novel α-Al2O3 diesel particulate filter with alkali metalbased catalyst for diesel soot oxidation
K. Mizutani, K. Takizawa, H. Shimokawa, T. Suzawa,
N. Ohyama
Nippon Soken, INC., Nischio, Aichi 445-0012, Japan
P126 Effect of soot during operation of a Pt-K/Al2O3 LNT
catalyst
R. Matarrese, N. Artioli, L. Lietti, L. Castoldi, P. Forzatti
Politecnico di Milano, Laboratory of Catalysis and Catalytic Processes,
Dipartimento di Energia, Piazza L. da Vinci, 32 - 20133 Milano, Italy
P127 In-operation monitoring of the soot load of diesel
particulate filters - initial tests
G. Hagen, M. Feulner, A. Piontkowski, A. Müller,
G. Fischerauer, D. Brüggemann, R. Moos
Bayreuth Engine Research Center (BERC), 95440 Bayreuth, Germany
P128 The role of electronic factor in soot oxidation process
over tunneled and layered potassium iron oxide
catalysts
P. Stelmachowski, P. Legutko, M. Trebala, W. Bieniasz,
Z. Sojka, A. Kotarba
Faculty of Chemestry, Jagiellonian University, Ingardena 3, 30-60
Cracow, Poland
P129 Influence of the alkali promoter on the activity and
stability of transition metal (Cu, Co, Fe) based
structured catalysts for the simultaneous removal of
soot and NOx
M.E. Gálvez, S. Ascaso, R. Moliner, M.J. Lázaro
Instituto de Carboquímica, CSIC, Miguel Luesma Castan 4, 50018
Zaragoza, Spain
P130 Kinetics of soot oxidation in wall-flow particulate filters
and determination of a surface area dependent rate
expression
J. A. Pihl1, V. Strots2, B. Adelman2, E. Derybowski2,
T. J. Toops1
1Oak Ridge National Laboratory, 2360 Cherahala Blvd., Knoxville,
TN 37932, USA
2Navistar, Inc., Navistar Engine Plant & Technical Center, Melrose Park,
IL 60160, USA
P131 Rare earth (La, Nd, Pr) doped ceria zirconia solid
solutions for soot combustion
P. Dulgheru1,2, J. A. Sullivan2
1CPMCT
Université Libre de Bruxelles, Bruxelles, 1050, Belgium
UCD School of Chemistry and Chemical Biology, Belfield, Dublin 4,
Ireland
2
30
S O L B O S C H
BUS 71, TRAM 25/94
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CONGRESS
31
M A P
Local organisation committee
EXECUTIVE CHAIRMAN
KRUSE N. Université Libre de Bruxelles, B.
CO–CHAIR
VISART DE BOCARMÉ T. Université Libre de Bruxelles, B.
TREASURER
BASTIN J-M. Université Libre de Bruxelles, B.
CONFERENCE SECRETARY
DESANTOINE A. Université Libre de Bruxelles, B.
Scientific advisory board
BAIKER A. Swiss Federal Institute of Technology, CH.
BOSTEELS D. AECC, B.
BURCH R. Queen’s University Belfast, UK.
DAWODY J. Volvo Technology CO, SE.
FORZATTI P. Politecnico di Milano, I.
GIESHOFF J. Umicore AG & Co. KG, B.
GREENING P. ACEA, B.
JANNES G. Institut Meurice, B.
JOHNSON T. Corning Incorporated, USA.
KRUTZSCH B. Daimler AG, D.
MAKKEE M. Delft University of Technology, NL.
McCABE R. Ford Research Laboratory, USA.
SKOGLUNDH M. Chalmers Univ. of Technology, SE.
TWIGG M. Caxton, Cambridge, UK.
SAKATA I. Toyota Motors Europe, B.
YEZERETS A. Cummins, USA.
32
Print : Clerebaut, 1180 Brussels
MATTHESS N. PSA Peugeot Citroën, F.